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91.
Rui Guo Xin Zhang Tong Li Qianli Li David A. Ruiz Liu Leo Liu Chen-Ho Tung Lingbing Kong 《Chemical science》2022,13(8):2303
A cationic terminal iminoborane [Mes*N B ← IPr2Me2][AlBr4] (3+[AlBr4]−) (Mes* = 2,4,6-tri-tert-butylphenyl and IPr2Me2 = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) has been synthesized and characterized. The employment of an aryl group and N-heterocyclic carbene (NHC) ligand enables 3+[AlBr4]− to exhibit both B-centered Lewis acidity and BN multiple bond reactivities, thus allowing for the construction of tri-coordinate boron cations 5+–12+. More importantly, initial reactions involving coordination, addition, and [2 + 3] cycloadditions have been observed for the cationic iminoborane, demonstrating the potential to build numerous organoboron species via several synthetic routes.An NHC-stabilized aryliminoboryl cation exhibits both boron-centered Lewis acidity and multiple bond reactivity and could be utilized as an effective synthon for unusual cationic boron species. 相似文献
92.
Teng Fang Jiazhan Xin Chenguang Fu Dongsheng Li Xinbing Zhao Claudia Felser Tiejun Zhu 《Annalen der Physik》2020,532(11):1900435
Lattice thermal conductivity can be reduced by introducing point defect, grain boundary, and nanoscale precipitates to scatter phonons of different wave-lengths, etc. Recently, the effect of electron–phonon (EP) interaction on phonon transport has attracted more and more attention, especially in heavily doped semiconductors. Here the effect of EP interaction in n-type P-doped single-crystal Si has been investigated. The lattice thermal conductivity decreases dramatically with increasing P doping. This reduction on lattice thermal conductivity cannot be explained solely considering point defect scattering. Further, the lattice thermal conductivity can be fitted well by introducing EP interaction into the modified Debye–Callaway model, which demonstrates that the EP interaction can play an important role in reducing lattice thermal conductivity of n-type P-doped single-crystal Si. 相似文献
93.
94.
Hepatic vessel skeletonization serves as an important means of hepatic vascular analysis and vessel segmentation. This paper presents a survey of techniques and algorithms for hepatic vessel skeletonization in medical images. We summarized the latest developments and classical approaches in this field. These methods are classified into five categories according to their methodological characteristics. The overview and brief assessment of each category are provided in the corresponding chapters, respectively. We provide a comprehensive summary among the cited publications, image modalities and datasets from various aspects, which hope to reveal the pros and cons of every method, summarize its achievements and discuss the challenges and future trends. 相似文献
95.
固定化脂质体色谱研究中药复方的细胞膜通透性成分及其质量控制 总被引:11,自引:0,他引:11
提出了固定化脂质体色谱(immobilized liposome chromatography,ILC)研究中药复方的细胞膜通透性成分及其质量控制的方法。以当归补血汤及其组分为例,考察了它们在ILC色谱柱上的分离效果;当归补血汤水提取液和75%乙醇提取液在ILC色谱柱上各有8个保留峰,当归水提取液、甲醇提取液和75%乙醇提取液在ILC色谱柱上分别有3、6、9个保留峰,黄芪水提取液、甲醇提取液和75%乙醇提取液在ILC色谱柱上各有7个保留峰;建立了当归补血汤及其组分中阿魏酸和蒿本内酯的定量分析方法,当归补血汤水提取液和75%乙醇提取液中阿魏酸的含量分别为0.0743%和0.0688%,蒿本内酯的含量分别为0.0472%和0.457%,当归水提取液和75%乙醇提取液中阿魏酸的含量分别为0.0694%和0.0691%,蒿本内酯的含量分别为0.0781%和0.455%。 相似文献
96.
Fifteen Chinese fly ashes were converted hydrothermally into zeolites, and phosphate immobilization capacity (PIC) of the synthesized zeolites and the corresponding raw fly ashes were determined using an initial phosphate concentration of 1000 mg/L. Results showed that there was a remarkable increase in PIC (from 1.2 to 7.6 times) following the synthesis process. Fractionation of immobilized phosphorus indicated that Fe+Al-P increased most significantly and consistently among all the phosphorus fractions following the conversion of fly ash to zeolite. The PIC and Ca+Mg-P were closely related to Ca content (with r values of 0.9683 and 0.9651, respectively) rather than Mg content (with r values of 0.3920 and 0.3212, respectively). The r values of PIC and Fe+Al-P with Fe content (with r values of 0.4686 and 0.6385, respectively) were higher than those with Al content (with r values of -0.7857 and -0.3770, respectively). Although calcium and iron components were mainly involved in phosphate immobilization, there was no significant change of Ca and Fe content following the conversion of fly ash to zeolite. Increase in dissociated Fe(2)O(3) and specific surface area probably accounted for the enhancement in PIC of synthesized zeolites compared with corresponding fly ashes. The PIC value of zeolites showed a significant correlation with dissociated Fe(2)O(3) (r=0.6186). The specific surface area increased 26.0-89.4 times as a result of the conversion of fly ash to zeolite. The maximum removal of phosphate occurred within different pH ranges for zeolites which were synthesized from high, medium and low calcium fly ashes and this behavior was explained by the reaction of phosphate with calcium and iron components. 相似文献
97.
Collisions between hot H atoms and CO2 molecules were studied experimentally by time-resolved Fourier transform infrared emission spectroscopy. H atoms with three translational energies, 174.7, 241.0 and 306.2 kJ/mol respectively, were generated by UV laser photolysis to initiate a chemical reaction of H+CO2!OH+CO. Vibrationally excited CO (v≤2) was observed in the spectrum, where CO was the product of the reaction. The highly efficient T-V energy transfer from the hot H atoms to the CO2 was verified too. The highest vibrational level of v=4 in CO2 (v≤3) was found. Rate ratio of the chemical reaction to the energy transfer was estimated as 10. 相似文献
98.
99.
硫与金属元素所形成的二元团簇具有很多重要的特性,已受到人们的普遍重视.用激光-串级飞行时间质谱仪,我们曾研究了硫与过渡金属钽、铁等的二元团簇.最近我们选取主族金属元素铝,研究了铝硫团簇的形成及其光解,实验结果表明,与钽硫或铁硫团簇相比,铝硫团簇无论在其组份构成还是在其光解方面,都表现出鲜明的特有规律性.实验的主要参数如下:溅射用激光为Nd:YAG 二倍频,其输出强度控制在约10~7W·cm~(-2),激光的重复频率10Hz 样品位于激光束的焦点附近,由焦距f=50cm 的透镜调整其聚焦状 相似文献
100.
Sun YX Huang YX Li FL Wang HY Fan C Bao YL Sun LG Ma ZQ Kong J Li YX 《Chemistry Central journal》2012,6(1):2