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101.
Zhang J Leitus G Ben-David Y Milstein D 《Journal of the American Chemical Society》2005,127(31):10840-10841
An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H(2) under neutral conditions. 相似文献
102.
Kost D Peor N Sod-Moriah G Sharabi Y Durocher DT Raban M 《The Journal of organic chemistry》2002,67(20):6938-6943
Trans-1-acceptor-2-donor-substituted cyclohexanes (1), as well as their 4- (or 5-)methyl-substituted homologues (2), have been prepared and are shown to form intramolecular charge-transfer (donor-acceptor) complexes. These weak complexes are turned on and off by the chair-chair interconversion of the cyclohexane ring. The CT absorptions have been measured and the equilibrium constants for the ring reversal have been determined by UV/vis spectroscopy at 298 K, as well as by NMR spectroscopy at two temperatures: at 183 K, by direct comparison of signals due to the two chair conformations, and at 300 K, by comparison of calculated and measured widths of the alpha-proton signals. The Gibbs free energies assigned to the donor-acceptor interactions range between 0 and -1 kcal mol(-1). A crystal structure of one of the complexes (1b) confirms the intramolecular donor-acceptor alignment and interaction. The regioisomers of the methyl-substituted complexes were characterized by NOE interaction between the methyl and an alpha-proton cis to it. 相似文献
103.
104.
Alavi-Harati A Alexopoulos T Arenton M Arisaka K Averitte S Barker AR Bellantoni L Bellavance A Belz J Ben-David R Bergman DR Blucher E Bock GJ Bown C Bright S Cheu E Childress S Coleman R Corcoran MD Corti G Cox B Crisler MB Erwin AR Ford R Glazov A Golossanov A Graham G Graham J Hagan K Halkiadakis E Hamm J Hanagaki K Hidaka S Hsiung YB Jejer V Jensen DA Kessler R Kobrak HG LaDue J Lath A Ledovskoy A McBride PL Mikelsons P Monnier E Nakaya T Nelson KS Nguyen H O'Dell V Pang M Pordes R 《Physical review letters》2001,87(7):071801
We report on the analysis of the rare decay K(L)-->mu(+)mu(-)gamma the 1997 data from the KTeV experiment at Fermilab. A total of 9327 candidate events are observed with 2.4% background, representing a factor of 40 increase in statistics over the current world sample. We find that B(K(L)-->mu(+)mu(-)gamma) = (3.62 +/- 0.04(stat) +/- 0.08(syst)) x 10(-7). The form factor parameter alpha(K*) is measured to be alpha(K*) = -0.160(+0.026)(-0.028). In addition, we make the first measurement of the parameter alpha from the D'Ambrosio-Isidori-Portolés form factor, finding alpha = -1.54 +/- 0.10. In that model, this alpha measurement limits the Cabibbo-Kobayashi-Maskawa parameter rho>-0.2. 相似文献
105.
106.
Alavi-Harati A Albuquerque IF Alexopoulos T Arenton M Arisaka K Averitte S Barker AR Bellantoni L Bellavance A Belz J Ben-David R Bergman DR Blucher E Bock GJ Bown C Bright S Cheu E Childress S Coleman R Corcoran MD Corti G Cox B Crisler MB Erwin AR Ford R Glazov A 《Physical review letters》2000,84(3):408-411
We report the first observation of a manifestly CP violating effect in the K(L)-->pi(+)pi(-)e(+)e(-) decay mode. A large asymmetry was observed in the distribution of these decays in the CP-odd and T-odd angle straight phi between the decay planes of the e(+)e(-) and pi(+)pi(-) pairs in the K(L) center of mass system. After acceptance corrections, the overall asymmetry is found to be [13.6+/-2. 5(stat)+/-1.2(syst)]%. This is the largest CP-violating effect yet observed when integrating over the entire phase space of a mode and the first such effect observed in an angular variable. 相似文献
107.
Alavi-Harati A Alexopoulos T Arenton M Arisaka K Averitte S Barker AR Bellantoni L Bellavance A Belz J Ben-David R Bergman DR Blucher E Bock GJ Bown C Bright S Cheu E Childress S Coleman R Corcoran MD Corti G Cox B Crisler MB Erwin AR Ford R Glazov A Golossanov A 《Physical review letters》2000,84(12):2593-2597
We present results of a search for a new form of hadronic matter, a six-quark, dibaryon state called the H0, a state predicted to exist in several theoretical models. Analyzing data collected by experiment E799-II at Fermilab, we searched for the decay H0-->Lambdappi(-) and found no candidate events. We place an upper limit on [B(H0-->Lambdappi(-))dsigma(H)/dOmega]/(dsigma(Xi)/dOmega) and, in the context of published models, exclude the region of lightly bound mass states just below the LambdaLambda mass threshold, 2.194相似文献
108.
Alavi-Harati A Alexopoulos T Arenton M Arisaka K Averitte S Barker AR Bellantoni L Bellavance A Belz J Ben-David R Bergman DR Blucher E Bock GJ Bown C Bright S Cheu E Childress S Coleman R Corcoran MD Corti G Cox B Crisler MB Erwin AR Ford R Glazov A Golossanov A Graham G Graham J Hagan K Halkiadakis E Hamm J Hanagaki K Hidaka S Hsiung YB Jejer V Jensen DA Kessler R Kobrak HG LaDue J Lath A Ledovskoy A McBride PL Mikelsons P Monnier E Nakaya T Nelson KS Nguyen H O'Dell V Pang M Pordes R 《Physical review letters》2001,86(15):3239-3243
We have studied the rare weak radiative hyperon decay Xi degrees -->Sigma degrees gamma in the KTeV experiment at Fermilab. We have identified 4045 signal events over a background of 804 events. The dominant Xi degrees -->Lambdapi degrees decay, which was used for normalization, is the only important background source. An analysis of the acceptance of both modes yields a branching ratio of B(Xi degrees -->Sigma degrees gamma)/B(Xi degrees -->Lambdapi degrees ) = (3.34+/-0.05+/-0.09)x10(-3). By analyzing the final state decay distributions, we have also determined that the Sigma degrees emission asymmetry parameter for this decay is alpha(XiSigma) = -0.63+/-0.09. 相似文献
109.
Little is known about bromine trifluoride in organic chemistry. Under the right conditions, it can be a useful tool and generate a new and unprecedented chemistry. Thus, when reacted with oxime methyl ethers of alpha-ketoesters, BrF3 was able to convert the oxime group into a CF2 group and through a new type of rearrangement cause a shift of the carboxylate group to the nitrogen atom. The novel structure of the alpha,alpha-difluorocarbamate was also proven by 15N NMR as demonstrated for compounds 3, 8, 9, 12, 15, and 18. Another novel "double rearrangement" was observed during the formation of 19. Dynamic 19F NMR experiments indicate a high nitrogen inversion-rotation (NIR) barrier for these novel carbamates of about 12.5 kcal/mol. 相似文献
110.