Spectroscopic and laser properties of Nd~(3 ) ions in LaMgAl_(11)O_(19) crystals

The spectroscopic properties, optic quality and thermal lensing effect of Nd~(3 ) ions in LaMgAl_(11)O_(19)(LNA) crystals are investigated and the dependence of the laser characteristics on above properties are discussed.     

Constraints on models with a break in the primordial power spectrum

One of the characteristics of the “Matter Bounce” scenario, an alternative to cosmological inflation for producing a scale-invariant spectrum of primordial adiabatic fluctuations on large scales, is a break in the power spectrum at a characteristic scale, below which the spectral index changes from ns=1$n_s=1$ to ns=3$n_s=3$. We study the constraints which current cosmological data place on the location of such a break, and more generally on the position of the break and the slope at length scales smaller than the break. The observational data we use include the WMAP five-year data set (WMAP5), other CMB data from BOOMERanG, CBI, VSA, and ACBAR, large-scale structure data from the Sloan Digital Sky Survey (SDSS, their luminous red galaxies sample), Type Ia Supernovae data (the “Union” compilation), and the Sloan Digital Sky Survey Lyman-α forest power spectrum (Lyα) data. We employ the Markov Chain Monte Carlo method to constrain the features in the primordial power spectrum which are motivated by the matter bounce model. We give an upper limit on the length scale where the break in the spectrum occurs.     

Phase Transitions in Emulsions Formed by Aqueous Emulsifier and its Action on Improving Mobility in Oil Recovery

Transition from oil-in-water (O/W) emulsions to water-in-oil (W/O) emulsions and its action on enhanced oil recovery was investigated by viscosity, morphology, and simulated flooding experiments. This transition can be realized by increasing the volume ratio of oil to water or decreasing the emulsifier concentration. At a mass concentration of 0.3 wt%, the self-developed emulsifier FJ-1 mainly forms O/W emulsions at a volume ratio (oil to water) of 1:1. The emulsions behave as O/W emulsions with a low viscosity when the volume ratio of oil to water is below 2:1. Above 2:1, increasing volume ratio leads to the O/W emulsions transferring into W/O emulsions with high viscosity. For example, at a volume fraction of 4:1, the viscosity of W/O emulsions reaches 229.1 mPa · s, and separated water can hardly be detected. Transition from O/W emulsions to W/O emulsions with high viscosity can also be realized by decreasing the concentration of emulsifier to 0.05 wt% or lower at a volume ratio of 1:1. These may be the critical factors leading to transition from O/W emulsions to W/O emulsions at core conditions. Simulated flooding experiments show that emulsifier fluids can act as an in situ mobility improver and make an improvement of oil recovery even by 20.4%. The results indicate that the water-in-crude-oil emulsions possess great potential in enhancing oil recovery.     

Amorphous Li2O2: Chemical Synthesis and Electrochemical Properties

When aprotic Li–O₂ batteries discharge, the product phase formed in the cathode often contains two different morphologies, that is, crystalline and amorphous Li₂O₂. The morphology of Li₂O₂ impacts strongly on the electrochemical performance of Li–O₂ cells in terms of energy efficiency and rate capability. Crystalline Li₂O₂ is readily available and its properties have been studied in depth for Li–O₂ batteries. However, little is known about the amorphous Li₂O₂ because of its rarity in high purity. Herein, amorphous Li₂O₂ has been synthesized by a rapid reaction of tetramethylammonium superoxide and LiClO₄ in solution, and its amorphous nature has been confirmed by a range of techniques. Compared with its crystalline siblings, amorphous Li₂O₂ demonstrates enhanced charge‐transport properties and increased electro‐oxidation kinetics, manifesting itself a desirable discharge phase for high‐performance Li–O₂ batteries.     

