太阳能电池陷光结构辐射特性研究

本文分析了不同微结构、电池厚度对太阳能电池光损失的影响,提出了一种新的电池陷光结构。运用时域有限差分法(FDTD)仿真了该类太阳能电池陷光结构中光传输过程,获得了不同波源入射下陷光结构电池的储能特性和光捕获特性,优化设计了最佳陷光结构并分析了其光捕获性能。     

噪声诱导的二维复时空系统的同步研究

研究了一类噪声诱导的二维复时空系统的同步问题.首先讨论了二维复Ginzburg-Laudau(CGL) 方程随时间和空间变化的时空混沌特性;其次,研究了时空噪声驱动下CGL系统的同步问题.理论上利用线性稳定性分析,得到了常数激励下CGL系统达到稳定态的临界强度;结合噪声的随机性和非零均值特性, 揭示了噪声诱导同步的机理;并从理论上和数值上分别给出了达到同步所需要的控制参数和噪声强度满足的条件,实现了两个非耦合CGL系统的完全同步.结果表明,数值模拟和理论分析有很好的一致性.     

High-power ultraviolet 278 nm laser from fourth-harmonic generation of a Nd:YAG laser in CsB3O5

We demonstrate a high-power UV 278 nm laser by fourth-harmonic generation (FHG) of a 1112 nm Nd:YAG laser in a nonlinear optical (NLO) crystal CsB3O5 (CBO) for the first time, to our best knowledge. A 30 W level diode-pumped Q-switched Nd:YAG laser at 1112 nm with beam quality factor M2=1.2 was used as the fundamental light source at a pulse width of 500 ns. With an LiB3O5 crystal, the 1112 nm laser was first frequency-doubled to 556 nm with an average output power of 13.5 W. It was then frequency doubled again in a CBO crystal to obtain the FHG output at 278 nm. The maximum average output power of the 278 nm laser is up to 1.5 W. The results demonstrated that CBO crystal is a promising NLO material for UV high-power lasers below 300 nm.     

Electron conductance and mode stability in multi-gap coupled cavity m

根据空间电荷波小信号基础理论,建立了多间隙耦合腔中单个间隙电子电导的计算模型与模式稳定性分析模型.以3间隙耦合腔为例,推导出了各个间隙电子电导的计算公式.通过理论计算与仿真模拟,研究了3间隙耦合腔中各个模式的电子电导特性,并进行了间隙中注波互作用研究与模式稳定性分析.模型计算发现:各个间隙不同模式的电子电导不同,第3间隙内电子电导受注电压及间隙距离影响最大,对整个间隙内的注波互作用及电路稳定性的影响也最大.该模型还可以用于分布作用速调管注波互作用的计算模拟.     

Unique geometric and electronic structure of CO adsorbed on Ge(100): A DFT study

CO adsorption on the Ge(100) surface has been investigated using a slab model with density functional theory implemented in SIESTA. CO was found to be exclusively adsorbed on the asymmetric dimer with C attaching on the lower Ge dimer atom. The adsorption process is barrierless. The calculated adsorption energy and vibration frequencies are comparable to previous experimental results. The crystal orbital Hamilton analysis showed that the bonding between Ge and CO is mainly attributable to the Ge 4p_z orbital overlapping with C 2 s, or with CO molecular orbitals 3σ and 4σ. The repulsive energy between adsorbed CO molecules is less than 1 kcal/mol. The diffusion barrier of CO on the Ge(100) surface is about 14 kcal/mol.     

