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41.
Two new isostructural Zintl phases, EuInGe and SrInGe, are obtained from high-temperature reactions of the pure elements in welded Ta tubes. Both ternary phases crystallize in a new structure type in space group Pnma (No. 62), with a = 4.921(1) A, b = 3.9865(9) A, and c = 16.004(3) A for EuInGe; and a = 5.021(1) A, b = 4.0455(9) A, and c = 16.188(4) A for SrInGe. The crystal structures established by single-crystal X-ray diffraction feature zigzag chains of 3-bonded Ge atoms and puckered layers of 4-bonded In atoms. The two structural units are linked into an anionic network with channels composed of 5-membered and 7-membered rings. The channels are filled by the respective divalent cations. The chemical bonding of the anionic [InGe](2)(-) network, derived from a one-electron oxidative distortion of the alpha-ThSi(2) structure, is explained using extended-Hückel band structure calculations. Magnetic measurements indicate that EuInGe exhibits Curie-Weiss paramagnetic behavior above 35 K and antiferromagnetic behavior below 35 K. The calculated effective moment, mu(eff) = 8.11 mu(B), of EuInGe and the diamagnetic behavior of SrInGe are consistent with the oxidation states of Eu(II) and Sr(II), respectively. 相似文献
42.
A novel thin-layer amperometric detector (TLAD) based on chemically modified ring-disc electrode and its application for simultaneous measurements of nitric oxide (NO) and nitrite (NO2−) in rat brain were demonstrated in this work. The ring-disc electrode was simultaneously sensitive to nitric oxide (NO) and nitrite (NO2−) by modifying its inner disc with electropolymerized film of cobalt(II) tetraaminophthalocyanine (polyCoTAPc)/Nafion and its outer ring with poly(vinylpyridine) (PVP), respectively. The ring-disc electrode was used to constitute a novel TLAD in radial flow cell for simultaneous measurements of NO and NO2− in rat brain combined with techniques of high performance liquid chromatography (HPLC) and in vivo microdialysis. It was found that the basal concentration of NO in the caudate nucleus of rat brain is lower than 1.0×10−7 mol l−1, NO2− concentration is 5.0×10−7 mol l−1 and NO exists in brain maybe mainly in the form of its decomposed product. 相似文献
43.
SynthesisandCrystalStructureofTrigadoliniumBromoorthosilicate,Gd_3Br(SiO_4)_2MaoJiang-Gao;ZhuangHong-Hui;HuangJin-Shun(StateKe?.. 相似文献
44.
Mao Jia-Jun Chen Yu-De Zhang Gui-Rong Zhou Zu-Ming 《Journal of Radioanalytical and Nuclear Chemistry》1986,100(1):103-115
A study on the synergistic extraction of uranium(VI) from nitric acid media with double-chelating agent systems 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 (PMBP) plus thenoyltrifluoroacetone (TTA), and 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 plus 1-phenyl-3-methyl-4-trifluoroacetyl-pyrazolone-5 (PMTFP) is described. Some synergistic effects have been observed. The experimental results suggest that the composition of synergistic complex species is UO2PMBP·TTA and UO2PMBP·PMTFP, respectively. The equilibrium constants for these synergistic extractions are calculated by three methods and the mechanism and the regularity of extraction are discussed as well. 相似文献
45.
A Novel Dimeric Coumarin from Clausena lenis 总被引:1,自引:0,他引:1
HongPingHE ShunTingCHEN YueMaoSHEN ChangXiangCHEN YiBinZHAO XiaoJiangHAO 《中国化学快报》2003,14(11):1150-1153
A novel dimeric coumarin (1), a dimeric of seselin named diseselin A, was isolated from the aerial part of Clausena lenis. The structure was elucidated based on the MS, 1D and 2D NMR data. 相似文献
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48.
Yu P Lin Y Xiang L Su L Zhang J Mao L 《Langmuir : the ACS journal of surfaces and colloids》2005,21(20):9000-9006
This letter describes the formation and possible electrochemical applications of molecular films of water-miscible imidazolium-based ionic liquids (ILs) on glassy carbon (GC) electrodes. X-ray photoelectron spectroscopy (XPS) and electrochemical results indicate that the water-miscible ILs used in this study can interact with the GC electrode and form molecular films on the electrode surface. The formed molecular films are found to possess striking electrochemical properties such as electrocatalysis toward ascorbic acid (AA) and the capability to facilitate direct electron transfer of horseradish peroxidase (HRP). This demonstration would pave the way for new electrochemical applications of water-miscible ILs and is envisaged to be useful for the investigation of the electrochemical properties of water-miscible ILs in aqueous media provided the same counteranion is used as the supporting electrolyte. 相似文献
49.
The effect of B2O3 addition on the crystallization of amorphous TiO2-ZrO2 mixed oxide was investigated by X-ray diffraction (XRD), thermogravimetric and differential thermal analysis (TG/DTA). TiO2-ZrO2 mixed oxide was prepared by co-precipitation method with aqueous ammonia as the precipitation reagent. Boric acid was used as a source of boria, and boria contents varied from 2 to 20 wt%. The results indicate that the addition of small amount of boria (<8 wt%) hinders the crystallization of amorphous TiO2-ZrO2 into a crystalline ZrTiO4 compound, while a larger amount of boria (?8 wt%) promotes the crystallization process. FT-IR spectroscopy and 11B MAS NMR results show that tetrahedral borate species predominate at low boria loading, and trigonal borate species increase with increasing boria loading. Thus it is concluded that highly dispersed tetrahedral BO4 units delay, while a build-up of trigonal BO3 promote, the crystallization of amorphous TiO2-ZrO2 to form ZrTiO4 crystals. 相似文献
50.
L. G. Lin Y. Wang J. W. Yan Y. Z. Yuan J. Xiang B. W. Mao 《Electrochemistry communications》2003,5(12):995-999
We report an in situ STM study of a potential-dependent long-range surface restructuring of Au(1 1 1) electrode in neat 1-butyl-3-methylimidazolium tetrafluoroborates (BMIBF4) ionic liquid. Au(1 1 1) undergoes a significant long-range surface restructuring upon cathodic excursion to −1.0 V vs. Pt quasi-reference. The restructuring involves the formation of tiny pits, which then develops into a stable worm-like network with an average width of the network grids 2 nm. Electrochemical annealing occurs at the cathodic limit with the presence of a reduction product of cation BMI+. A smooth surface is recovered with the appearance of the typical (√3 × 22) reconstruction of Au(1 1 1). The surface restructuring is reestablished upon anodic excursion to −1.3 V after the adsorbed reduction product is oxidized. The long-range surface restructuring phenomenon is tentatively explained as a result of partial charge transfer to the weakly adsorbed BMI+, which reduces the metal–metal cohesive energy. In addition, the synergetic effect of the counter anion BF4− may also be involved. The results provide a knowledge of Au(1 1 1) electrode behavior in the neat ionic liquid and are beneficial to understanding in situ STM results involving surface morphological changes in such a media. 相似文献