Relativistic Consistent Angular-Momentum Projected Shell-Model:Relativistic Mean Field

We develop a relativistic nuclear structure model, relativistic consistent angular-momentum projected shell-model (RECAPS), which combines the relativistic mean-field theory with the angular-momentum projection method. In this new model, nuclear ground-state properties are first calculated consistently using relativistic mean-field (RMF) theory. Then angular momentum projection method is used to project out states with good angular momentum from a few important configurations. By diagonalizing the hamiltonian, the energy levels and wave functions are obtained. This model is a new attempt for the understanding of nuclear structure of normal nuclei and for the prediction of nuclear properties of nuclei far from stability. In this paper, we will describe the treatment of the relativistic mean field. A computer code, RECAPS-RMF, is developed. It solves the relativistic mean field with axial-symmetric deformation in the spherical harmonic oscillator basis. Comparisons between our calculations and existing relativistic mean-field calculations are made to test the model. These include the ground-state properties of spherical nuclei ¹⁶O and ²⁰⁸Pb, the deformed nucleus ²⁰Ne. Good agreement is obtained.     

掺杂对Ni51.5 Mn25 Ga23.5相变行为和磁性的影响

通过往母合金Ni51.5Mn25Ga23.5掺入7种ⅣA,ⅤA和ⅥA过渡族元素得到系列掺杂合金Ni51.5Mn23M2Ga23.5.M为掺杂元素.实验结果表明,掺杂效应一般引起马氏体相变温度的下降,其中,W的掺杂是7种元素中唯一使相变温度升高的特例,且出现了中间马氏体相变.同时,在价电子浓度不变的情况下,相变更敏感于原子的尺度效应.实验发现,Ti,Zr,Hf,V四种非磁性元素的掺杂使Mn原子磁矩减小,而Nb,Ta,W三种非磁性元素的掺杂却可以明显地增大Mn原子的磁矩.在考察掺杂效应时,不能忽略马氏体相变引起的晶格变化对材料磁性的影响.     

基于杂散光抑制要求的光学表面粗糙度控制方法研究

光学表面加工误差引起的散射是影响光学系统成像性能的重要因素.描述表面总散射能量的均方根粗糙度是评定光学表面粗糙度的通用指标,但因其未能体现散射能量的空间分布,在表征光学表面散射对具体光学系统杂散光性能影响时存在准确度不足的局限.本文基于全积分散射及双向散射分布函数理论,针对杂散光抑制要求提出一种光学表面粗糙度控制的新方法.首先通过分析确定光学表面纹理中影响系统杂散光的空间频率范围,然后度量该频率带限范围内的表面均方根粗糙度,作为控制光学表面粗糙度的指标.以太阳磁场望远镜(MFT)为例进行方法验证,确定主镜表面纹理有效频率范围为0—18 mm~(-1),分析了主镜表面带限均方根粗糙度对MFT杂散光性能的影响.结果表明,带限均方根粗糙度与MFT杂散光性能之间的关系稳定性能大幅提高,由此验证了采用带限均方根粗糙度描述光学表面粗糙度,能更为准确地控制其对具体光学系统杂散光性能的影响.     

Investigation of an S-Band Tapered Magnetically Insulated Transmission Line Oscillator

We present an improved structure of the tapered magnetically insulated transmission fine oscillator （MILO）. Simulation results show that this structure can obtain more microwave power with higher efficiency. Studies indicate that the distance between the load support legs and the last vane can affect the operation characteristics of this device. In the experiments, we obtain microwave with peak power of 2 GW, frequency of 2.63 GHz, and mode TMol. The beam to microwave power efficiency is 11%.     

Wettability and formation mechanism of ZnO micro-spheres composed film

This paper reports that the film composed of flower-like ZnO micro-spheres, which consists of nano-sheets, is fabricated by chemical bath deposition. By adding hydrogen fluoride (HF) into the reaction solution, which contains zinc nitrate hexahydrate and hexamethylenetetramine, the ZnO crystal growth process is changed and the film composed by ZnO micro-spheres is obtained after keeping the reaction solution at 95 oC for 2 h. The morphology, crystal phase and wettability of the sample are characterized by scanning electron microscope, x-ray diffraction and contact angle meter, respectively. The results show that the film has the micro-nano compound structure. After modification with heptadecafluorodecyltrimethoxy-silane, the wettability of the film changed from superhydrophilicity to superhydrophobicity, on which water contact angle and the sliding angle are 154o and less than 5o for 8-μL water droplet, respectively. Additionally, the formation mechanism of the ZnO micro-sphere is also discussed.     

Heat-set gels and egg-like vesicles using two component gel system based on chiral calix[4]arenes

Chiral calix[4]arenes bearing long tertiary alkyl groups at the upper rim and S-1-phenylethylamine groups at the lower rim can form heat-set gels and egg-like vesicles enantioselectively with d-2,3-dibenzoyltartaric acid in cyclohexane, which is the first example of heat-set gels resulting from difference in interactions between two component gelators: in addition, the diameter of vesicles decreased with the increase in length of alkyl groups, which could be used to control the size of the vesicles.     

Light-emitting property of simple AIE compounds in gel, suspension and precipitates, and application to quantitative determination of enantiomer composition

It was found that simple AIE compounds could emit different intensity of fluorescence in gel, suspension and precipitates for the first time, which could be applied to fluorescence switches and quantitative determination of enantiomer composition.     

Highly sensitive determination of enantiomeric composition of chiral acids based on aggregation-induced emission

A new chiral tetraphenylethylene derivative with the AIE effect was synthesized and showed not only high enantioselectivity for a wide range of chiral acids but also a high sensitivity of 3.0 × 10(-6) M scale. The enantiomeric purity of chiral acids could be quantitatively determined by this chiral sensor.     

金纳米粒子比色探针检测牛奶及鸡蛋中的三聚氰胺

三聚氰胺能诱导金纳米粒子(AuNPs)团聚,溶液颜色由酒红色变为紫色或蓝灰色.以AuNPs作为比色探针,建立了快速检测牛奶和鸡蛋中三聚氰胺的方法.实验优化得最佳反应条件为:AuNPs粒径13 min、pH=7、反应时间10 min和温度为室温.对样品中常见物质进行了干扰实验.样品经10％三氯乙酸和氯仿提取、离心分离后可...     

Chiral nitrogen-containing calix[4]crown—an excellent receptor for chiral recognition of mandelic acid

A chiral nitrogen-containing calix[4]crown 2 bearing optically pure 1,2-diphenyl-1,2-oxyamino residue at lower rim showed excellent chiral recognition between enantiomers of mandelic acid. Using competitive ¹H NMR titration the ratio of association constants of (S)- and (R)-mandelic acid with the chiral calix[4]crown was determined to be 102, that is 98% de, which is the best result obtained from artificial receptors for the chiral recognition of mandelic acid up to now.