分离作用射频四极场加速器频率调谐和高功率试验

在分离作用射频四极场(SFRFQ)加速腔中加入频率调谐装置,用步进电机驱动调谐杆运动,改变调谐板在腔中的位置来改变调谐板与支撑环之间的分布电容,从而改变SFRFQ腔的工作频率,使其谐振频率为26.07 MHz,实现了RFQ和SFRFQ组合加速系统频率的匹配。在完成两腔频率调谐的基础上进行了SFRFQ腔体1/6占空比高功率试验,轫致辐射谱的测量表明,SFRFQ极间电压在入射峰值功率为28.8 kW时已达到86.2 kV,超过了设计指标的70.0 kV。     

Sorption and decomposition of crude oil using exfoliated graphite/ZnO composites

Exfoliated graphite/ZnO composites (EG/ZnO) were prepared by impregnating expandable graphite with Zn(OH)₂, abruptly expanding at 700 °C for 40 s, and heating at 500 °C for 3 h. The composites were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), nitrogen adsorption and mercury porosimetry. The sorption capacity of the composites for spilled crude oil was measured and under UV irradiation the decomposition of the absorbed crude oil was investigated. The results showed that the composites provided with the adsorption and photocatalysis capacity for crude oil at the same time. The sorption capacity of the composites decreased gradually on increasing the ZnO content of the composites. Moreover, the decomposition ratio of the absorbed crude oil increased on increasing the ZnO content or decreasing the weight ratio of crude oil to composites.     

Synthesis, spectral and thermal studies of some organotin(IV) derivatives of 5-amino-3H-1,3,4-thiadiazole-2-thione

Some tri- and diorganotin(IV) compounds of the general formula, RnSnL4-n (where n=2, R=Me, n-Bu and Ph; n=3, R=Me, n-Bu, n-Pr and Ph; HL=5-amino-3H-1,3,4-thiadiazole-2-thione) have been synthesized by the reaction of RnSnCl4-n (where n=2 or 3, R=Me, n-Bu, n-Pr and Ph) and the sodium salt of the ligand. Oct2SnL2 was obtained by the reaction of Oct2SnO with HL in a 1:2 molar ratio under azeotropic removal of water. The bonding and coordination behavior in these derivatives are discussed on the basis of IR, Far-IR, multinuclear (1H, 13C and 119Sn) NMR and 119Sn M?ssbauer spectroscopic studies. These investigations suggest that in all the compounds the ligand acts as monoanionic bidentate coordinating through ring N(3) and exocyclic S. Thermal studies of five compounds, viz., Ph3SnL, Me2SnL2, n-Bu2SnL2, Oct2SnL2 and Ph2SnL2 have been carried out in the temperature range 25-1000 degrees C using TG, DTG and DTA techniques under an atmosphere of dry nitrogen.     

A highly active nano-palladium catalyst for the preparation of aromatic azos under mild conditions

A worm-like Pd nanocatalyst has been prepared and used in the preparation of azo compounds from nitroaromatics under mild reaction conditions. This highly dispersible nano-Pd catalyst shows high activity toward the synthesis of both symmetric aromatic azo compounds and a range of asymmetric aromatic azo compounds.     

Graphene-supported biomimetic catalysts with synergistic effect of adsorption and degradation for efficient dye capture and removal

Design and development of iron porphyrin-based artificial enzymes system have been attracting a lot of attention.Herein,without any toxic reductant and harsh processing,we present a facile one-pot method to fabricate bifunctional catalytic nanocomposites consisting of graphene and hemin by using vitamin C as a mild reduction reagent.The presence of graphene helps the formation of a high degree of highly active and stable hemin on the graphene surface in a monomeric form through theirπ-πstacking interaction.As a result,such nanocomposites possess a superior adsorption capacity and intrinsic peroxidase-like catalytic activity.Moreover,by the combination of their dye adsorption ability,RGOhemin nanocomposites can serve as a suitable candidate for efficient capture and removal of dyes via a synergistic effect.Our findings may pave the way to apply graphene-supported artificial enzymes in a variety of fields,such as environmental chemistry,bionics,medicine,and biotechnology.     

