冷原子吸收光谱法测定饲料添加剂硫酸锰中的汞

采用冷原子吸收光谱法测定饲料添加剂硫酸锰中的汞含量,研究了测定介质及其浓度、重铬酸钾用量、还原剂用量、共存元素干扰等因素对测定的影响,方法的加标回收率为96%~103%,样品测定相对标准偏差10%,能满足日常检验的要求。     

Research on Very Volatile Organic Compounds and Odors from Veneered Medium Density Fiberboard Coated with Water-Based Lacquers

Very volatile organic compounds (VVOCs) are a group of important odor pollutants affecting indoor air quality that have been shown to be harmful to human health. A 15 L environmental chamber, combined with multi-bed tube was used to collect gases. Fifteen very volatile organic compounds (VVOCs), including 12 odor compounds, were identified from veneered medium density fiberboard coated with water-based lacquer (WB-MDF) using gas chromatography–mass spectrometry/olfactometry (GC-MS/O). The total very volatile organic compound (TVVOC) and total odor intensity (TOI) showed a decreasing trend over time, reaching equilibrium on day 28. TVVOC showed an overall slow-fast-slow emission profile, from day 3 to day 7, with a maximum decay rate of 29.7%. TOI showed the greatest rate of decline from day 1 to day 3, at approximately 12%. Alkane and alcohol VVOCs were the more abundant compounds, accounting for at least 60% and even up to 80% of the total. The major odor impression was fruity, with a highest odor rating of 6.6, followed by sweet, with an odor rating of 6.1. Although the odor impression changed from sweet to fruity over time, it seemed pleasant overall. The odor contributors were mainly alkanes, alcohols, esters, and ethers, which had relatively high odor intensities. The main odor-contributing substances were dichloromethane, ethanol, ethyl acetate, 2-methylacrylic acid methyl ester, and tetrahydrofuran. When WB-MDF is used for furniture or other decorative materials, it is strongly recommended that it be stored under ventilation for at least 28 days and the adoption of substitute solvents of lacquers, modified adhesives, and low-odor wood raw materials is recommended. These possible initiatives would contribute to the aim of building an environmentally friendly indoor environment.     

W2m(Rn)中单个函数的平移和伸缩组合的稠密性

本文讨论单个函数的平移和伸缩的组合在Ｓｏｂｏｌｅｖ空间Ｗ２＾ｍ（Ｒ＾ｎ）中稠密的问题,得到了稠密的一个充分必要条件,并对于Ｗ２＾ｍ（Ｒ＾ｎ）中紧集内的函数给出更强的逼近结果。     

Synthesis of a novel comb-like copolymer used as dispersant in organic solvent and influence of free comb-like copolymer on CaCO3 suspension

A novel comb-like copolymer poly (1e)-graft-poly (ε-caprolactone) (SMA-g-PCL, SP), which can be used as an effective CaCO₃ dispersant in organic solvent, was prepared via the esterification reaction between SMA and PCL. The structures and compositions of the graft copolymer were determined by Fourier transform infrared spectrometry (FTIR), H-nuclear magnetic resonance (¹H NMR), and gel permeation chromatography (GPC), respectively. The influences of free comb-like copolymer on CaCO₃ suspension viscosity and rheological behavior were investigated. It was found that the particle-binding bridge generated among CaCO₃ particles through hydrogen bonding and/or electrostatic interactions increased the suspension viscosity as well as the depletion flocculation. On the other hand, it was noteworthy that the free comb-like copolymer could make the CaCO₃ suspension evolve from shear-thinning fluid or nearly Newtonian fluid into shear-thickening fluid. It was attributed to the formation of a transient network through intermolecular associations between the adsorbed SP and the free polymer chains under the action of shear. Finally, the fitting parameters from the Herschel–Bulkley model were in good agreement with the evolution of the rheological behavior of CaCO₃ suspension.     