Infrared broadband emission of bismuth–thulium co-doped lanthanum–aluminum–silica glasses

The Bi–Tm co-doped SiO₂–Al₂O₃–La₂O₃ (SAL) glasses, which exhibited a broadband near-infrared (NIR) emission was investigated by the optical absorption and photoluminescence spectra. The super broadband near-infrared emission from 1000 to 2100 nm, which covered the whole O, E, S, C and L bands, was observed in the Bi–Tm co-doped samples, as a result of the overlap of the Bi-related emission band (centered at 1270 nm) and the emission from Tm^{3+ 3}H₄→³F₄ transition (1440 nm) as well as Tm^{3+ 3}F₄→³H₆ transition (1800 nm). Relative luminescence intensity at 1270, 1440 and 1800 nm wavelength varied depending on the mixing ratio of Bi and Tm and the full-width at half-maximum (FWHM) extending from 1000 to 1600 nm could be 400 nm. These results indicated that Bi–Tm co-doped SiO₂–Al₂O₃–La₂O₃ glasses could provide potential applications in tunable lasers as well as the broadband optical amplifiers in WDM system.     

时滞对一类单位负反馈二阶振荡系统的正面作用分析

针对一类被控对象具有二阶系统标准形式的振荡系统进行了稳定性分析,讨论了闭环系统为单位负反馈时信号传输时滞对控制系统性能的影响.通过绘制和分析相对阻尼系数在不同取值区间的Nyquist曲线,得出了时滞与闭环系统稳定性的关系,并对各种情况进行了单位阶跃响应的实例仿真.仿真结果表明了分析的正确性.     

应用可见/近红外光谱技术快速检测果珍中二氧化钛的含量

为了实现快速检测果珍中的二氧化钛含量,提出了应用近红外光谱技术结合化学计量学的快速检测方法。研究采用了320份果珍样本进行光谱特性的检测,其中200个样本用来建模,120个样本进行预测。首先比较了标准正态变量校正(SNV)、变量标准化(Normalize)、多元散射校正(MSC)等6种不同的数据预处理方法对偏最小二乘法(PLS)建模预测效果的影响。然后将PLS模型与应用主成分(PC)建立的主成分-神经网络校正(PC-ANN)模型进行比较。结果表明,MSC预处理的效果最好,PLS模型的最佳主成分数为7,预测值与标准值的相关系数R2达0.900 8,预测标准误差RMSEP为0.05。PC-ANN模型预测值与标准值的R2为0.868 4,RMSEP为0.04。说明PLS模型比PC-ANN模型的预测效果好。同时本研究也说明能够应用可见/近红外技术对二氧化钛进行快速定量测定。     

1,8-萘啶衍生物分子结构与理论电子光谱

采用密度泛函理论B3LYP/6-31G(d)方法优化计算4种2,4-二甲基-7-氨基-1,8-萘啶衍生物分子结构,探讨了其分子结构与前线分子轨道、能量的关系。运用含时密度泛函理论(TD-DFT)计算了它们的气相和溶液相电子光谱,研究了溶剂模型和计算方法对理论光谱的影响。计算结果表明,4种萘啶衍生物均含离域π键,HOMO与LUMO能级差ΔE较小,且大小顺序与它们的最大吸收波长实验值变化趋势一致。理论电子光谱证实,1,8-萘啶衍生物的吸收光谱随共轭性增强逐渐红移, 最大吸收源自于HOMO→LUMO的π→π*电子跃迁。PCM-B3LYP/6-31+G(d)计算结果与实验值相比,最大吸收波长分别相差2.6,10.3,5.3和6.9 nm,能量相差0.03,0.09,0.04和0.08 eV。因此,在考虑溶剂效应条件下,采用B3LYP/6-31(d) 方法优化分子构型和TD-DFT方法获得的电子光谱与实验光谱具有一致性。     

广义H non映射的滑模变结构控制同步

基于可线性化的非线性离散变结构跟踪控制方法实现了广义H non映射混沌系统的同步 .广义H non映射的混沌吸引子比H non映射的混沌吸引子要复杂得多 ,对于保密通信来说 ,这种复杂性正是所期望的 .提出的同步方法允许参数有适当的失配程度 ,这对工程实现是非常有利的 ,理论分析和仿真结果证实了该方法的有效性