Synthesis and adsorption properties of gold nanoparticles within pores of surface‐functional porous polymer microspheres

Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004     

Electrochemical behavior of Li intercalation processes into a Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 cathode

Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO₂ structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂. Indeed, Li[Ni_0.50Mn_0.50]O₂ compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni_0.17Li_0.22Mn_0.61]O₂ and Li[Ni_0.25Li_0.17Mn₀.₅₈]O₂ compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni²⁺ and about Ni³⁺, while the oxidation state of Mn ion sustains Mn⁴⁺ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂, in which Ni ion changes between Ni²⁺ and NI⁴⁺. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process.     

数码相机原理与系统设计研究

介绍了数码相机的工作原理 ,分析了数码相机的系统结构 ,提出了设计数码相机的处理流程。典型的数码相机系统有镜头、闪光灯、光学取景器、LCD显示屏、图像数据存储扩展设备接口、图像数据传输接口、供电系统以及核心处理器等八个主要模块。数码相机的数据流向从图像传感器开始 ,止于图像数据的存储和传输。数据流的处理主要包括模数转换、光学黑电平钳位、针对镜头的边缘畸变的运算修正、坏像素处理、白平衡处理、伽马校正、色彩合成处理、边缘检测 (锐度检测 )和伪彩色检测 (伪彩色抑制 )、JPEG压缩和图像存储器等模块     

SYNTHESIS OF LIGHT OLEFINS FROM SYNGAS VIA DIMETHYLETHR——A NEW TECHNIQUE PROCESS

A new route named as SDTO method for the synthesis of lightolefins from syngas has been proposed.That is to convert syngas todimethylether and then to convert dimethylether to light olefins.The catalystsfor the two conversion reactions have been developed.For the first reaction,the catulySt was synthesized by the combination of methanol synthesis catalystwith γ-Al_2O_3or zeolites which possesses both metallic and acidic functions.Thecatalyst for the second reaction was modified SAPO-34 molecular sieve.Thevariables of the reactions have also been investigated.The results from theserial connection of the two conversion steps without any separation show thatthe yield of C_2~-C_4~- olefins Could be>100g/(m~3 syngas).     

金属表面生成氧化膜在电解质中的电位

测量金属表面生成氧化膜在电解质中的电位时,金属/氧化膜/电解质/参比电极构成了多电极体系,其中包括3个电池,由3个电池之间的关系、电池过程中所有的电化学反应、电荷传输步骤和化学反应步骤,导出电位的普遍适用的公式: E=E_a⁰+sum from s=1 to 3|η_t,s|-1/(ne)v₇ΔG₇, E=E_c⁰-sum from s=4 to 6|η_t,s|+1/(ne)v₈ΔG₈.当金属/氧化膜/电解质电池受到不同的步骤控制时,可以得到不同的简化公式.     

微微秒自动调谐参量激光的研究

采用一对MgO:LiNbO_3角度调谐覆盖了红近外波段0.7～2.2μm,并配以自动波长扫描。文中分析了影响脉冲宽度与线宽的因素,与实验结果相吻合。脉宽<30ps,线宽～1nm(简并波长附近～10nm),单脉冲峰功率达MW级,参量光总能量转换效率达5.4％。     

随机删失下乘积限过程和累积失效率过程振动模的局部渐近性

在随机删失下研究了乘积限过程和累积失效率过程的振动模的局部性质 .给出了这两个过程的振动模的重对数律 ,并应用这些结果得到了几种核密度估计和Bahadur-Kiefer过程的精确收敛速度     

Transfer matrix approach of vibration isolation analysis of periodic composite structure

The transmission properties of elastic waves propagating in a three-dimensional composite structure embedded periodically with spherical inclusions are analyzed by the transfer matrix method in this paper. Firstly, the periodic composite structures are divided into many layers, the transfer matrix of monolayer structure is deduced by the wave equations, and the transfer matrix of the entire structure is obtained in the case of boundary conditions of displacement and stress continuity between layers. Then, the effective impedance of the structure is analyzed to calculate its reflectivity and transmissivity of vibration isolation. Finally, numerical simulation is carried out; the experiment results validate the accuracy and feasibility of the method adopted in the paper and some useful conclusions are obtained. Project (No. 50075029) supported by the National Natural Science Foundation of China.     

不等式约束优化问题的一个势函数

基于Carroll(1961)建立的罚函数，本文给出了不等式约束优化问题的一个势函数，并且讨论了该函数的性质．最后证明了在此基础上建立的对偶算法具有Q-线性收敛性．