负载型MoOx和VOx催化剂上二甲醚选择氧化制甲醛反应

 考察了负载型MoOx和VOx催化剂上二甲醚选择氧化制甲醛反应的性能. 结果表明,两类催化剂在低温(240~320 ℃)下都具有良好的催化性能,VOx催化剂比MoOx催化剂所需的反应温度低,300 ℃下在VOx/γ-Al2O3催化剂上二甲醚转化率可达20%,甲醛选择性可达70%. 载体对催化剂性能有较大的影响,对于VOx催化剂,使用酸性载体时二甲醚转化率和甲醛选择性更高. 催化剂的稳定性较好, 反应17 h后,VOx/γ-Al2O3催化剂上未检测到有积碳生成.     

某些q-差分方程亚纯解的增长性

运用Nevanlinna理论的基本方法研究了某些比Schr(o)der方程更为一般的q-差分方程的亚纯解,当方程系数在给定的条件下对解的增长性进行了估计,推广了前人已有的结果,并给出了一些例子说明这些结果是精确的.     

几类亚纯函数q移动微差分多项式的零点与Nevanlinna亏量

The first purpose of this paper is to study the properties on some q-shift difference differential polynomials of meromorphic functions,some theorems about the zeros of some q-shift difference-differential polynomials with more general forms are obtained.The second purpose of this paper is to investigate the properties on the Nevanlinna deficiencies for q-shift difference differential monomials of meromorphic functions,we obtain some relations amongδ(∞,f),δ(∞,f′),δ(∞,f(z)ⁿf(qz+c)^mf′(z)),δ(∞,f(qz+c);f′(z))andδ(∞,f(z)ⁿf(qz+c)^m).     

单位圆内一类亚纯函数系数高阶非齐次线性微分方程解的零点

研究单位圆内一类亚纯函数系数高阶非齐次线性微分方程,当方程系数A₀（z）起支配作用,且具有无限正则级,同时满足一定极点条件时,得到方程任意两个线性无关亚纯解的不同零点收敛指数的估计,所得结果推广了复平面上的相应结论。 更多还原     

Experimental observation of tangent-azimuthal non-spiral optical vortex

Optical vortices have attracted much attention recently due to their novel properties and widening applications. And lots of optical vortices can be obtained though most of them turn on spiral pattern on increasing azimuthal angle. In this paper, one kind of non-spiral optical vortex was proposed whose front phase distribution is tangent function of azimuthal angle. And this kind of optical vortices were also observed experimentally by computer-generated hologram method. It was found that when topological charge is smaller than unit one, vortex beam shape changes considerably on increasing topological charge, from hollow pattern to curve shape. When topological charge is bigger than unit and is times of 0.5, vortex beam turns symmetrical polygonal pattern though there is crack between adjacent sides, and the side number is twice of topological charge.     

D维各向异性q变形振子及其波函数

把一维q变形振子的结论推广到D维q变形振子体系,得到了D维q变形振子体系的哈密顿算符形式,并求出了其本征值和在坐标象中的本征函数.结果显示,这是一个非线性振子.     

Vibration energy harvesting under concurrent base and flow excitations with internal resonance

Nonlinear Dynamics - Modulational instability, as a mechanism of wave trains and soliton formation in biological system, is explored in the frame work of the new FitzHugh–Nagumo model. This...     

微通道板玻璃的电阻率

叙述微通道板玻璃的电阻率和其氢原处理后的表面电阻率以及表面电阻率的影响因素。按照玻璃钢络结构观点并就微通道板制造工艺中出现的电阻率差异进行了分析。最后，给出了改进措施。     

Sums of four cubes of primes

It is conjectured that all sufficiently large integers satisfying some necessary congruence conditions are the sum of four cubes of primes. Using the circle method and sieves, we prove that the conjecture is true for at least 1.5% of the positive integers satisfying the necessary conditions.     

Miniemulsion polymerization of styrene with liquid polybutadiene as the sole co-stabilizer

A low-molecular-weight liquid polybutadiene (LPB) is employed as the sole co-stabilizer in miniemulsion polymerization of styrene in present work. Results indicate that the LPB can be used as an effective co-stabilizer to retard the diffusional degradation of monomer droplets in miniemulsion system and get stable miniemulsions. When the miniemulsions were initiated, particle formation occurred predominantly by monomer droplet nucleation. Moreover, the effects of various reaction parameters on the polymerization kinetics and the nucleation mechanisms were also investigated. These parameters include the level of LPB ([LPB]) and the concentrations of SDS ([SDS]) and potassium persulfate ([KPS]). It is shown that the polymerization rate indicates little dependence on [LPB], while increases with increasing [SDS] and [KPS]. Competition between droplet nucleation and homogeneous nucleation occur in the course of polymerization, but droplet nucleation becomes more important by increasing [LPB] or decreasing [SDS]. Furthermore, the result that the particle size is rather insensitive to changes in [KPS] provides the most compelling evidence for the dominant droplet nucleation.