5-(对羧基苯偶氮)-8-羟基喹啉与钍的显色反应及应用

研究了钍与5-(对羧基苯偶氮)-8-羟基喹啉(5-CPAHQ)的显色反应条件:在阳离子表面活性剂十六烷基三甲基溴化铵(CTMAB)存在下,pH4.4-5.4缓冲介质中,形成稳定的橙红色络合物,最大吸收波长为490nm,ε=1.10×105L·mol-1·cm-1,钍在0-9μg/25mL范围内符合比尔定律。用TBP萃淋树脂分离,该方法可用于测定矿石中的微量钍。     

热线法测定气体导热系数实验的探讨与改进

在准静态低气压下测量气体的热传导系数时，理论上在低压强范围内应得到Q^-1低-p^-1线性关系图象，但实验数据所绘出的图象出现明显的非线性．本文着重分析出现非线性的原因，并提出实验改进的方法。     

Fe-ZSM-5杂原子分子筛的合成与表征

采用静态水热法分别以正丁胺、四丙基溴化铵为模板剂合成ZSM-5分子筛及Fe-ZSM-5杂原子分子筛；利用XRD与FT-IR对其结构进行表征；考察了Mo改性后分子筛催化剂上甲烷脱氢芳构化的反应性能。结果表明，Fe部分进入了分子筛的骨架，导致分子筛的结晶度及表面酸强度的下降，使Mo／Fe-ZSM-5催化剂的反应性能较Mo／HZSM-5显著下降。     

Na离子和Cl离子引起He原子直接多重电离过程的研究

利用2～8 MeV的Naq+、Clq+(q=2,3,4,5)轰击氦原子,对碰撞的直接多重电离过程进行研究.实验采用反冲离子-散射离子飞行时间符合技术,通过反冲离子飞行时间谱区分不同价态反冲离子;利用静电偏转和位置灵敏探测技术区分不同电荷态散射离子;结合CAMAC-PC多参数获取系统得到一定价态散射离子所对应的反冲离子电荷态分布谱;经分析该谱得到直接多重电离截面与直接单电离截面之比R21.讨论了R21随入射离子速度和电荷态的变化关系.     

EXACT CONTROLLABILITY FOR FIRST ORDER QUASILINEAR HYPERBOLIC SYSTEMS WITH ZERO EIGENVALUES＊＊＊

For a class of mixed initial-boundary value problem for general quasilinear hyperbolic sys-tems with zero eigenvalues, the authors establish the local exact controllability with boundary controls acting on one end or on two ends and internai controls acting on a part of equations in the system.     

基于积分方法的二维平行剪切层声远场预测

本文采用二维Ffowcs Williams＆Hawkings(FW-H)方程对平行剪切层远声场辐射特性进行了研究。近流场时间精确数据通过计算气动声学(Computational Aeroacoustics,CAA)技术数值模拟获得,声远场信息则通过FW-H方程对近流场内的可穿透积分面进行积分获得。该方法首先采用具有解析解的涡/尾缘干涉问题进行了校核,进一步采用CAA/FW-H匹配技术对二维平行剪切层声辐射问题进行了预测,计算结果表明,积分解与计算域内的CAA数值解吻合较好。     

STUDIES ON HYPERFINE STRUCTURE AND ISOTOPE SHIFT OF SOME EXCITED STATES IN Yb AND Tm ATOMS

The hyperfine structures and isotope shifts in some excited states of Yb and Tm have been measured using laser-atomic beam interaction, stepwise excitation and fluorescence detection techniques. From the experimental results, magnetic dipole hyperfine constants A and electric quadrupole hyperfine constants B have been derived. So for as we know, the A factor of [4f¹²5d6s6p]9/2 level in Tm is given for the first time.     

[二苯并-18-冠(醚)-6]KC60奇异特性的核磁共振研究

报道了用［二苯并-18-冠（醚）-6］修饰的碱金属富勒烯作核磁共振测试的一些结果．这类碱金属富勒烯呈现的奇特物理特性，反映了材料在低于200K温度下的磁有序性及电子磁矩与核磁矩的强相互作用，使共振信号增强，亦反映了超分子化学能调控碱金属富勒烯的物理性能 关键词：     

A Two-Dimensional Photonic Crystal Slab Mirror with Silicon on Insulator for Wavelength 1.3μm

A concrete two-dimensional photonic crystal slab with triangular lattice used as a mirror for the light at wavelength 1.3μm with a silicon-on-insulator （SOI） substrate is designed by the three-dimensional plane wave expansion method. For TE-like modes, the bandgap in the Г-K direction is from 1087nm to 1559nm. The central wavelength in the bandgap is about 1.3μm, hence the incident light at wavelength 1.3μm will be strongly reflected. Experimentally, such a photonic crystal slab is fabricated on an SOI substrate by the combination of EBL and ICP etching. The measurement of its transmission characteristics shows the bandgap edge in a longer wavelength is about 1540 nm. The little discrepancy between the experimental data and the theoretical values is mainly due to the size discrepancy of the fabricated air holes.     

关于E-凸函数及E-凸规划几个错误结论的修正

本文研究Youness在1999年建立的有关E凸函数和E规划的结论.利用E凸函数和E凸规划的基本性质和优化分析技术,获得了有关E凸函数E凸规划的几个错误结论的修正..