全文获取类型
收费全文 | 46042篇 |
免费 | 8062篇 |
国内免费 | 7033篇 |
专业分类
化学 | 34749篇 |
晶体学 | 711篇 |
力学 | 2553篇 |
综合类 | 592篇 |
数学 | 5458篇 |
物理学 | 17074篇 |
出版年
2024年 | 95篇 |
2023年 | 794篇 |
2022年 | 1355篇 |
2021年 | 1563篇 |
2020年 | 1865篇 |
2019年 | 1901篇 |
2018年 | 1595篇 |
2017年 | 1630篇 |
2016年 | 2160篇 |
2015年 | 2235篇 |
2014年 | 2799篇 |
2013年 | 3510篇 |
2012年 | 4213篇 |
2011年 | 4487篇 |
2010年 | 3323篇 |
2009年 | 3225篇 |
2008年 | 3435篇 |
2007年 | 3116篇 |
2006年 | 2926篇 |
2005年 | 2365篇 |
2004年 | 1858篇 |
2003年 | 1436篇 |
2002年 | 1407篇 |
2001年 | 1226篇 |
2000年 | 1024篇 |
1999年 | 885篇 |
1998年 | 662篇 |
1997年 | 630篇 |
1996年 | 543篇 |
1995年 | 489篇 |
1994年 | 450篇 |
1993年 | 326篇 |
1992年 | 255篇 |
1991年 | 259篇 |
1990年 | 226篇 |
1989年 | 165篇 |
1988年 | 146篇 |
1987年 | 116篇 |
1986年 | 104篇 |
1985年 | 82篇 |
1984年 | 47篇 |
1983年 | 45篇 |
1982年 | 44篇 |
1981年 | 24篇 |
1980年 | 22篇 |
1979年 | 14篇 |
1976年 | 7篇 |
1975年 | 8篇 |
1971年 | 7篇 |
1936年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 250 毫秒
131.
双线性系统的无反馈解耦线性化 总被引:1,自引:1,他引:0
严星刚 《纯粹数学与应用数学》1995,11(2):21-28
用现代微分几何方法研究了双线性控制系统的解耦线性化问题,给出了一般双线性系统解耦线性化的充分条件及严格双线性系统解耦线性化的充要条件,并举例说明了本文的结论。 相似文献
132.
Imaging mass spectrometry requires the acquisition and interpretation of hundreds to thousands of individual spectra in order to map the mineral phases within heterogeneous geomatrices. A fuzzy logic inference engine (FLIE) was developed to automate data interpretation. To evaluate the strengths and limitations of FLIE, the chemical images obtained using FLIE were compared with those developed using two chemometric methods: principle component analysis (PCA) and cluster analysis (K-Means). Two heterogeneous geomatrices, a low-grade chalcopyrite ore and basalt, were imaged using a laser-desorption Fourier transform mass spectrometer. Similar mineral distribution patterns in the chalcopyrite ore sample were obtained by the three data analysis methods with most of the differences occurring at the interfaces between mineral phases. PCA missed one minor mineral phase in the chalcopyrite ore sample and did not clearly differentiate among the mineral classes of the basalt. K-Means cluster analysis differentiated among the various mineral phases in both samples, but improperly grouped some spectra in the chalcopyrite sample that only contained unanticipated high mass peaks. Unlike the chemometric methods, FLIE was able to classify spectra as unknowns for those spectra that fell below the confidence level threshold. A nearest neighbor approach, included in FLIE, was used to classify the unknowns to form a visually complete image; however, the unknowns identified by FLIE can be informative because they highlight potential problems or overlooked results. In conclusion, this study validated the fuzzy logic-based approach used in our laboratory and reveald some limitations in the three techniques that were evaluated. 相似文献
133.
