多自由基体系溶液ESR谱的数据分析

将ER-200D ESR波谱仪ASPECT 3000计算机采集的ESR图谱传输到IBM PC/XT计算机上,通过自行设计的ESR图谱模拟程序ESRSIMU,同屏显示比较,方便、灵活地对多自由基体系溶液ESR一级近似谱进行了模拟,获取了各个自由基的ESR波谱参数和体系中各类自由基的相对浓度等信息.对单个自由基ESR谱的模拟,ESRSIMU的运行速度比BRUKER EPR 3002快近100倍.     

Production of water-soluble sugar from cellulose and corn stover via molten salt hydrate impregnation and separation

Cellulose - Saccharification of cellulose into glucose is a key step for the utilization of lignocellulose. Molten salt hydrate (MSH) is unique in selective hydrolysis of cellulose into glucose but...     

无创正压通气治疗COPD 合并肺源性心脏病的疗效及对血浆C反应蛋白和脑钠素水平的影响

目的 探讨无创正压通气对慢性阻塞性肺疾病（COPD）合并肺源性心脏病的疗效和对患者血浆C 反应蛋白（CRP）和脑钠素（BNP）水平的影响。方法 将2012 年1 月到2014 年1月收治的120 例COPD 急性加重期合并肺源性心脏病患者随机分为观察组（60 例）和对照组（60 例）,对照组给予常规治疗,观察组在此基础上给予无创正压通气治疗。治疗前和治疗3d 后分别进行动脉血气分析,比较患者血pH 值、PaO2、PaCO2和动脉血氧饱和度（SaO2）在治疗前后的改变,并监测治疗前后血浆CRP和BNP 水平的改变。结果 治疗3d 后,两组患者的pH 值、PaO2、SaO2均较治疗前明显升高,PaCO2较治疗前明显降低,而观察组患者治疗后的动态血气分析指标的改善情况明显优于对照组,均有统计学差异（均P＜0.05）。两组患者的血浆CRP 和BNP 水平均较治疗前明显降低,而观察组患者治疗后的血浆CRP 和BNP 水平明显低于对照组,均有统计学差异（均P＜0.05）。结论 无创正压通气治疗COPD 合并肺源性心脏病,能够有效改善血气指标,提高SaO2和PaO2,同时降低血浆CRP 和BNP 的水平,值得在临床推广应用。     

Self‐Assembly of Imidazolium‐Based Rodlike Ionic Liquid Crystals: Transition from Lamellar to Micellar Organization

By using aryl‐amination chemistry, a series of rodlike 1‐phenyl‐1H‐imidazole‐based liquid crystals (LCs) and related imidazolium‐based ionic liquid crystals (ILCs) has been prepared. The number and length of the C‐terminal chains (at the noncharged end of the rodlike core) and the length of the N‐terminal chain (on the imidazolium unit in the ILCs) were modified and the influence of these structural parameters on the mode of self‐assembly in LC phases was investigated by polarizing microscopy, differential scanning calorimetry, and X‐ray diffraction. For the single‐chain imidazole derivatives nematic phases (N) and bilayer SmA₂ phases were found, but upon increasing the number of alkyl chains the LC phases were lost. For the related imidazolium salts LC phases were preserved upon increasing the number and length of the C‐terminal chains and in this series it leads to the phase sequence SmA–columnar (Col)–micellar cubic (Cub_I/Pm3n). Elongation of the N‐terminal chain gives the reversed sequence. Short N‐terminal chains prefer an end‐to‐end packing of the mesogens in which these chains are separated from the C‐terminal chains. Elongation of the N‐terminal chain leads to a mixing of N‐ and C‐terminal chains, which is accompanied by complete intercalation of the aromatic cores. In the smectic phases this gives rise to a transition from bilayer (SmA₂) to monolayer smectic (SmA) phases. For the columnar and cubic phases the segregated end‐to‐end packing leads to core–shell aggregates. In this case, elongation of the N‐terminal chains distorts core–shell formation and removes Cub_I and Col phases in favor of single‐layer SmA phases. Hence, by tailoring the length of the N‐terminal chain, a crossover from taper‐shaped to polycatenar LC tectons was achieved, which provides a powerful tool for control of self‐assembly in ILCs.     

New triorganotin (IV) derivatives of dipeptides as models for metal-protein interactions: synthesis, structural characterization and biological studies

New non-electrolytic triorganotin(IV) derivatives of dipeptides with general formulae R3Sn(HL), where R = Ph and HL = monoanion of glycylisoleucine (H2L-1), valylvaline (H2L-2), alanylvaline (H2L-3), leucylalanine (H2L-4), leucylleucine (H2L-5); R = n-Bu and HL = monoanion of glycylisoleucine (H2L-1) and leucylalanine (H2L-4); and R = Me and HL = monoanion of leucylalanine (H2L-4) have been synthesized and characterized on the basis of infrared, multinuclear 1H, 13C and 119Sn NMR and 119Sn M?ssbauer spectroscopic studies. These investigations suggest that all the ligands in R3Sn(HL) act as monoanionic bidentates coordinating through the COO- and NH2 groups. The 119Sn M?ssbauer studies, together with the NMR data, indicate that, for these polymeric derivatives, the polyhedron around tin in R3Sn(HL) is a trigonal-bipyramid with the three organic groups in the equatorial positions, while the axial positions are occupied by a carboxylic oxygen and the amino nitrogen atom from the adjacent molecule. The anti-inflammatory and cardiovascular activities and toxicity of all these compounds have been determined. Four of the complexes have also been screened against some of the chosen bacterial and fungal strains. The Ph3Sn(IV) compounds exhibit better anti-inflammatory and cardiovascular activities in comparison to the Me3Sn(IV) and n-Bu3Sn(IV) analogues. n-Bu3Sn(Gly-Ile) and Ph3Sn(Ala-Val) exhibit good antibacterial activity against all the chosen strains.     

