TiO_2/SnO_2复合光催化剂的制备及光催化降解敌敌畏

以 Sn Cl4· Ti( OBu) 4、氨水、乙醇为原料 ,采用活性层包覆法 ,制备出 Ti O2 / Sn O2 复合光催化剂 ,并用IR、XRD、TEM和 BET等手段对样品进行了表征 .研究其对有机磷农药敌敌畏的光催化降解效果 ,与单一半导体催化剂 Sn O2 、Ti O2 做了简单对比 .结果表明 :所制 Ti O2 / Sn O2 样品为包覆型结构 ,由锐钛矿型 Ti O2 金红石型 Sn O2 组成 ,与 Sn O2 及 Ti O2 晶体粉末相比所制 Ti O2 / Sn O2 包覆粒子光催化活性得到明显提高 .     

Novel CuS nanofibers using organogel as a template: controlled by binding sites

A new cholesterol organogelator 1 was synthesized, which was confirmed as an effective gelator for various organic solvents and could self-assemble into network fibers in some organic solvents. Moreover, gelator 1 could act as templates for the synthesis of various CuS nanofibers with different helical pitches. For example, when H(2)S was used as the sulfur source, straight and bending helical CuS nanofibers with a pitch of 100-200 nm could be fabricated in butyl acetate and benzene-butanol gel systems, respectively, while bending CuS nanofibers with a similar helical pitch (ca. 50 nm) could be obtained when thioacetamide was used as the sulfur source in both gel systems. It was first found that the morphologies of inorganic nanofibers could be controlled by the binding sites between the inorganic precursor and the organogel.     

Clockwise helical stacking of triphenylbenzene-based organogelator induced by peripheral chirality

We report on the synthesis and self-assembly of a new discotic organogelator based on π-conjugated triphenylbenzene with three peripheral chiral substituents. It is found that the introduction of chiral groups to the C₃-symmetric molecule led to a hexagonal columnar chiral stacking of the molecules in a clockwise direction in the organogel fibers. And the fluorescent emission of the gel decreased significantly compared to the monomer state at the same concentration, as a result of the aggregation of the nonplanar triphenylbenzene core in the gel phase.     

Ag/ZnO heterostructure nanocrystals: synthesis, characterization, and photocatalysis

A high yield of the dimer-type heterostructure of Ag/ZnO nanocrystals with different Ag contents is successfully prepared through a simple solvothermal method in the absence of surfactants. The samples are characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-vis spectroscopy, and IR spectroscopy. The results show that all samples are composed of metallic Ag and ZnO; Ag nanoparticles locate on the surface of ZnO nanorods; the binding energy of Ag 3d(5/2) for the Ag/ZnO sample with a Ag content of 5.0 atom % shifts remarkably to the lower binding energy compared with the corresponding value of pure metallic Ag because of the interaction between Ag and ZnO nanocrystals; the concentration of oxygen vacancy for the as-synthesized samples varies with the increasing Ag content, and the Ag/ZnO sample with a Ag content of 5.0 atom % has the largest density of oxygen vacancy. In addition, the relationship between their structure and photocatalytic property is investigated in detail. It is found that the photocatalytic property is closely related to its structure, such as heterostructure, oxygen defect, and crystallinity. The presence of metallic Ag nanoparticles and oxygen vacancy on the surface of ZnO nanorods promotes the separation of photogenerated electron-hole pairs and thus enhances the photocatalytic activity.     

Synthesis of linear monodisperse vinylene-linked phenothiazine oligomers

A series of linear monodisperse vinylene-linked phenothiazine oligomers have been synthesized by alternate Heck reaction and Wittig reaction in good yields. It was found that their absorption and fluorescence emission bands red-shifted with increasing phenothiazine units due to extending of the conjugated degree. The fluorescent quantum yield increased from OPTZ1 to OPTZ6, and the Φ_F of OPTZ6 was close to phenothiazine-based polymers.     

目标检测与跟踪方法在自动跟踪装置中的应用

介绍了一种应用于自动跟踪装置上的运动背景下目标检测与跟踪的方法,采用仿射模型作背景运动估计进行检测以及mean-shift算法跟踪目标,并将该方法应用到一套自动跟踪系统实验平台上。     

弹性蛋白酶发酵过程中发酵液紫外吸收光谱的研究

研究了弹性蛋白酶发酵过程中发酵液紫外吸收光谱的变化,分析比较了发酵液吸收光谱的变化与细菌生长以及发酵产酶过程之间的联系.结果表明,弹性蛋白酶发酵液紫外吸收光谱的变化与菌体生长以及弹性蛋白产酶过程存在密切联系.紫外吸收光谱技术可以用于检测发酵液中有机氮源消耗以及弹性蛋白酶的产生等动态变化,研究为检测弹性蛋白酶发酵的动态过程提供一种比较新颖的方法,为建立紫外光谱技术在线检测发酵过程奠定了基础.     

High Electrical-to-Green Efficiency 123 W Average-Power Quasicontinuous-Wave Laser at 532 nm in Compact Design

We present an efficient high-power quasicontinuous-wave (QCW) all-solid-state laser at 532 nm with a simple and compact symmetrical resonator. We design a stable green laser at 532 nm with an average power of 123 W and a repetition rate of 10 kHz by combining a single side-pumped Nd:YAG laser module with a type II LBO crystal for intracavity frequency doubling. The corresponding electrical-to-green conversion efficiency is 12.5%. To the best of our knowledge, this is the highest electrical-to-green efficiency in 532 nm lasers with above 100 W output power ever reported. The pulse width is 62 ns at 123 W, so the peak power is calculated up to 198.4 kW. Such a compact and efficient resonator is promising for integration into laser-application systems.     

In Situ X-Ray Diffraction Study on Surface Melting of Bi Nanoparticles Embedded in a Si02 Matrix

Bi nanoparticles embedded in a Si02 matrix were prepared via the high energy ball milling method. The melting behavior of Bi nanopartieles was studied by means of differential scanning calorimetry （DSC） arid high- temperature in situ X-ray diffraction （XRD）. DSC cannot distinguish the surface melting from ＇bulk＇ melting of the Bi nanoparticles. The XRD intensity of the Bi nanopartieles decreases progressively during the in situ heating process. The variation in the normalized integrated XRD intensity versus temperature is related to the average grain size of Bi nanoparticles. Considering the effects of temperature on Debye Waller factor and Lorentz-polarization factor, we discuss the XRD results in accordance with surface melting. Our results show that the in situ XRD technique is effective to explore the surface melting of nanoparticles.     

一种无参考型模糊图像质量评价方法

图像的边缘信息是人眼观察和识别物体的重要特征,根据模糊图像相对于清晰图像其边缘特征发生较大变化的特点,提出了一种基于边缘锐度的无参考模糊图像质量评价方法。首先,通过文中所示方法寻找图像中的所有阶跃边缘;其次,根据一些原则选择合适的部分边缘;最终,计算这些合适边缘的锐利程度作为图像的模糊度评价依据。实验结果表明,该方法相比于全参考模型SSIM能够更好地评价高斯模糊、离焦模糊等模糊类型图像,与主观评价结构相关性强,更符合人眼视觉系统特性,并且易于实现。