原位X射线衍射研究VOx和MoOx在Al2O3上的分散

 采用原位X射线衍射技术考察了机械研磨法和浸渍法制备的负载型VOx(MoOx)/Al2O3催化剂在空气中升温时的晶相变化. 结果表明,采用草酸络合浸渍法制备的VOx/Al2O3催化剂上前驱体(NH4)2［VO(C2O4)2］分散均匀,在升温至200～300 ℃时前驱体开始分解, 300～400 ℃是主要分解区间,到400 ℃时分解完全; VOx物种是通过晶相HxV2O5进行分散的. 机械研磨法制备的VOx/Al2O3催化剂在升温过程中虽然VOx与Al2O3之间存在相互作用,但并没有观察到明显的自发分散现象, V2O5一直以晶体氧化物形式存在. 在空气中升温至400 ℃时,浸渍法制备的MoOx/Al2O3催化剂上(NH4)6Mo2O24·4H2O已完全分解成MoO3. 机械研磨法制备的MoOx/Al2O3在加热过程中分解生成的MoO3与浸渍法得到的MoO3不完全相同,主要体现在(040)和(060)晶面的含量不同; 机械研磨法制得的催化剂在500 ℃下焙烧1 h的分散度小于浸渍法制备的催化剂.     

基于LDPC/Turbo双模译码器的自适应迭代译码算法研究

针对现有WIMAX标准中LDPC/Turbo双模译码器设计在精确计算时未充分考虑迭代次数的问题,提出了一种适用于LDPC和Turbo码的自适应迭代译码算法,可灵活应用于由FPGA技术实现的双模译码器.该算法通过跟踪中间消息计算错误概率,根据多条件判定精确计算迭代次数,从而实现译码算法与错误概率变化特征的自适应性;通过改进的预判决机制减少平均迭代次数.利用Matlab搭建WIMAX系统测试链路,对TDMP多种算法的误码性能与迭代次数的关系进行测试,实现了12个SISO处理单元并行的LDPC/Turbo双模译码器.结果表明,所设计的译码器减少了算法中冗余的迭代过程,并且完全满足该标准下最大码长的要求.     

用同步调制方法降低偏振模色散影响的理论研究

本文利用分布Fourier变换求解在双折射光纤中的耦合非线性薛定谔方程,数值计算了在20Gb/s的光孤子通信系统中偏振模色散(PMD)的影响.通过数值计算发现用同步调制的方法可以有效的降低偏振模色散对系统的影响.     

Modulation Instability in Non-Kerr-like Optical Fibers near the Zero Dispersion Point

Modulation instability (MI) in non-Kerr-like optical fiber near the zero dispersion point is analyzed. Taking into account the fourth order dispersion, new regions of MI are found. The action of the self-steepening is not the same for each region of MI and critical modulation frequency.     

中空纤维液相微萃取-高效液相色谱法测定水中残留的氨基甲酸酯类农药

应用中空纤维液相微萃取(HP-LPME)技术建立了水样中呋喃丹、西维因、异丙威和乙霉威的高效液相色谱分析方法。对影响HP-LPME的实验条件进行了优化。采用Accurel Q3/2聚丙烯中空纤维,以甲苯为萃取溶剂,于室温、搅拌速度为720 r/min条件下在4.5 mL样品溶液中萃取20 min,萃取物在室温下经氮气流吹干后用流动相溶解进样。采用Baseline C18分离柱(4.6 mm×250 mm,5.0 μm),以甲醇-水(体积比为60∶40) 为流动相,流速为1.0 mL/min。呋喃丹、西维因、异丙威和乙霉威的检测波长分别为200,223,200和208 nm。该方法对4种氨基甲酸酯类农药的富集倍数均大于45倍;4种氨基甲酸酯类农药在10~100 μg/L质量浓度范围内,其质量浓度与峰面积之间有良好的线性关系,相关系数均大于0.99;呋喃丹、西维因、异丙威和乙霉威的检出限(S/N=3)分别为5,1,5和3 μg/L;实际水样中的加标回收率为82.0%~102.2%,相对标准偏差为2.0%～6.2%(n=6)。     

具有饱和非线性的非克尔光纤的调制不稳定性

理论上分析了当存在高阶色散时具有饱和非线性的非克尔光纤的调制不稳定性.三阶色散对调制不稳定性没有影响,四阶色散效应导致在正常和反常色散区出现了新的调制不稳定区.并且对比了不同他和参数的增益谱,在新的调制不稳定区,发现同样有一个临界调制频率对应两个入射功率的现象.     

Focal shift of apodized truncated hyperbolic-cosine-Gaussian beam

Focal shift of hyperbolic-cosine-Gaussian beams induced by pure phase apodizer was investigated theoretically. The pure phase apodizer consists of three concentric zones: center circle zone, inner annular zone and outer annular zone. And the phase variance of the inner annular zone is adjustable. Results show that intensity peak moves far from optical aperture and then shrinks sharply for certain radii of zones with increasing phase variance of the inner annular zone. Simultaneously, one new intensity peak occurs near optical aperture, moves far from the optical aperture, and then becomes intensity maximum peak, and repeats the evolution process of the former intensity peak. Tunable focal shift occurs with focal switch. Decreasing the phase variance can change the move direction of the intensity peaks. In addition, the maximum distance between the two intensity peaks can be altered by beam parameters of cosh parts, and the distance value increases and then decreases with increasing beam parameters of cosh parts for certain radii of zones. Tunable focal shift is also discussed to construct optical tweezers.     

Chirp elimination using a linearly chirped fiber grating

Gain-switched distributed feedback laser diodes (GS-DFB-LD) with high repetition bit rate have large frequency chirp. Conventionally, the F–P spectrum filter and normal dispersion fiber were used to eliminate chirp in GS-DFB-LD pulse sources. In this paper, a new method for eliminating chirp of high repetition pulses generated from DFB laser diodes is proposed. The use of a linearly chirped fiber grating for chirp elimination is discussed theoretically and numerically. A new apodized coupling profile function for the grating, which we call it the inverse Gaussian, is given. Its characteristics are analyzed and compared with other profiles. The numerical results are in agreement with the theoretical analysis.     

三维各向同性q变形振子的双波描述

利用双波函数理论描述三维各向同性q变形振子力学量随时间的演化方程,结果显示粒子做非线性振动.同时,当r→0时,所有结论退化为普通三维各向同性谐振子的相关结果.     

On properties of difference polynomials

We study the value distribution of difference polynomials of meromorphic functions, and extend classical theorems of Tumura-Clunie type to difference polynomials. We also consider the value distribution of f (z)f (z + c).