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排序方式: 共有187条查询结果,搜索用时 78 毫秒
91.
92.
Yu?Liang Fukai?Zhao Qingli?Wang Yunyin?NiuEmail author 《Journal of chemical crystallography》2011,41(6):763-766
Abstract
A novel coordinated polymer [HgI2(4-bped)2] was synthesized through the reaction of bis(4-pyridyl)ethylene diamine and HgI2 in mixed MeOH–THF (5:2). The crystal structural analysis indicated that the complex crystallized in a monoclinic space group P21/c, a = 10.8392(12), b = 19.841(2), c = 8.8279(10), β = 95.452(2), V = 1889.9(4) ?3, Z = 4. The complex possessed a novel three-dimensional supramolecular framework formed by hydrogen bonds among repeating [HgI2(4-bped)]2 dimeric units. 相似文献93.
94.
Hiratsuka H Horiuchi H Furukawa Y Watanabe H Ishihara A Okutsu T Tobita S Yoshinaga T Shinohara A Tokitoh N Oba M Nishiyama K 《The journal of physical chemistry. A》2006,110(11):3868-3874
Photophysical and photochemical processes of 9-methyl- and 9-phenyl-9,10-dihydro-9-silaphenanthrene derivatives have been studied at room temperature and 77 K in comparison with the carbon analogue, 9,10-dihydrophenanthrene. These 9,10-dihydro-9-silaphenanthrene derivatives show smaller fluorescence quantum yield and remarkably larger Stokes shifts than those of the carbon analogue. In contrast, their phosphorescence quantum yields are two times larger than those of the carbon analogue, although the absolute value is not so large (approximately 0.1). Reaction products and intermediates produced by the 266 nm light photolysis have been studied, and it has been confirmed that 9-methyl- and 9-phenyl-9-silaphenanthrenes have been photochemically formed in methylcyclohexane at 77 K, in addition to the formation of radical cations of 9,10-dihydro-9-silaphenanthrene derivatives and the carbon-centered radical: 9-hydro-9-silaphenanthrenyl radical. 相似文献
95.
The isomeric states and intermolecular packing of tris(8-hydroxyquinoline) aluminum(III) (Alq(3)) in the alpha-, gamma-, and delta-crystalline forms and in the amorphous state, which are important for understanding the light-emitting and electron-transport properties, have been analyzed by CP/MAS (13)C NMR. This simple NMR experiment shows that the isomeric state of alpha- and amorphous Alq(3) is meridional, whereas that of gamma- and delta-Alq(3) is facial. In the amorphous Alq(3), the inclusion of facial isomers has been under debate. Our experiments show that meridional isomers are dominant in the amorphous Alq(3), although the existence of facial isomers cannot be completely denied. The local structure of amorphous Alq(3) is similar to that of alpha-Alq(3) and is significantly different from those of gamma- and delta-Alq(3). Among these Alq(3) samples, the effect of intermolecular interaction is not found only for gamma-Alq(3). This finding can explain the good solvent solubility of gamma-Alq(3), compared with the other crystalline forms. It is also shown that the structures are locally disordered not only for amorphous Alq(3) but also for alpha-Alq(3), although clear X-ray diffraction peaks are observed for alpha-Alq(3). In contrast, the local structures of gamma- and delta-Alq(3) are well defined. A clear relation is found between the spectral patterns of CP/MAS (13)C NMR and the fluorescence wavelengths; the samples, which consist of facial isomers, show blue-shifted fluorescence compared with those of meridionals. 相似文献
96.
Citridone D was isolated from the culture broth of Penicillium sp. FKI-1938 by solvent extraction, silica gel column chromatography and HPLC. The structure of citridone D was elucidated by spectroscopic analysis including NMR analysis. Citridone D was found to have a novel phenylfuropyridine skeleton different from those of other citridones. Citridone D potentiated miconazole activity against Candida albicans. 相似文献
97.
98.
Hitoshi Tamiaki Kazuhiro Fukai Hideki Shimazu Sunao Shoji 《Photochemistry and photobiology》2014,90(1):121-128
Zinc complex of pyropheophorbide‐b, a derivative of chlorophyll‐b, was covalently dimerized through ethylene glycol diester. The synthetic homo‐dyad was axially ligated with two methanol molecules from the β‐face and both the diastereomerically coordinating methanol species were hydrogen bonded with the keto‐carbonyl groups of the neighboring chlorin in a complex. The resulting folded conformer in a solution was confirmed by visible, 1H NMR and IR spectra. All the synthetic zinc chlorin homo‐ and hetero‐dyads consisting of pyropheophorbides‐a, b and/or d took the above methanol‐locked and π–π stacked supramolecules in 1% (v/v) methanol and benzene to give redmost (Qy) electronic absorption band(s) at longer wavelengths than those of the corresponding monomeric chlorin composites. The other zinc chlorin and bacteriochlorin homo‐dyads completely formed similar folded conformers in the same solution, while zinc inverse chlorin and porphyrin homo‐dyads partially took such supramolecules. The J‐type aggregation to folded conformers and the redshift values of composite Qy bands were dependent on the electronic and steric factors of porphyrinoid moieties in dyads. 相似文献
99.
Xueshun Jiao Yunyin Niu Hongyun Zhang Lingjun Zhu Fukai Zhao 《Journal of chemical crystallography》2006,36(10):685-689
The solution-phase reaction of a metal iodide with 1, 3-bis(4-pyridyl)propane (bpp) yields a new organic-inorganic hybrid framework, [(CuI2)2(N,N-dimethyl-bpp)]
n
(1), which is made up of organic cations [dimethyl-bpp]2+ and an infinite [Cu2I4]
n
2− anion chain; The cluster 1 obtained via the reaction between polyiodide complexes and organic N-donor ligand suggests that this simple synthetic approach is likely to be applicable to the construction of polymeric clusters.Supplementary material CCDC-253123 contains the crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: +44-1223-336-033; E-mail: deposit@ccdc.cam.ac.uk]. 相似文献
100.
Masami Fukushima Ken FurubayashiNaotaka Fujisawa Mio TakeuchiTakeshi Komai Keishi OtsukaMitsuo Yamamoto Yasunari KawabeShigekazu Horiya 《Journal of Analytical and Applied Pyrolysis》2011,91(2):323-331
The structural features of humic acids (HAs) isolated from sediments on the bottom of dam reservoirs that can affect their binding capacities for Fe(II) were investigated by pyrolysis-gas chromatography/mass spectroscopy using tetramethylammonium hydroxide (TMAH-py-GC/MS). The binding capacities for Fe(II) increased with increasing O/C molar ratio, suggesting that the oxygen-containing functional group content plays a role in the binding of Fe(II). However, it was not possible to identify specific binding-sites for Fe(II) by TMAH-py-GC/MS analysis. Although C16:1ω7, iso-C15:0 and anteiso-C17:0 fatty acids, which serve as molecular markers of anaerobic microbial activity, were detected in all of the HA samples, the contents of these acids were not correlated with binding capacities for Fe(II). However, the ratio of C16:0 to C16:1ω7 fatty acids, which is used as an index of anaerobic bacterial activity, increased with increasing Fe(II) binding capacities of the HAs. It thus appears likely that the activities of anaerobic bacteria on the bottom of dam reservoirs contribute to alterations in the structural features for HAs, and that this process results in increased binding capacities for Fe(II). 相似文献