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991.
992.
Alexander Semenov Aurélia Charlot Rachel Auzély-Velty Marguerite Rinaudo 《Rheologica Acta》2007,46(5):541-568
Dynamics of associating polymer solutions above the reversible gelation point are studied. Each macromolecule consists of
a soluble backbone (B) and a small fraction of specific strongly interacting groups (A or C stickers) attached to B. A mixture
of B–A and B–C associating polymers with 1:1 stoichiometric ratio is considered. As a result of AC association, the polymers
reversibly gelate above the overlap concentration. It is shown that (1) the network strands are linear complexes (double chains)
of B–A and B–C; (2) “diffusion” of the network junction points is characterized by an apparent activation energy, which can
be significantly higher than the energy of one AC bond; (3) most importantly, the randomness of sticker distribution along
the chain can significantly slow down the network relaxation leading to a markedly non-Maxwellian viscoelastic behavior. The
theory elucidates the most essential features of rheological behavior of polysaccharide associating systems (with A = adamantyl
moiety, C = β-cyclodextrin, B = either chitosan or hyaluronan) including similar behavior of G
′ and G
″ in a wide frequency range, strong temperature dependence of the characteristic frequency ω
x
, and an extremely strong effect of added free stickers (fC) on the dynamics.
This paper was presented at Annual European Rheology Conference (AERC) held in Hersonisos, Crete, Greece, April 27–29, 2006. 相似文献
993.
Praveen K. Tandon Gayatri Sumita Sahgal Manish Srivastava Santosh B. Singh 《应用有机金属化学》2007,21(3):135-138
Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H2O2. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
994.
Jing Ping YANG Shi Hong CHENG Xiao Qian WANG 《数学学报(英文版)》2007,23(3):467-478
This paper investigates bivariate recursive equations on excess-of-loss reinsurance. For an insurance portfolio, under the assumptions that the individual claim severity distribution has bounded continuous density and the number of claims belongs to R1 (a, b) family, bivariate recursive equations for the joint distribution of the cedent's aggregate claims and the reinsurer's aggregate claims are obtained. 相似文献
995.
Meghan Griffith 《Acta Analytica》2007,22(1):16-28
In this paper, I argue that trying is the locus of freedom and moral responsibility. Thus, any plausible view of free and
responsible action must accommodate and account for free tryings. I then consider a version of agent causation whereby the
agent directly causes her tryings. On this view, the agent is afforded direct control over her efforts and there is no need
to posit—as other agent-causal theorists do—an uncaused event. I discuss the potential advantages of this sort of view, and
its challenges. 相似文献
996.
G. K. Shenoy 《Hyperfine Interactions》2006,170(1-3):5-13
Stanley L. Ruby (1924–2004) made major contributions to Mössbauer spectroscopy and was the first to suggest the feasibility of observing the Mössbauer effect using synchrotron radiation. In this article we recall his scientific legacy that have inspired his scientific colleagues. 相似文献
997.
Magnetism of Fe/Cr/Sn/Cr multilayers have been studied by the first-principles density-functional theory. Calculations by the full-potential linearized augmented plane waves (FP LAPW) and screened Korringa–Kohn–Rostoker (SKKR) methods have shown that two types of solutions may be found in these systems: a high-spin (HS) and a low-spin (LS) ones in accordance with the Cr magnetic moment magnitudes. In this work, we have concentrated our attention on the LS solution. The calculation has shown that the LS solution has a phase slip of antiferromagnetic ordering in Cr and is classified as an incommensurate spin density wave (ISDW). The dependence of the ISDW solution on the thickness of Cr, lattice parameter and boundary conditions has been investigated. 相似文献
998.
S. S. Banerjee S. Goldberg Y. Myasoedov M. Rappaport E. Zeldov A. Soibel F. de la Cruz J. van der Beek M. Konczykowski T. Tamegai V. Vinokur 《Pramana》2006,66(1):43-54
Disorder and porosity are parameters that strongly influence the physical behavior of materials, including their mechanical,
electrical, magnetic and optical properties. Vortices in superconductors can provide important insight into the effects of
disorder because their size is comparable to characteristic sizes of nanofabricated structures. Here we present experimental
evidence for a novel form of vortex matter that consists of inter-connected nanodroplets of vortex liquid caged in the pores
of a solid vortex structure, like a liquid permeated into a nanoporous solid skeleton. Our nanoporous skeleton is formed by
vortices pinned by correlated disorder created by high-energy heavy ion irradiation. By sweeping the applied magnetic field,
the number of vortices in the nanodroplets is varied continuously from a few to several hundred. Upon cooling, the caged nanodroplets
freeze into ordered nanocrystals through either a first-order or a continuous transition, whereas at high temperatures a uniform
liquid phase is formed upon delocalization-induced melting of the solid skeleton. This new vortex nanoliquid displays unique
properties and symmetries that are distinct from both solid and liquid phases. 相似文献
999.
We give a new independent self-dual 3-basis for the trivial variety with two binary operations.
Received October 24, 2006; accepted in final form January 25, 2007. 相似文献
1000.
A mistake concerning the ultra LI-ideal of a lattice implication algebra is pointed out, and some new sufficient and necessary conditions for an LI-ideal to be an ultra LI-ideal are given. Moreover, the notion of an LI-ideal is extended to MTL-algebras, the notions of a (prime, ultra, obstinate, Boolean) LI-ideal and an ILI-ideal of an MTL-algebra are introduced, some important examples are given, and the following notions are proved to be equivalent in MTL-algebra: (1) prime proper LI-ideal and Boolean LI-ideal, (2) prime proper LI-ideal and ILI-ideal, (3) proper obstinate LI-ideal, (4) ultra LI-ideal.
This work was supported by the Zhejiang Provincial Natural Science Foundation of China (Grant No. Y605389) and K. C. Wong
Magna Fund in Ningbo University. 相似文献