铝酸盐水泥矿物结构与性能的量子化学计算研究

用量子化学的电荷自洽离散变分Xα(SCC-DV-Xα)计算方法研究了CaO-Al₂O₃系统五种水泥矿物的结构、性能与化学键之间的关系及固溶的杂质离子Na⁺对矿物性能的影响。计算结果表明:Ca-O共价键强度的次序是C₃A < C₁₂A₇ < CA < CA₂ < CA₆,且各矿物的Ca-O键强度都小于它们的Al-O键强度,与相应的水泥矿物水化活性的实验结果一致。Na⁺固溶于C₃A结构后使其Al-O键增强,水化活化能变大,态密度减小,被认为是Na⁺降低C₃A水化活性的主要原因。     

Cr3+:BeAl2O4单晶的特性及生长工艺的改进

描述了掺Cr3+离子的紫翠宝石(Cr3+:BeAl2O4)单晶的晶体结构、物理性质、晶体的吸收光谱与发射光谱及其激光特性.讨论了用引上法生长Cr3+:BeAl2O4晶体的一些工艺问题中.引上法晶体生长过程中选用较慢的提拉速度、较快的转速和生长较大直径的晶体的工艺参数,能够生长出高质量的Cr3+:BeAl2O4单晶体.我们的实验表明,采用温梯法也能生长出高质量的Cr3+:BeAl2O4单晶.与提拉法相比,温梯法减少了原料对环境的污染;易于实现自动温度程序控制;对缺少自然对流的熔体有相当好的适用性.     

介质不均匀性对激光模式相位与光强分布的影响

将不均匀介质势函数进行泰勒展开,取其前3项近似,与描述光腔模式的亥姆霍兹方程中的特殊函数结合,根据光腔边界条件推导出光腔模式的本征解、激光输出功率以及不均匀介质与激光模式的相位与强度分布关系表达式。将表达式应用于氧碘化学激光器的功率与输出耦合率的非线性拟合以及近场光强分布的分析,预测趋势与文献结果相符。     

A possible interpretation of the Higgs mass by the cosmological attractive relaxion

Recently, a novel idea [1] has been proposed to relax the electroweak hierarchy problem through the cosmological inflation and the axion periotic potential. Here, we further assume that only the attractive inflation is needed to explain the light mass of the Higgs boson, where we do not need a specified periodic potential of the axion field. Attractive inflation during the early universe drives the Higgs boson mass from the large value in the early universe to the small value at present, where the Higgs mass is an evolving parameter of the Universe. Thus, the small Higgs mass can technically originate from the cosmological evolution rather than dynamical symmetry or anthropics. Further, we study the possible collider signals or constraints at a future lepton collier and the possible constraints from the muon anomalous magnetic moment. A concrete attractive relaxion model is also discussed, which is consistent with the data of Planck 2015.     

Reservoir Pore Structure Classification Technology of Carbonate Rock Based on NMR T 2 Spectrum Decomposition

The carbonate reservoir has a number of properties such as multi-type pore space, strong heterogeneity, and complex pore structure, which make the classification of reservoir pore structure extremely difficult. According to nuclear magnetic resonance (NMR) T ₂ spectrum characteristics of carbonate rock, an automatic pore structure classification and discrimination method based on the T ₂ spectrum decomposition is proposed. The objective function is constructed based on the multi-variate Gaussian distribution properties of the NMR T ₂ spectrum. The particle swarm optimization algorithm was used to solve the objective function and get the initial values and then the generalized reduced gradient algorithm was proposed for solving the objective function, which ensured the stability and convergence of the solution. Based on the featured parameters of the Gaussian function such as normalized weights, spectrum peaks and standard deviations, the combinatory spectrum parameters (by multiplying peak value and normalized weight for every peak) are constructed. According to the principle of fuzzy clustering, the carbonate rock pore structure is classified automatically and the discrimination function of each pore structure type is obtained using Fisher discrimination analysis. The classification results were analyzed with the corresponding casting thin section and scanning electron microscopy. The study shows that the type of the pore structure based on the NMR T ₂ spectrum decomposition is strongly consistent with other methods, which provides a good basis for the quantitative characterization of the carbonate rock reservoir pore space and lays a foundation of the carbonate rock reservoir classification based on NMR logging.     

求解稳恒磁场的谐函数展开法

推导出稳恒磁场矢势的谐函数展开式,当稳恒电流的分布适宜于用直角坐标系表示时,可应用该展开式求解磁场,给出了应用该展开式求解稳恒磁场的例子。