DNA功能化纳米金用于生物小分子检测

纳米金是金的微小颗粒,在水溶液中以胶体金的形态存在。胶体金的颜色会随着其粒径及表面修饰差异而发生变化,这种颜色变化可通过肉眼观察;同时,这种改变会产生强烈的光散射或光吸收信号。基于这种信号而建立的纳米金比色检测法,已被广泛用于生物分子(如核酸、蛋白质、多糖甚至是细胞)的检测。DNA功能化纳米生物传感器是利用核酸碱基配对原则进行识别,能实现特定基因片段的持续、快速、灵敏和选择性检测。本文结合最近十年的研究现状,主要论述了DNA功能化纳米金用于比色检测法的原理及用于核酸、蛋白质和部分生物小分子的检测,并评述了其中的挑战和前景。     

DNA功能化纳米金用于生物小分子检测

纳米金是金的微小颗粒,在水溶液中以胶体金的形态存在。胶体金的颜色会随着其粒径及表面修饰差异而发生变化,这种颜色变化可通过肉眼观察;同时,这种改变会产生强烈的光散射或光吸收信号。基于这种信号而建立的纳米金比色检测法,已被广泛用于生物分子(如核酸、蛋白质、多糖甚至是细胞)的检测。DNA功能化纳米生物传感器是利用核酸碱基配对原则进行识别,能实现特定基因片段的持续、快速、灵敏和选择性检测。本文结合最近十年的研究现状,主要论述了DNA功能化纳米金用于比色检测法的原理及用于核酸、蛋白质和部分生物小分子的检测,并评述了其中的挑战和前景。     

几种特殊结构全光网中多播路由的波长分配算法

研究全光WDM网络中多播请求的路由与波长分配问题.给定网络拓扑和一组多播通信请求,要求对其进行路由和波长分配,满足波长连续性和波长无冲突约束,使得所用的波长总数最少.就几类特殊网络进行了研究.首先对二分树网络进行了研究,此时问题是多项式时间可求解的.其次对树网络进行了讨论,证明了即使是星网络,问题也不存在近似比小于m1/2-ρ(0＜ρ＜1))的近似算法,除非NP=ZPP,这里m是星图的边数.随后给出了近似比为(√m 1)(log r/√m 1 1)的近似算法,此结果对一般图也成立.最后考虑了环网和树环网,给出了近似比为3.6和2△的近似算法,这里△是图的最大度.     

On character sums over a short interval

The main purpose of this paper is using the analytic methods to study the hybrid mean value involving the character sums, general quadratic Gauss sums and general Kloosterman sums, and give several interesting mean value formulae.     

Comparison of Immobilization Modes in pH-Sensitive Phase Separation Immunoassay

Three immobilization modes of antigen to the polymers in the pH‐sensitive phase separation immunoassay were investigated and compared. The results showed that the immobilization mode in the presence of N‐ethyl‐N′‐(3‐dimethylaminopropyl)carbodiimide hydrochloride (EDCI) rendered the most desirable results. The immobilization efficiencies and immunological reaction activities of immobilized antigen of this mode were improved over the other two modes. The novel immobilization mode by EDCI was used in the pH‐sensitive phase separation immunoassay for rabbit IgG (Ag). In the competitive immunoassay, immobilized Ag and the standard Ag (or sample) competed for binding to a horseradish peroxidase labeled antibody at 37°C in a homogeneous format. After changing the pH to separate the polymer‐immune complex, the complex precipitate was re‐dissolved and determined by coupling with the color reaction of hydrogen peroxide and o‐phenylenediamine. The linear range of this determination was between 100–1400 ng/mL. Compared to the traditional enzyme‐linked immunosorbent assays (ELISA) using the same reactants, the proposed method was quiet fast (the time decreased from 100?120 to 30 min) and showed similar sensitivity, i.e., 6.0 ng/mL.     

真空高功率微波介质窗表面击穿破坏现象的研究进展

综述了国内外真空中高功率微波(HPM)下介质窗表面击穿问题的研究现状和进展。在介质窗表面击穿实验研究方面,介绍了国外最具代表性的研究成果,给出了介质窗材料表面及内部的破坏发展规律,并提出相应的理论模型。在理论仿真方面,重点介绍了国外在运用蒙特卡罗(Monte Carlo)程序和PIC模型对认识HPM下介质窗表面倍增放电机理上做出的突出贡献,给出了HPM下介质窗表面电子在不同影响因素下的运行状态,并提出了一个理论模型,从本质上解释了倍增电子数目和表面静电场以微波频率的2倍振荡的原因。介绍了目前几种可有效抑制介质窗表面微波击穿的技术手段。