配位化学的创始与现代化

本文扼要介绍了韦尔纳配位理论的第一篇文章的内容，讨论了配位化学的发展和现代化。配合物稳定性决定于多种作用力与组分间的互补性和拓扑约束性。     

Triboelectric pulsed direct current for self-powered sterilization of cellulose fiber

A variety of liquid energy exists in papermaking engineering and has not yet been developed and utilized. In addition, for the papermaking industry, the presence of slime can seriously affect the quality of the finished paper and can lead to paper breaking. The current slime control strategies cannot completely solve the problem and also have some low toxicity. In this study, a method of self-powered sterilization of cellulose fibers by using triboelectric pulsed direct current is reported. A liquid–solid triboelectric nanogenerator (L–S TENG) was used to convert the liquid energy of nanocellulose suspension into electrical energy and convert this electrical energy into pulsed direct current for self-powered sterilization of cellulose fiber. A hydrophobic coating material is used as solid triboelectric material and electrode for sterilization. Driven by L–S TENG, the electrodes exhibited an excellent sterilization rate against four microorganisms including Escherichia coli, Aspergillus niger, Candida albicans, and Klebsiella pneumoniae, which from slime in the papermaking industry. This study could provide a basic research theory for liquid energy harvesting in the papermaking industry, and also provide a new strategy for pulp sterilization.

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Grape tissue-based electrochemical sensor for the determination of hydrogen peroxide

The use of grape tissue as a source of catalase for the determination of hydrogen peroxide is reported. A slice of grape tissue attached to the membrane of a Clark-type oxgen sensor was used to monitor the oxidation of hydrogen peroxide by catalase. At the steady state, the sensor responds linearly to hydrogen peroxide in the concentration range 1 × 10^?5–5 × 10^?4 M. The response time (T₉₀) was of the order of 1 min for this sensor. No interference was observed from ethanol, amino acids, glucose and lactic acid. The long-term stability of the grape tissue sensor was much better than previously reported immobilized enzyme and liver tissue-based hydrogen peroxide sensors.     

Preparation and study on the novel solid inclusion complex of ciprofloxacin with HP-beta-cyclodextrin

The interaction of ciprofloxacin with HP-beta-cyclodextrin (HP-beta-CD) has been studied by several analytical techniques, including 1H nuclear magnetic resonance (NMR), 13C NMR, fluorescence spectra, infrared spectroscopy, thermal analyzer and scanning electron microscope. In this paper, solid inclusion complex of ciprofloxacin with HP-beta-CD was synthesized by the coprecipitation method. In addition, the characterization of the inclusion complex has been proved by fluorimetry, infrared, differential scanning calorimetry and one-dimensional (1D), 2D NMR. The experimental results confirmed the existence of 1:1 inclusion complex of ciprofloxacin with HP-beta-CD. The formation constant of complex was determined by fluorescence method and 1H NMR. Spacial configuration of complex has been proposed on two-dimensional NMR technique.     

The Color Reaction of Mercury(II) with the New Reagent 2-Methylthiophenyldiazoaminoazobenzene and Its Application

A new and very sensitive and selective chromogenic reagent, 2-methylthiophenyldiazoaminoa-zobenzene (MTDAA), was synthesized and studied in detail for the determination of trace mercury(II) in water samples. The method is based on the color reaction between MTDAA and mercury(II). It was found that mercury(II) reacts with MTDAA in Na₂B₄O₇-NaOH buffer solution (pH = 10.0) to form 1 : 2 red complexes; these show maximum absorption at 520 nm. Beer’s law is obeyed in 0–15 µg of mercury(II) in 25 mL of solution. The apparent molar absorptivity of the complex is 1.33 × 10⁵ L/(mol cm); its limit of quantification, limit of detection, and relative standard deviation are 0.75 ng/mL, 0.27 ng/mL, and 1.0%, respectively, giving better sensitivity. The influence of the reaction variables and the effect of interfering ions are reported; most of the metal ions in water samples can be tolerated in considerable amounts. Only a few ions can interfere with the determination of trace mercury(II), but these can be eliminated by prior extraction. The proposed method is sensitive, simple, and rapid. It has been applied to the determination of trace mercury(II) in water samples with satisfactory results.__________From Zhurnal Analiticheskoi Khimii, Vol. 60, No. 7, 2005, pp. 703–706.Original English Text Copyright © 2005 by Guo, Din, Tian, Liu, Chang, Meng.The text was submitted by the authors in English.     

