核固红分光光度法测定红霉素

在弱酸条件下,用二次石英蒸馏水为溶剂,核固红和红霉素在常温下可以反应形成稳定的离子缔合物,导致吸收光谱改变,且吸光度(以试剂空白作参比)与红霉素的浓度成正比.于535nm测定其吸光度得到ε=2.33×104L/mol·cm,红霉素的浓度在0.0009-0.050mg/mL范围内服从Beer定律,基于此,我们建立了一种测定红霉素的新方法.方法的检出限为0.10μg/mL.实验表明:该法简便可靠,重现性和选择性好,可用于红毒素肠溶片和红毒紊片中红霉素含量的测定.     

费菜不同部位氨基酸组成及含量分析

采用氨基酸自动分析仪检测并比较费菜根、茎、叶和果4个部位17种氨基酸的组成与含量,并对其中必需氨基酸的含量进行分析.结果表明:费菜含有丰富的氨基酸种类,根和果中含有所测定的全部17种氨基酸,叶片和茎中含16种氨基酸,其总氨基酸含量为样品干重4.44％-7.20％,不同部位氨基酸含量果＞叶＞茎＞根;4个部位均含有实验所测定的7种人体必需氨基酸,其中,叶片作为费菜主要的食用部位,必需氨基酸与总氨基酸的比值(EAA/TAA)为34.10％,必须氨基酸与非必需氨基酸的比例(EAA/NEAA)为51.74％,与食物蛋白氨基酸理想比例接近,必需氨基酸配比较为合理,具有较好的营养价值.     

Modulation of electroencephalograph activity by manual acupuncture stimulation in healthy subjects:An autoregressive spectral analysis

To investigate whether and how manual acupuncture(MA) modulates brain activities,we design an experiment where acupuncture at acupoint ST36 of the right leg is used to obtain electroencephalograph(EEG) signals in healthy subjects.We adopt the autoregressive(AR) Burg method to estimate the power spectrum of EEG signals and analyze the relative powers in delta(0 Hz-4 Hz),theta(4 Hz-8 Hz),alpha(8 Hz-13 Hz),and beta(13 Hz-30 Hz) bands.Our results show that MA at ST36 can significantly increase the EEG slow wave relative power(delta band) and reduce the fast wave relative powers(alpha and beta bands),while there are no statistical differences in theta band relative power between different acupuncture states.In order to quantify the ratio of slow to fast wave EEG activity,we compute the power ratio index.It is found that the MA can significantly increase the power ratio index,especially in frontal and central lobes.All the results highlight the modulation of brain activities with MA and may provide potential help for the clinical use of acupuncture.The proposed quantitative method of acupuncture signals may be further used to make MA more standardized.     

分数阶Chua's系统错位同步无感模块化电路实现及应用

基于分数阶混沌系统稳定性理论, 设计高效的非线性控制器, 实现初始值不同的两个分数阶Chua's系统错位投影同步. 根据分数阶复频域近似方法, 提出分数阶系统的等效电路, 实现分数阶Chua's系统错位投影同步的无感模块化电路. 最后,利用改进的混沌掩盖通信原理, 将以上同步方案应用于混沌保密通信中, 在发送端使用分数阶混沌序列对有用信号加密传送, 从接收端可以无失真地恢复出有用信号. 数值仿真与电路仿真证实了提出方案的可行性. 关键词： 分数阶Chua's系统 错位投影同步 无感模块化电路 保密通信     

182Os 核yrast带相继SU(3)–U(5)–SU(3)结构相变势能曲面的一种可能理解

基于联合实施微观相互作用玻色子模型的最大F旋方案 (sdIBM-F_max)与γ射线能量-自旋曲线 (γ-ray energy over spin curves, E-GOS)方案, 成功描述了¹⁸²Os核yrast带相继的SU(3)–U(5)–SU(3)结构相变, 由于缺少直观解释而显得抽象. 本文借助微观sdIBM-F_max的微观参数与Bohr哈密顿量的势能曲面方程之间存在的泛函关系, 几何地给出了对这种相继相变途径的另外一种可能理解; 并阐述了在完全变形核的高角动量态中, 由于量子效应在高激发态与低激发态之间生成高简并的临界区, 提供了γ振动能量会变得低于转动能量的一个可能途径, 从而实现了SU(3)–U(5)的相变. 关键词： yrast带结构演化 势能曲面 相变临界区 182Os核')" href="#">¹⁸²Os核     

