三导体螺旋脉冲形成线的输出特性

 采用横电磁波传输理论,分析了三导体螺旋脉冲形成线（PFL）（包含内筒、螺旋中筒和外筒）的脉冲形成过程,给出了螺旋PFL的波阻抗、慢波系数、输出脉冲的平顶波动幅度等特征参数的计算公式。研究表明:三导体螺旋PFL具有与螺旋传输线同样的波阻抗和慢波系数;螺旋PFL的输出脉冲平顶波动,随着慢波系数或负载阻抗的增大而减小。     

Analysis and Evaluation the Effect of Electrode Films on the SAW Torque Sensitivity

Acoustical Physics - The surface acoustic wave (SAW) sensor has been widely used to measure torque, and the temperature effect on torque sensitivity has been taken into account. However, few...     

Decentralized direct adaptive output feedback fuzzy H ∞ tracking design of large-scale nonaffine nonlinear systems

A novel H _∞ tracking-based decentralized direct adaptive output feedback fuzzy controller is developed for a class of interconnected nonaffine uncertain nonlinear systems in this paper. By virtue of the proper filtering of the observation error dynamics to assure its strictly positive realness, the observer-based decentralized direct adaptive fuzzy control (DAFC) scheme is presented for a class of large-scale nonaffine nonlinear systems by the combination of H _∞ tracking technique, implicit function theorem, a state observer and a fuzzy inference system. The output feedback and adaptation mechanisms for each subsystem depend upon local measurements not only to achieve asymptotical tracking of a reference trajectory but to guarantee arbitrary small attenuation level of the mismatched errors and external disturbances on the tracking error. Simulation results confirm the effectiveness of the proposed decentralized output feedback scheme.     

Facile Synthesis of Thermal‐ and Photostable Titania with Paramagnetic Oxygen Vacancies for Visible‐Light Photocatalysis

A novel dopant‐free TiO₂ photocatalyst (V_o^.‐TiO₂), which is self‐modified by a large number of paramagnetic (single‐electron‐trapped) oxygen vacancies, was prepared by calcining a mixture of a porous amorphous TiO₂ precursor, imidazole, and hydrochloric acid at elevated temperature (450 °C) in air. Control experiments demonstrate that the porous TiO₂ precursor, imidazole, and hydrochloric acid are all necessary for the formation of V_o^.‐TiO₂. Although the synthesis of V_o^.‐TiO₂ originates from such a multicomponent system, this synthetic approach is facile, controllable, and reproducible. X‐ray diffraction, XPS, and EPR spectroscopy reveal that the V_o^.‐TiO₂ material with a high crystallinity embodies a mass of paramagnetic oxygen vacancies, and is free of other dopant species such as nitrogen and carbon. UV/Vis diffuse‐reflectance spectroscopy and photoelectrochemical measurement demonstrate that V_o^.‐TiO₂ is a stable visible‐light‐responsive material with photogenerated charge separation efficiency higher than N‐TiO₂ and P25 under visible‐light irradiation. The V_o^.‐TiO₂ material exhibits not only satisfactory thermal‐ and photostability, but also superior photocatalytic activity for H₂ evolution (115 μmol h^?1 g^?1) from water with methanol as sacrificial reagent under visible light (λ>400 nm) irradiation. Furthermore, the effects of reaction temperature, ratio of starting materials (imidazole:TiO₂ precursor) and calcination time on the photocatalytic activity and the microstructure of V_o^.‐TiO₂ were elucidated.     

Tunable Electrochemical C−N versus N−N Bond Formation of Nitrogen‐Centered Radicals Enabled by Dehydrogenative Dearomatization: Biological Applications

Herein, an environmentally friendly electrochemical approach is reported that takes advantage of the captodative effect and delocalization effect to generate nitrogen‐centered radicals (NCRs). By changing the reaction parameters of the electrode material and feedstock solubility, dearomatization enabled a selective dehydrogenative C?N versus N?N bond formation reaction. Hence, pyrido[1,2‐a]benzimidazole and tetraarylhydrazine frameworks were prepared through a sustainable transition‐metal‐ and exogenous oxidant‐free strategy with broad generality. Bioactivity assays demonstrated that pyrido[1,2‐a]benzimidazoles displayed antimicrobial activity and cytotoxicity against human cancer cells. Compound 21 exhibited good photochemical properties with a large Stokes shift (approximately 130 nm) and was successfully applied to subcellular imaging. A preliminary mechanism investigation and density functional theory (DFT) calculations revealed the possible reaction pathway.     

FRP加固金属裂纹板的断裂力学分析

传统的金属结构加固方法会形成新的疲劳源,而粘贴FRP加固则具有明显的优势．提出了“三维实体-弹簧-壳元”有限元模型,金属板采用三维实体单元, FRP采用壳单元,用弹簧单元来模拟FRP与金属板之间的胶层,对金属裂纹板粘贴FRP加固后的性能进行了线弹性断裂力学分析,并对影响金属板裂纹前缘应力强度因子的参数进行了讨论．分析结果表明,采用高弹性模量的FRP和增加FRP的厚度对改善加固效果非常明显．     

介质窗口材料对高功率微波传输特性的影响

运用光学方法,分析平面波通过无限大介质平板的传输特性,进而分析单层介质窗口的引入对微波传输性能的影响。在S波段微波源上对聚四氟乙烯材料进行了真空环境下的微波放电击穿实验,通过长时间的表面放电,在聚四氟乙烯材料表面出现电痕和电树枝。在100 ns脉冲宽度下,未发生大面积表面放电前,通过光学照相,在介质表面观测到局部放电现象,认为局部放电仍能导致材料表面破坏。作为对比,进行了聚苯乙烯材料的电老化实验,实验结果表明聚苯乙烯材料具有良好的耐电痕、耐电树枝老化特性。     

基于热解ZIF-8的氮掺杂碳电化学氧还原合成过氧化氢催化剂

氧气的两电子还原反应(2e-ORR)是绿色、安全的H₂O₂合成路线. 本工作以Zn²⁺和2-甲基咪唑合成的沸石型咪唑酸框架-8 (ZIF-8)为前驱体, 通过高温热解炭化, 利用ZIF-8中的锌在高温下的可挥发性, 制备了非金属氮掺杂石墨化多孔碳材料(p-ZIF), 系统考察了ZIF-8热解炭化温度(900、950和1000 ℃)对催化剂结构和2e-ORR催化性能的影响. p-ZIF不仅保留了ZIF-8规整的菱形十二面体形貌, 而且氮含量高, 拥有高的比表面积和多级孔结构. 在酸性条件下的2e-ORR反应中, 三个p-ZIF催化剂均显示了较低的过电位和较低的Tafel斜率, 而且稳定性良好. 其中在H₂O₂选择性最高的p-ZIF-950催化剂上, 过电位为86 mV, H₂O₂选择性最高可达89.2%. 在6 h恒电位反应中, p-ZIF-950催化剂能够以87 mmol•g_cat^-1•h^-1的恒定速率产生H₂O₂. 根据多种表征结果, 推测p-ZIF催化剂的孔径尺寸和石墨N含量是影响其2e-ORR催化性能的主要因素.     

新型含有苯并咪唑取代基的多取代吡啶类化合物及其配合物的合成与表征

以苯并咪唑查尔酮、吡啶盐在醋酸氨和冰醋酸中的混合物为原料,在微波作用下合成了一系列未见文献报道的多取代吡啶类化合物,并研究了具有代表性的化合物与金属离子的配位反应.通过IR,UV,1HNMR,13CNMR等方法进行了表征,并用单晶X-ray衍射法测定了一个配合物的单晶分子结构.