Synthesis and characterization of highly fluorescent europium functionalized β-diketonate complexes

Several functionalized β-diketones and their europium complexes have been synthesized and characterized. The UV-Vis absorption, photoluminescent spectra, thermal and electrochemical properties of these complexes were investigated. The thermal analysis shows that the complexes have good thermal stability. By introducing the number of extended phenyl rings we succeeded in obtaining europium complexes with extremely high photoluminescent quantum yield (PLQY) in solution due to strong site isolation effect.     

Improving nucleation in the fabrication of high-quality 3D macro-porous copper film through the surface-modification of a polystyrene colloid-assembled template

A new approach is developed to the fabrication of high-quality three-dimensional macro-porous copper films. A highly-ordered macroporous copper film is successfully produced on a polystyrene sphere (PS) template that has been modified by sodium dodecyl sulfate (SDS). It is shown that this procedure can change a hydrophobic surface of PS template into a hydrophilic surface. The present study is devoted to the influence of the electrolyte solution transport on the nucleation process. It is demonstrated that the permeability of the electrolyte solution in the nanochannels of the PS template plays an important role in the chemical electrodeposition of high-quality macroporous copper film. The permeability is drastically enhanced in our experiment through the surface modification of the PS templates. The method could be used to homogeneously produce a large number of nucleations on a substrate, which is a key factor for the fabrication of the high-quality macroporous copper film.     

Explicit Exact Solutions for Some Nonlinear Partial Differential Equations with Nonlinear Terms of Any Order

In this paper, by introducing some appropriate transformation and with the help of symbolic computation, we study exact travelling wave solutions for the high-order modified Boussinesq equation, a single nonlinear reaction-diffusion equation and a generalized nonlinear Schrödinger equation with nonlinear terms of any order by use of the extended-tanh method. Thus, some new exact travelling-wave solutions, which contain kink-shaped solitons, bell-shaped solitons, periodic solutions, combined formal solitons, rational solutions and singular solitons for these equations, are obtained.     

Lie Symmetrical Hojman Conserved Quantity of Relativistic Mechanical System

In this paper, we study the Lie symmetrical Hojman conserved quantity of a relativistic mechanical system under general infinitesimal transformations of groups in which the time parameter is variable. The determining equation of Lie symmetry of the system is established. The theorem of the Lie symmetrical Hojman conserved quantity of the system is presented. The above results are generalization to Hojman's conclusions, in which the time parameter is not variable and the system is non-relativistic. An example is given to illustrate the application of the results in the last.     

Bandgap engineering of self-assembled InAs quantum dots with a thin AlAs barrier

We investigate the effects of a thin AlAs layer with different position and thickness on the optical properties of InAs quantum dots (QDs) by using transmission electron microscopy and photoluminescence (PL). The energy level shift of InAs QD samples is observed by introducing the thin AlAs layer without any significant loss of the QD qualities. The emission peak from InAs QDs directly grown on the 4 monolayer (ML) AlAs layer is blueshifted from that of reference sample by 219 meV with a little increase in FWHM from 42–47 meV for ground state. In contrast, InAs QDs grown under the 4 ML AlAs layer have PL peak a little redshifted to lower energy by 17 meV. This result is related to the interdiffusion of Al atom at the InAs QDs caused by the annealing effect during growing of InAs QDs on AlAs layer.     

Fringe contrast-based 3D profilometry using fringe projection

Quality-guided algorithm is a widely used method in phase unwrapping. This paper shows an accurate quality map based on fringe contrast for 3D shape measurement. Phase-shifted fringe patterns are projected onto an object surface by a programmable liquid crystal projector and recorded by a CCD camera. A wrapped phase map and a fringe contrast map are extracted from the deformed fringe patterns by the phase-shifting technique. Guided by the contrast map, the quality-guided unwrapping algorithm minimizes unwanted shadow and non-uniform surface reflectance effects and is able to retrieve a correct surface profile. Validity of the proposed method is tested on a fish model and a cutting tool specimen.     

“Hopf/homoclinic”簇放电和“SubHopf/homoclinic"簇放电之间的同步

以修正过的Morris-Lecar神经元模型为例,讨论了“Hopf/homoclinic”簇放电和“SubHopf/homoclinic"簇放电之间的同步行为.首先,分别考察了同一拓扑类型的两个耦合簇放电神经元的同步行为,发现“Hopf/homoclinic”簇放电比“SubHopf/homoclinic”簇放电达到膜电位完全同步所需要的耦合强度小,即前者比后者更容易达到膜电位完全同步.其次,对这两个不同拓扑类型的簇放电神经元的耦合同步行为进行了讨论.通过数值分析发现随着耦合强度的增加,两种不同类型的簇放电首先达到簇放电同步,然后当耦合强度足够大时甚至可以达到膜电位完全同步,并且同步后的放电类型更接近容易同步的簇放电类型,即“Hopf/homoclinic”簇放电.然而令人奇怪的是此时慢变量并没有达到完全同步,而是相位同步;慢变量之间呈现为一种线性关系.这一点和现有文献的结果截然不同.     

新型傅里叶变换光谱仪反射镜倾斜容限分析及实验

采用微机电系统微镜阵列和倾斜反射镜替代传统傅里叶变换光谱仪的动镜系统,提出一种基于微机电系统微镜阵列的新型傅里叶变换光谱仪.介绍了该光谱仪的工作原理,分析了倾斜反射镜倾斜角度的容限范围,并搭建了实验系统,进行了实验验证.理论推导表明:在近红外区域,反射镜倾角理论最大值为0.52°,光谱分辨率达到8 nm;在可见光区域,反射镜倾角理论最大值0.183°,光谱分辨率达到3 nm.选取可见光源488 nm激光器进行的实验验证结果表明:在倾角容限范围之内,光谱能准确还原;反之,光谱严重失真.最终,采用复色光源进一步实验验证了理论分析的正确性.     

利用数值再现实现彩虹全息色差评价

为了在计算机制彩色彩虹全息图输出之前定量得到再现像的色彩保真度,提出了一种采用数值再现进行色差评价的方法.首先对彩虹全息图进行了频谱分析,得到再现参量与频谱分布之间的关系;然后采用频域滤波算法实现彩色彩虹全息图数值再现,得到再现像的相对功率谱分布;最后采用CIE1976UCS均匀颜色空间对再现像色差情况进行了计算.设计了7个色块并制作了计算机制真彩色彩虹全息图,以金卤射灯作为照明光源进行了光学再现实验,给出实验结果及分析.研究证明了采用数值再现方法实现对计算彩虹全息再现像光谱分布和色差进行计算分析是一种快速经济的方法.     

抑制高阶谐波误差的随机相移条纹分析算法

高阶谐波和随机相移误差是影响条纹分析精度的主要因素。为了同时解决这两个问题,提出了基于频域滤波的迭代相移算法。该算法采用巴特沃斯低通滤波器,从频域上滤除条纹的高阶谐波分量,再运用最小二乘迭代方法从三帧随机相移条纹图像中提取相位信息。数值模拟和实验结果表明,该算法可有效地抑制由高阶谐波和随机相移引入的波纹误差,误差PV值和RMS值分别为0.368 8 rad和0.025 3 rad,其精度高于传统的三步相移算法和Wang算法。该方法适合于高精度干涉测量和三维物体表面轮廓测量。