Alkaline‐Earth Metal Doped K‐V Catalysts for Diesel Soot Combustion–Preparation,Characterization and Catalytic Properties

The K‐V‐alkaline‐earth metal catalysts supported on α‐alumina ceramic substrate have been prepared. The morphology of the soot particulates deposited on prepared catalysts supported on α‐alumina ceramic substrate was described by scanning electron microscopy (SEM). The XRD was used to characterize the catalysts and their catalytic activities were evaluated by soot oxidation reaction using the TPR system. The SEM photographs presented that soot particles have a particle size of about 100 nm in diameter forming a loose contact with catalyst, which is resemble to the real situation for the catalyst application. The XRD and TPR study showed that the catalytic activities of the catalysts were improved through the cooperation of KNO₃ and some alkaline earth metal compounds. The soot onset ignition temperature at 310°C is the lowest by the cooperation of the crystalline phases KNO₃, KCaVO₄, and Ca₃(VO₄)₂ for the K‐V‐Ca catalyst with a molar ratio of 6:1:1. In addition, the catalyst containing higher KNO₃ content has an adsorption for CO₂. The all prepared K‐V‐Ba catalysts can adsorb more CO₂ at room temperature.     

过氧钒配合物的合成、结构及模拟过氧化酶催化溴化动力学

根据模拟钒卤代过氧化物酶(V-HPOs)活性中心的配位环境,设计并合成了2种新型过氧钒配合物：Na[VO(O2)2(C10H8N2)]·8H2O(1)和K3H[(VO)2(O2)4(μ2-O)]·H2O(2),通过元素分析、红外光谱和紫外光谱对其进行了表征,并通过X射线单晶衍射方法确定了其结构。 配合物1晶体属于三斜晶系,空间群：P-1,a=0.7213(2) nm,b=1.1269(4) nm,c=1.3728(4) nm,α=68.349(4)°,β=89.178(4)°,γ=88.050(4)°,V=1.0365(6) nm3。 配合物2的晶体属于单斜晶系,空间群：P21/c,a=0.67047(12) nm,b=0.99503(18) nm,c=1.5817(3) nm,α=γ=90°,β=93.739(2)°,V=1.0530(3) nm3。 配合物1和2分别是五角双锥和八面体配位构型。 通过催化溴化反应活性研究发现,2种配合物均可作为潜在的钒卤代过氧化物酶模拟物。     

Abundance gradients in the galactic disk

The relationship between abundances and orbital parameters for 235 F- and G-type intermediate- and low- mass stars in the Galaxy is analyzed. We foundthat there are abundance gradients in the thin disk in both radial and verticaldirections (-0.116 dex kpc-1 and -0.309 dex kpc-1 respectively). The gradients appear to be flatter as the Galaxy evolves. No gradient is found in the thick disk based on 18 thick disk stars. These results indicate that the ELS model is mainly suitable for the evolution of the thin disk, while the SZ model is more suitable for the evolution of the thick disk. Additionally, these results indicate that in-fall and out-flow processes play important roles in the chemical evolution of the Galaxy.     

小脑齿状核MRI功能成象研究

通过测量齿状核T₁弛豫时间,设计出齿状核功能成象破坏稳态梯度回波序列的成象参数,并用此序列在一正常志愿者,在静止和刺激时交替扫描3次,进行齿状核功能成象,刺激时齿状核信号平均强度是静止时的1.2倍.静止和刺激时齿状核信号强度没有重叠     

Experimental study of heat and mass transfer of a rolling wheel

Heat transfer characteristics of a rolling wheel are investigated by using the naphthalene sublimation technique. The local and average Nusselt numbers are obtained. The results reveal that the local and average Nusselt numbers increase with increasing rotating Reynolds number. Under the same rotating Reynolds number they decrease along the radius direction. After comparing with similar available cases reported, it is found that the results are very close to the results of rotating disk in crossflow under the condition that rotating Reynolds number is equal the main flow Reynolds number.     

异物致损铁道车轴的疲劳强度及寿命评估

车轴是高速列车关键承载部件, 承受着源自车体、轨道的各种载荷,其疲劳行为直接关乎列车运行安全. 疲劳裂纹往往具有较强的隐蔽性和突然性,由车轴断裂发生的列车脱轨事件具有灾难性,因此确保车轴在运行中不发生失效事故, 对高速列车可靠运行至关重要.高速列车实际运营中, 车轴外表面受到各种异物击打, 会形成深度达毫米级的缺陷,破坏车轴表面完整性, 严重威胁车辆安全.本研究采用空气炮装置预制合金钢车轴小试样异物致损(foreign object damage, FOD)缺陷,采用扫描电子显微镜和体视显微镜观测损伤特征.开展高周疲劳试验获得光滑试样和FOD损伤小试样的疲劳S-N曲线,考虑载荷模式、表面质量和尺寸系数推证出全尺寸车轴的疲劳性能.断口分析表明, 裂纹于FOD附近多处位置萌生, 并在不同平面内连续扩展,最终汇聚为一个半椭圆形裂纹. 基于Peterson公式和El Haddad模型估算异物冲击速度100 m/s和138 m/s试样的理论疲劳极限远低于试验结果, 过于保守; 同时也远低于标准推荐值, 偏于危险. 最后,采用修正的Miner理论公式估算含FOD实物车轴的服役寿命,满足最低25年的服役寿命.      