基于干涉原理的双图像加密系统

提出一种新的虚拟光学加密方法,该方法分3个步骤将两幅图像隐藏于3个随机相位板中。将两幅图像分别作为相位和幅度信息隐藏于一个复数场中,利用随机相位板作为参考光,并采用数字全息术将该复数场转换成平稳随机白噪声,利用干涉加密原理进一步将此白噪声储存于2个随机相位板中,从而将两幅图像信息隐藏于3个纯随机相位板中。该方法原理简单,无需进行迭代操作。计算机模拟结果显示:任何一个密钥错误,均无法得到原始图像的任何信息。同时,解密过程对系统中距离及波长等参数非常敏感,较大地提升了系统的安全性。     

空间站快速充电事件的机理研究

空间站等大型航天器由于采用高压太阳电池阵而引发的 带电问题成为近年来航天器带电研究领域的热点问题. 近年来观测到国际空间站(ISS)在出地影瞬间产生的"快速带电"事件 (也称"异常带电") , 再度引起了对低轨道航天器充电效应的深入研究. "快速带电"事件的特征为, 集中出现在出地影的瞬间, 在几秒内快速上升到较高电位(30—70 V), 然后在几十秒时间内缓慢衰降, 相对高压电池阵本身引起的结构体带电(称为"正常带电", 一般在30 V以下)严重得多. 目前国际上对"快速带电"的研究尚不充分. 本文在Furguson等人机理研究工作的基础上, 首次建立了描述"快速带电"事件的物理模型, 定量揭示了其充电过程的主要机理. 根据该模型对国际空间站的"快速带电"进行计算, 结果与观测到的典型充电脉冲符合, 模型预测的快速带电事件的统计规律也与观测结果基本一致. 关键词： 表面充电 等离子体 空间站 高压太阳电池阵     

Pigment identification and decoration analysis of a 5th century Chinese lacquer painting screen: a micro‐Raman and FTIR study

To investigate the pigments and decoration applied to a wood‐based lacquer painting screen from the tomb of Si‐ma Jin‐long, Shanxi Province, central China, made by Chinese craftsmen in the 5th century, a combination of micro‐Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), wavelength dispersive X‐ray fluorescence (WDXRF), and microscopic examination was used. The obtained results are as follows: (1) the black, yellow, and red colors are identified as carbon black, orpiment and realgar, and cinnabar, respectively, by using micro‐Raman spectroscopy. The FTIR result shows that the white pigment filled in the leaves is not lead white, as assumed in the literature, but gypsum. Whether lead white was used at other locations remains unanswered and requires more samples for further work; (2) the thickness of each discernable pigment layer, as observed under the microscope, is approximately equal and the differences among them are small, suggesting a superfine painting skill; besides, a noticeable smooth interface between wood and the red grounding substance indicates that a polishing process might have been applied before the painting; (3) the red background was proved to contain cinnabar, but further FTIR analyses found no evidence for the presence of Chinese wood oil; and (4) the most interesting finding, rarely reported before, is that white grains of different sizes are found in both pigment layers and the grounding substance, which are perhaps an intentional addition. Further, in situ XRF and Raman analyses indicate that they are sourced from hydroxyapatite, coming probably from the intentional addition of animal bone ash to the lacquer. But how such a process could be finished and what purpose it served have not yet been answered. Copyright © 2009 John Wiley & Sons, Ltd.     

广西大风子中2个新木脂素的NMR研究

从广西大风子的皮中分离得到两个新木脂素1和2,并通过高分辨质谱和核磁共振确定了其结构. 利用多种二维核磁共振技术,包括HSQC, HMBC, DQF-COSY 和NOESY谱,对其碳氢信号进行了全归属. 毛细管电泳分析显示1和2均为外消旋体.     

双轴晶体会聚偏光干涉的理论与实验研究

晶体会聚偏光干涉图包含了晶体特性的许多信息,建立偏光干涉图的定量分析方法可以使这些信息得到充分利用。基于双轴晶体折射时满足的波矢关系,导出了两折射光波相位差的精确计算公式。分析了光波在各界面折射时偏振态的变化,提出了会聚偏光干涉合成振幅的计算方法。针对任意取向的双轴晶体,计算了完整的偏光干涉图,反映了相位分布决定等色线、振幅分布决定消光影的规律。用数字图像模似了干涉图,并讨论了干涉图的变化情况。对4块不同取向的KTP晶片进行实验,实验干涉图与理论干涉图的特征完全一致,两者仔细对比可判断现有KTP晶体色散方程的优劣。