全文获取类型
收费全文 | 10793篇 |
免费 | 1817篇 |
国内免费 | 2082篇 |
专业分类
化学 | 8297篇 |
晶体学 | 134篇 |
力学 | 663篇 |
综合类 | 152篇 |
数学 | 1392篇 |
物理学 | 4054篇 |
出版年
2024年 | 34篇 |
2023年 | 253篇 |
2022年 | 469篇 |
2021年 | 462篇 |
2020年 | 534篇 |
2019年 | 522篇 |
2018年 | 414篇 |
2017年 | 436篇 |
2016年 | 597篇 |
2015年 | 615篇 |
2014年 | 644篇 |
2013年 | 893篇 |
2012年 | 816篇 |
2011年 | 912篇 |
2010年 | 680篇 |
2009年 | 632篇 |
2008年 | 734篇 |
2007年 | 595篇 |
2006年 | 569篇 |
2005年 | 520篇 |
2004年 | 429篇 |
2003年 | 356篇 |
2002年 | 407篇 |
2001年 | 321篇 |
2000年 | 279篇 |
1999年 | 235篇 |
1998年 | 185篇 |
1997年 | 132篇 |
1996年 | 157篇 |
1995年 | 115篇 |
1994年 | 138篇 |
1993年 | 100篇 |
1992年 | 73篇 |
1991年 | 94篇 |
1990年 | 90篇 |
1989年 | 44篇 |
1988年 | 40篇 |
1987年 | 29篇 |
1986年 | 35篇 |
1985年 | 38篇 |
1984年 | 15篇 |
1983年 | 18篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1971年 | 1篇 |
1957年 | 3篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
ONOO-活性氧的荧光光谱分析进展 总被引:1,自引:0,他引:1
系统介绍了ONOO^-活性氧的化学性质,并对其参与的主要化学反应进行了分类和总结.同时,比较了近年来用于ONOO^-检测的方法,并重点论述了荧光光谱分析方法尤其是酶催化动力学荧光分析法在检测ONOO^-活性氧方面的优势和最新的研究进展. 相似文献
62.
63.
Liqun Qi 《Operations Research Letters》1997,20(5):223-228
We show that strong differentiability at solutions is not necessary for superlinear convergence of quasi-Newton methods for solving nonsmooth equations. We improve the superlinear convergence result of Ip and Kyparisis for general quasi-Newton methods as well as the Broyden method. For a special example, the Newton method is divergent but the Broyden method is superlinearly convergent. 相似文献
64.
用Chapman-Enskog方法计算了相对论性重离子碰撞快度中心区产生的π介子物质的输运系数,并建立了相应的粘滞流体力学方程,进而讨论了粘滞对π介子物质演化过程的影响.结果表明,粘滞将减缓快度中心区π介子物质的冷却速度. 相似文献
65.
One of the main methods for solving stochastic programs is approximation by discretizing the probability distribution. However, discretization may lose differentiability of expectational functionals. The complexity of discrete approximation schemes also increases exponentially as the dimension of the random vector increases. On the other hand, stochastic methods can solve stochastic programs with larger dimensions but their convergence is in the sense of probability one. In this paper, we study the differentiability property of stochastic two-stage programs and discuss continuous approximation methods for stochastic programs. We present several ways to calculate and estimate this derivative. We then design several continuous approximation schemes and study their convergence behavior and implementation. The methods include several types of truncation approximation, lower dimensional approximation and limited basis approximation.His work is supported by Office of Naval Research Grant N0014-86-K-0628 and the National Science Foundation under Grant ECS-8815101 and DDM-9215921.His work is supported by the Australian Research Council. 相似文献
66.
Effects of barium on the nonlinear electrical characteristics and dielectric properties of SnO2-based varistors
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The effects of barium on electrical and dielectric properties of the SnO_2·Co_2O_3·Ta_2O_5 varistor system sintered at 1250℃ for 60min were investigated. It is found that barium significantly improves the nonlinear properties. The breakdown electrical field increases from 378.0 to 2834.5V/mm, relative dielectric constant (at 1kHz) falls from 1206 to 161 and the resistivity (at 1kHz) rises from 60.3 to 1146.5kΩ·cm with an increase of BaCO_3 concentration from 0mol% to 1.00mol%. The sample with 1.00mol% barium has the best nonlinear electrical property and the highest nonlinear coefficient (α=29.2). A modified defect barrier model is introduced to illustrate the grain-boundary barrier formation of barium-doped SnO_{2}-based varistors. 相似文献
67.
68.
A Novel and Efficient Catalytic System for Aerobic Oxidative Coupling of 2-Naphthol Derivatives 总被引:2,自引:0,他引:2
LiCHEN JingBoLAN ZhiHuaMAO XiaoQiYU RuGangXIE 《中国化学快报》2004,15(8):903-906
The paper reported a novel and efficient aerobic oxidative coupling reaction of 2-naphthol derivatives catalyzed by CuCu (Ⅰ or Ⅱ)N-alkylimidazole complexes in excellent yields. The crystal structure of CuCu(Ⅱ)N-methylimidazole complex to be determined by X-Ray. 相似文献
69.
Qi Sheng Liu Lian Dong Liu Jing Min Shi 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(1):m58-m60
In the title centrosymmetric binuclear complex, [Cd2(C17H11N3O)4(H2O)2](ClO4)4, the CdII ion assumes a distorted octahedral geometry. There are π–π stacking interactions between the pyridine and 1,10‐phenanthroline ring systems of adjacent ligands at the same CdII centre. Intermolecular hydrogen bonds between the coordinated aqua ligand and the O atom of a keto group connect adjacent complex cations into extended chains. Hydrogen bonds also exist between the complex cations and the perchlorate anions. Compared with the fluorescence spectrum of the organic ligand, the complex displays strong fluorescent emission and an ipsochromic shift of the emission peaks, which may be attributed to the structural character. 相似文献
70.
M. Carme Calderer M. Gregory Forest Qi Wang 《ournal of non Newtonian Fluid Mechanics》2004,120(1-3):69
We present a systematic derivation of hydrodynamic theories for nonhomogeneous nematic liquid crystal polymers (LCPs) by approximating the molecules as rigid ellipsoids, which can be either uniaxial molecules (spheroids) or biaxial ones. The short range interaction is assumed to be dominated by the excluded volume effect. Additional molecular properties with ellipsoidal molecules, e.g., a dipole–dipole interaction in extended nematics and chiral molecular structure in cholesterics, are accounted for through additional intermolecular potentials. Long-range molecular interaction is implemented through an averaged mean-field potential characterized by interaction functions. The extra elastic stress tensor is calculated using an extended virtual work principle consistent with conservation of angular momentum on the material volume, whereas the extra viscous stress is obtained by Batchelor’s volume averaging method. In the isothermal case, the theories are shown to satisfy the second law of thermodynamics, i.e., they admit positive production of entropy or energy dissipation. In the case of cholesterics, the kinetic theory reduces to the Leslie–Ericksen theory in the limit of weak translational diffusion, weak long range interaction, and weak flow. 相似文献