A Quantum Analog of Generalized Cluster Algebras

We define a quantum analog of a class of generalized cluster algebras which can be viewed as a generalization of quantum cluster algebras defined in Berenstein and Zelevinsky (Adv. Math. 195(2), 405–455 2005). In the case of rank two, we extend some structural results from the classical theory of generalized cluster algebras obtained in Chekhov and Shapiro (Int. Math. Res. Notices 10, 2746–2772 2014) and Rupel (2013) to the quantum case.     

政府投资环保的随机增长模型

本文分析了一个带有污染的随机内生增长模型.利用随机最优化的方法,求出了最优的政府环保投资比率和最优的税收政策.并进一步得出了最优的收入税因污染的外部性指标、生产的扰动的增大而减少;而最优消费税则因这两个参数的增大而增加的结论.     

Exceptional Sequences in Hall Algebras and Quantum Groups

Let be a finite-dimensional hereditary algebra over a finite field k, () and () be, respectively, the Hall algebra and the composition algebra of , be the isomorphism classes of finite dimensional -modules and I the isomorphism classes of simple -modules. We define and , in , to be the right and left derivations of () respectively. By using these derivations and the action of the braid group on the set of exceptional sequences of -mod, we provide an effective algorithm of calculating the root vectors of real Schur roots. This means that we get an inductive method to express u as the combinations of elements u_i in the Hall algebra, where i I and in is any exceptional -module. Because of the canonical isomorphism between the Drinfeld–Jimbo quantum group and the generic composition algebra, our algorithm is applicable directly to quantum groups. In particular, all the root vectors are obtained in this way in the finite type cases.     

液晶基元直接竖挂于主链上的液晶共聚物的研究

合成了含液晶基元的单体，４＋４＇－（对甲氧基－苯甲酰氧基）－苯甲酸氧基］－苯基－甲基丙烯酸酯，以及由此单体与苯乙烯，通过自由基共聚合反应合成了一系列含液晶性和非液晶性两种序列结构的共聚物．采用ＤＳＣ、偏光显微镜和Ｘ－衍射方法研究了共聚物的液晶行为，发现单体和所有的共聚物（除ＣＰ—９外）均有很好的热致液晶性及较宽的液晶态温度范围；随苯乙烯单体单元摩尔百分含量的增加，共聚物的分子量、相转变温度和热失重温度基本上呈下降趋势．通讯联系人０．ｓｇ／ｄｌ的溶液，于４０ｏＣ用乌氏粘度计测定．ｌ·２单体合成合成路线如下：化合物Ｉ、１１、Ｉｌｌ和ＩＶ的制备按文献ｌ’］的方法进行．化合物１、１１、Ｉｌｌ和ＩＶ经元素分析、‘Ｈ—ＮＭＲ和ＭＳ等表征，结果与其化学结构～致．１．３聚合物的合成聚合反应和共聚物结构式表示如下：按单体（ＩＶ）与苯乙烯不同摩尔比，以ＤＭＦ为溶剂，ＡＩＢＮ为引发剂（相当于单体摩尔数的０．５０）．通过封管聚合，在６０ｏＣ水浴中反应３６ｈ，升温至７０ｏＣ反应１２ｈ，抽滤，用ＤＭＦ和甲醇洗，真空干燥．２结果与讨论２．ｌ含液晶基元的单体（Ｉ）化合物１、１１、Ｉｌｌ和ＩＶ经测试分析结果与其化学结构一致．由表１可见，单体?     

Molecular species analysis of phosphatidylcholine by reversed-phase ion-pair high-performance liquid chromatography

The retention behavior of molecular species of phosphatidylcholine (PC) is studied by reversed-phase (RP) ion-pair high-performance liquid chromatography (HPLC). Mobile phases contain tetraalkyl ammonium phosphates (TAAPs) in methano-acetonitrile-water. The stationary phase is alkyl-bonded silica. Competitive interactions of TAAPs, analyte solutes, and an RP-HPLC column result in reduced retention of PC molecular species. PC molecular species are eluted at longer retention times with a larger size of TAAP in the mobile phase, and an increase in the TAAP concentration invariably causes a decrease in PC molecular species retention times. There is a linear correlation between the logarithmic retention factors (k) of PC molecular species and the total number of carbon atoms of TAAP, and the logarithm of k values of PC molecular species can be approximated as a linear function of the logarithm of the counter-ion concentration. There is found to be no distinct dependence between k values of PC molecular species and the mobile phase pH.