Thermal Rate Constants of the N(^4S)+O2(X^3∑g^-) → NO(X^2Ⅱ) +O(^3P) Reaction on the ^2A′ Potential Energy Surface
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A quasiclassical trajectory study with the sixth-order explicit symplectic algorithm for the N(^4S)+O2(X^3∑g^-) → NO(X^2Ⅱ) +O(^3P) reaction has been reported by employing a new ground potential energy surface. We have discussed the influence of the relative translational energy, the vibrational and rotational levels of O2 molecules on the total reaction cross section. Thermal rate constants at temperatures 300, 600, and 1000 K determined in this work for the reaction are 4.4 × 10^7, 1.8 × 10^10, and 3.1 × 10^11 cm^3mol^-1s^-1, respectively. It is found that they are in better agreement with the experimental data than previous theoretical values. 相似文献
134.
采用固相反应合成了四羟基苯基卟啉与与Fe^2+,Co^2+金属离子的配合物,在室温下,将其与分子O2作用,提纯后得到两种固态氧合配合物.通过元素分析、红外光谱(IR)、核磁共振氢谱(^1HNMR)、电导、热分析(TG/DTA)、紫外光谱(UV)等测试手段确定了氧合配合物的组成为[Co·THPP·O2](NO3)2·2H2O、[Fe·THPP·O2]Cl2·2H2O],可知1mol配合物吸收了1molO2,采用失重法测定了氧合配合物中的配位氧,确定1mol金属配合物吸收1molO2形成超氧配合物. 相似文献
135.
136.
通过光谱响应特性实验和记录/读出图像实验,研究了基因变异型细菌视紫红质(BRD96N)分子膜对单色光的光调制特性.发现BRD96N分子膜在550nm—600nm范围内对调制光有吸收增强的现象,且对此范围内不同波长的单色光其调制程度有差异.利用曲线拟和方法发现550nm—600nm吸收增强的变化过程分为快过程和慢过程,其对应的时间常数分别为30s和5min.利用强度调制器的吸收强度与图像灰度之间的关系,分析了560nm—600nm范围内出现图像反转的实验现象.
关键词:
细菌视紫红质D96N分子膜
光谱响应
吸收增强现象
图像反转现象 相似文献
137.
全固态多波长飞秒脉冲激光系统 总被引:1,自引:1,他引:0
利用棱镜对引进频谱空间啁啾来补偿飞秒脉冲激光二次谐波产生中的相位失配,提高了倍频效率建立了一套全固态、多波长(1065nm, 532nm,823.1nm, 402nm)飞秒脉冲激光系统自制的Nd:YVO4激光器输出532nm绿光激光,最高平均功率可达5.6W当用2.5W绿光激光泵浦时,从自制的钛宝石激光器及经BBO倍频可分别输出中心波长为823.1nm和402nm,平均功率300mW和73mW,谱宽32.3nm和5.1nm,脉宽22fs和33.3fs、重复率108MHz的近红外和蓝光激光整个系统具有结构紧凑、倍频效率高、运行稳定的特点. 相似文献
138.
139.
140.
This paper investigates mutual influence of duct and room acoustics in the whole fan-duct-plenum-room integrations. Applying the parametric design language of finite element software ANSYS (APDL), dimensional and positional influence on system acoustics has been studied. Models with different room dimensions, duct lengths, duct cross-sections, duct locations, duct discharges and duct elbow were constructed, and their characteristics were compared qualitatively. Results show that small rooms, short ducts, large duct cross-sections and bell mouth duct discharges help to increase room sound pressure levels (SPLs); SPLs in ducts and plenums are sensitive to duct dimensions and duct discharge types but insensitive to duct locations and room dimensions; duct elbows have relatively indistinct acoustic influence in each component. Based on the calculation results, a semi-experimental method was proposed for simply and approximately evaluating indoor acoustic spectra of fan-duct-plenum-room integrations, then an example was used to demonstrate the prediction process. Finally, by adopting several ideal models, sound field constitutions, duct and room wall admittances and duct end reflection were explored quantitatively. This study may give a detailed understanding of fan-duct-plenum-room acoustics for researchers, also it might provide a new, simple and approximate prediction method for professionals to evaluate and improve fan-ducted acoustics. 相似文献