不同光滑度立方体氧化铁对液晶电光性能的改善

向列相液晶被广泛应用于液晶显示中,但是由于杂质的存在,会导致液晶的驱动电压变大,增加能耗。 为了降低阈值电压和饱和电压,通常向液晶中添加纳米颗粒来提高电光性能。 本文利用水热法制备了表面粗糙和光滑的两种立方体Fe₂O₃纳米颗粒,其形貌均匀,尺寸约550 nm。 将二者分别掺杂到向列相液晶E7中,结果表明,粗糙立方体Fe₂O₃/E7复合体系具有比光滑立方体Fe₂O₃/E7复合体系和向列相液晶E7更优的电光性能,且在掺杂质量分数为0.4%时,其电光性能达到最优,阈值电压和饱和电压分别降低9.9%和11.6%,对比度增大80%,响应时间降低至6.0 ms。 这归因于粗糙立方体Fe₂O₃具有足够的表面积和表面所带电荷更多,所以会更易吸附体系中的杂质离子和减弱杂质离子的屏蔽作用,从而提高了电光性能。     

SYNTHESIS AND PROPERTIES OF SULFONATED POLY（ARYLENE ETHER） CONTAINING TRIPHENYL METHANE MOIETIES FROM ISOCYNATE MASKED BISPHENOL

A novel sulfonated poly（arylene ether） containing triphenylmethane moieties was synthesized by the sulfonation of a designed parent polymer using chlorosulfonic acid as sulfonation agent. The sulfonation took place at the para position of the pendant phenyl rings because of the specially designed parent polymer. The position and degree of sulfonation were characterized by ^1H-NMR and elemental analysis. The sulfonated polymers are highly soluble in common organic solvents, such as dimethylsulfoxide, N,N＇-dimethylacetamide, dimethylformamide, ethylene glycol monomethyl ether, and can be readily cast into tough and smooth films from solutions. The films showed good thermal and hydrolysis stabilities. Moreover, Fenton＇s reagent test revealed that the films exhibited superior stability to oxidation. The proton conductivities of the films were comparable with Nation 117 under same conditions. The membrane electrode assembly （MEA） prepared with the asmade film （706 EW, 100 μm dry thickness） shows better cell performance than Nation 115-MEA in the whole current density range.     

硬木热解过程中颗粒内部二次反应的数值研究Ⅱ.数值模拟结果

为了研究生物质（硬木）热解过程中颗粒内部的二次反应，对流化床环境下单颗粒生物质热解模型进行了求解。计算针对典型大颗粒和典型小颗粒在流化床反应器反应条件下的热解过程，对不同大小颗粒内部各种产物的生成、消耗、积累以及逃逸行为进行了定量描述。计算结果表明：对于直径为2mm的小颗粒，颗粒内二次裂解的份额可以忽略，但是对于直径10mm的大颗粒，热争过程中有超过20%的一次焦油参加了颗粒内部二次反应，颗粒内二次裂解显著地改变了热解产物分布，改变了热解产物的品质。     

Synthesis, crystal structure and magnetic property of a new 1D molecular material [1-(4′-chlorobenzyl)-4-aminopyridinium](+) bis(maleonitriledithiolato)nickel(-)

A new ion-pair complex, [1-(4′-chlorobenzyl)-4-aminopyridinium](+)bis(maleonitrile-dithiolato)nickel(−),[ClbzPyNH₂][Ni(mnt)₂] (1), has been prepared and characterized. X-ray single crystal structure conforms that the Ni(mnt)₂⁻ anions and [ClbzPyNH₂]⁺ cations of 1 form completely segregated uniform stacking columns with the Ni?Ni distance 3.944 Å in the Ni(mnt)₂⁻ stacking column. The temperature dependence of the magnetic susceptibility reveals that 1 undergoes a magnetic transition, and exhibits ferromagnetic interaction in the high-temperature phase and spin gap system in the low-temperature phase.