A 6-site force field for succinonitrile

A 6-site succinonitrile force field has been developed. The model has produced proper proportions of the three succinonitrile conformers, which is necessary to avoid the thermal contraction of the plastic crystal phase around the melting point. The solid and liquid densities are about 1% lower or higher than the experimental values. The melting point of the model has been adjusted using the Gibbs–Duhem integration method. The theoretical melting point is in good agreement with experiment.     

Chiral Diamine/Brønsted Acid Conjugates Confined in Mesoporous Silica as Catalyst for the Asymmetric Aldol Reaction

Chiral primary-tertiary diamine/Brønsted acid conjugates were selectively immobilized on the inner surface of mesoporous silica and used as catalyst for the asymmetric aldol reaction of acetone with various aldehydes. The catalyst showed modest reactivity and enantioselectivity and can be reused 6 times without loss of activity and enantioselectivity. As compared with silica gel as the support, an increase in ee value of the reaction product was observed with the SBA-15-immobilized organic catalyst. This was believed to be due to the confinement effect of the nanopores.     

基于福利经济基础的健康不公平指数若干研究

在满足健康不公平度量的一般偏好基础下，根据我们的特殊偏好确定具体的健康不公平指数，对健康不公平度量具有重要的实践意义。     

基于LabVIEW与Multisim的火控系统半实物联合仿真方法

针对当前装甲装备火控系统电路组成与功能特点,对火控系统维修保养过程中的故障诊断方法与测试需求进行了研究,提出了一种火控系统半实物联合仿真方法,介绍了该仿真建模方法的设计思路与实现方法。该方法可充分发挥LabVIEW和Multisim软件的优势,通过半实物联合仿真的方法,以仿真模型代替部分或者全部火控系统部组件,能够很好地实现火控系统不同级别的电路功能模拟、故障复现,快速完成故障诊断分析,解决了当前装甲装备火控系统维修诊断设备通用性差、规范化程度低、开放性差,难以真实的模拟系统级、部件级功能、故障注入和故障检测等问题,为装甲装备火控系统故障诊断与测试设备开发提供了有效平台,为基层部队开展维修训练和维护保障提供了有效途径。     

低温辐射计的结构优化方案设计

传统低温辐射计的布儒斯特窗口会对传递探测器的绝对光谱响应率定标产生较大的影响。文中阐述了低温辐射计对传递探测器的传统定标过程;分析定标过程中因布儒斯特窗口及窗口复现导致定标精度降低的原因;提出一种新的定标结构。该结构中低温辐射计和传递探测器安置于同心弧形轨道上,二者通过精密电机的控制可以分时切入定标光路,实现传递探测器相对于低温辐射计的绝对定标。新的定标结构能够完全消除布儒斯特窗口在传递探测器定标过程中的影响,降低测量激光功率约50%的不确定度,可以进一步降低辐射定标溯源基准的不确定度,提高定标的精度。     

Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation of beta-ketoesters

The synthesis and resolution of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed asymmetric hydrogenation reaction of beta-ketoesters are reported. Up to 99.5% ee was achieved. Under solvent-free reaction conditions, acetoacetates could be reduced with good enantioselectivity and high efficiency; a TON of 20 000 was obtained within 3.5 h. The results obtained were comparable to those when SEGPhos was applied.     

Quantum efficiency calibration of opto-electronic detector by means of correlated photons method

A new calibration method of detectors can be realized by using correlated photons generated in spontaneous parametric down-conversion (SPDC) effect of nonlinear crystal.An absolute calibration system of detector quantum efficiency is performed.And its principle and experimental setup are introduced.A continuouswave (CW) ultraviolet (351 nm),diode-pumped,frequency-doubled,and solid-state laser is used to pump BBO crystal.The quantum efficiencies of the photomultiplier at 633,702,and 789 nm are measured respectively.The coincidence peaks are observed using coincidence circuit.Some measurement factors including the filter bandwidth of trigger channel,the detector position alignment and polarization of the pump light are analyzed.The uncertainties of this calibration method are also analyzed,and the relative uncertainties of total calibration are less than 5.8%.The accuracy of this method could be improved in the future.     

高精度光谱辐射标准探测器的温度特性研究

高精度辐射定标技术是现代空间遥感的主要支撑技术之一。基于滤光片辐射计的新型光辐射标准探测器在野外、机载和星上高精度辐射定标中具有广阔的应用前景。温度特性是工程应用中影响标准探测器绝对精度和稳定性的一项关键因素。在20～60℃的宽温度范围内,对基于硅陷阱探测器的滤光片辐射计温度特性进行了系统测试和定量研究,在所获取的完备的实验数据基础上设计并研制了一套精密温控系统。实验结果显示在加入精密温控后,滤光片辐射计的温度系数降低了约一个数量级,从而有利于在不同温度工作平台上保持标准探测器的高精度。     

太阳天顶角对反演高光谱地表反射率影响分析

为了满足星上载荷高频次的在轨定标需求,常使用场地自动化定标技术将多光谱反射率反演为高光谱反射率,所以提升光谱的反演精度对提高自动化定标精度尤为重要.使用布设在敦煌辐射校正场的通道式自动化观测仪器计算从2018年9月至2019年9月的反射率;根据测量过程中太阳天顶角的不同将数据分为6组,并使用双向反射分布函数模型对不同太...