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131.
A transparent this film was prepared by depositing the sol-gel mixture for the synthesis of MCM-41 mesoporous molecular sieve doped with rhodamine 6G(R6G) dye on glass substrates. The film of silica-surfactant-R6G materials, which was identified to possess hexagonally ordered mesostructure,was composed of nanocrystallites about 35 nm in diameter and 1-10μm in thickness. Cleanness of the substrates, concentration of the sol-gel mixture and rate of evaporation of the solvent were the key factors affecting transparency and homogeneity of the film. Moreover,optical change and lack in dye aggregation were observed to the R6G-functionalized MCM-41 thin film in contrast with that in ethanol solution. 相似文献
132.
Solvation interaction and ion association in solutions of lithium perchlorate/4-methoxymethyl-ethylene carbonate (MEC) have been studied by using Infrared and Raman spectra as a function of concentration of lithium perchlorate. The splitting of ring deformation band and ring ether asymmetric stretching band, and the change of carbonyl stretching band suggest that there should be a strong interaction between Li^+ and the solvent molecules, and the site of solvation should be the oxygen atom of carbonyl group. The apparent solvation number of Li^+ was calculated by using band fitting technique. The solvation number was decreased from 3.3 to 1.1 with increasing the concentration of LiClO4/MEC solutions. On the other hand, the band fitting for the ClO4^- band revealed the presence of contact ion pair, and free ClO4^- anion in the concentrated solutions. 相似文献
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用等压法研究了273.15 K下Li2B4O7-LiCl-H2O体系不同质量摩尔浓度分数的等压平衡浓度和水活度; 计算了LiCl和Li2B4O7混合盐溶液的渗透系数等热力学性质. 用273.15 K下的实验数据对Pitzer离子相互作用模型进行了参数化研究, 拟合求取了273.15 K下Pitzer离子相互作用参数, 用获得的参数计算了LiCl和Li2B4O7在Li2B4O7-LiCl-H2O体系中的活度系数. 273.15 K下由相应的Pitzer模型计算的渗透系数值与实验结果一致. 这对完善含锂、硼盐湖卤水体系的热力学模型具有重要意义. 相似文献
135.
IntroductionInthepasttwodecades ,alargefamilyofnaturalproductsnamedannonaceousacetogeninswereisolatedandcharacterizedbytheglobalresearchersfromvariousspeciesoftheplantannonaeae .1Amongover 4 0 0mem bers,mostofthemwerefoundtoshowpotentcytotoxicandantitumora… 相似文献
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随着大型激光器的发展,对短波段减反膜的要求日益提高,其中钕玻璃激光三倍频(355nm)的减反射成为新的技术要点。采用溶胶-凝胶工艺合成SiO2溶胶,采用提拉镀膜法制备纳米多孔SiO2薄膜,薄膜厚度为75nm,折射率控制在1.22,镀制在石英基底上的薄膜其355nm波长的反射率仅为0.2%。通过氨处理工艺和薄膜的表面修饰,薄膜的抗磨擦性能和疏水性能大大提高,薄膜经过蘸有灰尘、乙醇的棉花球擦洗20次和50次后,透射率最大值仅分别降低0.13% 和 0.39%,与水珠的接触角达到110°。 相似文献
138.
Polar groups in the skeletons of conjugated microporous polymers (CMPs) play an important role in determining their porosity and gas sorption performance. Understanding the effect of the polar group on the properties of CMPs is essential for further advances in this field. To address this fundamental issue, we used benzene, the simplest aromatic system, as a monomer for the construction of two novel CMPs with multi-carboxylic acid groups in their skeletons (CMP-COOH@1 and CMP-COOH@2). We then explored the profound effect the amount of free carboxylic acid in each polymer had on their porosity, isosteric heat, gas adsorption, and gas selectivity. CMP-COOH@1 and CMP-COOH@2 showed Brunauer-Emmett-Teller (BET) surface areas of 835 and 765 m2·g-1, respectively, displaying high potential for carbon dioxide storage applications. CMP-COOH@1 and CMP-COOH@2 exhibited CO2 capture capabilities of 2.17 and 2.63 mmol·g-1 (at 273 K and 1.05 × 105 Pa), respectively, which were higher than those of their counterpart polymers, CMP-1 and CMP-2, which showed CO2 capture capabilities of 1.66 and 2.28 mmol·g-1, respectively. Our results revealed that increasing the number of carboxylic acid groups in polymers could improve their adsorption capacity and selectivity. 相似文献
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140.