一类具对流项的奇异扩散方程解的逼近性质

讨论了一类带对流项的奇异扩散方.程的Neumann边值问题,证明了整体解的存在唯一性;讨论了带对流项非线性间题解的线性逼近,得到了逼近的显式表示式;同时还对││u-(u)││L2(0,1)进行了估计,得到了解关于时间t充分大时的渐近性态,其中(u)＝∫o/1udx.     

纯钯电沉积及其成核机理研究

研究在柠檬酸钾和草酸铵镀液体系中纯钯电沉积及电结晶机理。结果表明，采用本实验案研制的添加剂（２）ＸＰ－４和ＸＰ－７，可在电流密度０．５￣３．５Ａ／ｄｍ＾２，温度４０￣６０℃的宽广范围内获得全光亮的钯电沉积积层。采用脉冲电源电镀可有效地改善厚沉积层质量，减少沉积层裂纹和孔洞，循环伏安实验表明，钯电极过程的阴阳峰电位之差达１．０５Ｖ，说明其电极过程明显不可逆；伏安图上同时出现－感抗性电流环，说明钯沉积     

On the Eigen‐Mode Excitation of Linear Oscillators and the Earth's Polar Motion

By transforming a 1D second‐order linear oscillator into a 2D first‐order polar motion differential equation, it can be shown that the finite smoothness (i.e., the presence of jump in finite order derivatives) of the applied Newtonian forcing constitutes the sufficient and necessary condition for instantaneous excitation of free eigen‐mode. This condition can be met by forcing functions originated from turbulent and multiphase fluid motions. Sub‐macroscopic transition time associated with astatic elastic deformation limits the physical smoothness of the applied forcing for the Earth's polar motion. Eigen‐modes can also be excited by an infinitely smooth forcing that has a finite domain of non‐zero values. The eigen‐period serves as a macroscopic timescale to characterize the inertia of a linear oscillator. If a zero mean irregular forcing of finite smoothness exhibits a high degree of randomness and the timescale is much shorter than the eigen‐period, then for negligible damping the eigen‐waveform will increase in proportion to the squareroot of time, while the waveform distortion is statistically a constant. As a result, the pattern of distinctive eigen‐oscillation will dominate the forced solution for longer enough duration.     

Effects of Modified Sodium Lignosulfonate on Rheological Properties of Coal–Water Slurry with Low-Rank Coal

Coal–water slurry (CWS) is a new type of oil-replaceable liquid fuel with low pollution. The cost of CWS preparation will be greatly reduced if low-rank coal is used as the preparation material. In this work, chemical modification was used to prepare the modified sodium lignosulfonate (SL-M) hyper-dispersant, having larger molecular weight and more sulfonic groups than sodium lignosulfonate (SL), which was widely used for preparation of CWS from low-rank Shenhua coal due to its rich source and lower price. Effects of preparation conditions and molecular structure of SL-M on rheological properties of CWS were studied by using Haak rheometer. Results showed that the CWS transfered from viscous fluid to swelling fluid when the coal particle size decreased. The consistency coefficient of CWS decreased with the increase of additive dosage. The rheological properties of CWS became much better with the addition of the stabilizer, sodium carboxymethyl cellulose (CMC), compared with that of CWS without CMC. The prepared CWS changed from yield viscous fluid into yield swelling fluid with the increase of the molecular weight of SL-M. The rheological index was lower than 1 when the sulfonic group content was low, then it was increased with the increase of the sulfonic group content.     

电子束泵浦XeCl准分子激光器及应用

为了获得高能紫外激光输出,开展了电子束泵浦XeCl准分子激光技术研究。详细介绍了四向电子束泵浦准分子激光装置的工作原理和结构特征,简述Marx发生器的放电电压、放电电流,激光气室中的沉积能量,激光脉冲能量、脉宽等参数的测量方法;研究了电子束泵浦XeCl准分子激光输出特性,得到了激光脉冲能量随激光气室内混合气体气压变化的规律,当激光器的充电电压为81kV时,获得了能量100J、脉宽200ns的XeCl准分子激光输出,其本征效率约为3.2%。并且开展了XeCl准分子激光辐照涂层材料力学特性研究,采用微型红外通光冲量探头测量不同条件下激光辐照涂层材料的冲量耦合系数,在常压空气环境中的冲量耦合系数约为8.32×10-5 N·W-1。