Cd(Ⅱ)双苯吡唑基吡啶-草酸混配合物的合成、结构与性质

合成了Cd(Ⅱ)与类蝎型吡唑衍生物和草酸的混合配体的配合物[Cd2(HL)2(ox)]·1.5H2O(H2L=2,6-二(5-苯基-吡唑-3-基)吡啶,H2ox=草酸)。 通过元素分析、红外光谱、紫外光谱、X射线粉末衍射(PXRD)和X射线单晶结构分析确定了配合物的结构。 配合物晶体属于三斜晶系、P-1空间群,Cd(Ⅱ)是六配位,由一个ox2-基中的2个O原子和来自2个HL-中的4个N原子配位,构成变形八面体配位构型,而相邻Cd(Ⅱ)原子间均通过HL-上的N原子和草酸根分别连接形成2条互不相交的一维无限链状结构。 性质测试结果表明,该配合物具有良好的热稳定性和荧光特性,对环己烷氧化反应也具有一定的催化活性。     

席夫碱及其金属配合物的合成及生物活性研究进展

席夫碱及其金属配合物具有独特的抗菌、抗肿瘤和抗氧化等生物活性.为筛选高效低毒的药物,人们合成了大量不同类型的席夫碱及其金属配合物并对其生物活性进行了研究.本文综述了近年来席夫碱及其金属配合物的合成,以及在抗菌、抗氧化、抗肿瘤等方面生物活性的研究进展,并为进一步研究其在医药领域的应用提供了信息支持.     

铁(Ⅲ)的氮杂环配合物的合成、结构及对环己烷氧化的催化性能

制备了铁氮杂环配合物[Fe(H2L)2]·(CH3COO)2·(OH)·H2O(H2L=2,6-二(5-甲基-1H-吡唑-3-基)吡啶),通过元素分析、X射线粉末衍射和X射线单晶结构分析等技术手段表征了它的结构。 将其用于液相环己烷的催化氧化,系统研究了H2O2用量、HNO3用量、水量、反应时间和温度等对中间活性物种环己基过氧化氢(C6H11OOH) 的生成和分解的影响,探讨了反应机理。 结果表明,H2O2是氧化环己烷为C6H11OOH的主要氧化剂;硝酸对此过程没有氧化作用,但能大幅度提高C6H11OOH分解成环己醇(酮)的分解速率。 H2O会抑制中间物种C6H11OOH的生成和分解,而降低催化剂的比活性。 在不同反应阶段,C6H11OOH和环己醇(酮)的生成速率不同。 升温能促进C6H11OOH的分解速率,而有利于环己醇(酮)的生成。     

An Internet-Oriented Multilayer Network Model Characterization and Robustness Analysis Method

The Internet creates multidimensional and complex relationships in terms of the composition, application and mapping of social users. Most of the previous related research has focused on the single-layer topology of physical device networks but ignored the study of service access relationships and the social structure of users on the Internet. Here, we propose a composite framework to understand how the interaction between the physical devices network, business application network, and user role network affects the robustness of the entire Internet. In this paper, a multilayer network consisting of a physical device layer, business application layer and user role layer is constructed by collecting experimental network data. We characterize the disturbance process of the entire multilayer network when a physical entity device fails by designing nodal disturbance to investigate the interactions that exist between the different network layers. Meanwhile, we analyze the characteristics of the Internet-oriented multilayer network structure and propose a heuristic multilayer network topology generation algorithm based on the initial routing topology and networking pattern, which simulates the evolution process of multilayer network topology. To further analyze the robustness of this multilayer network model, we combined a total of six target node ranking indicators including random strategy, degree centrality, betweenness centrality, closeness centrality, clustering coefficient and network constraint coefficient, performed node deletion simulations in the experimental network, and analyzed the impact of component types and interactions on the robustness of the overall multilayer network based on the maximum component change in the network. These results provide new insights into the operational processes of the Internet from a multi-domain data fusion perspective, reflecting that the coupling relationships that exist between the different interaction layers are closely linked to the robustness of multilayer networks.