植物油中邻苯二甲酸酯含量测定结果的不确定度评定

依据GB/T 21911–2008《食品中邻苯二甲酸酯的测定》,采用GPC净化在线浓缩、气相色谱–质谱法测定植物油中的邻苯二甲酸酯类增塑剂。参照JJF1059–1999《测量不确定度的评定与表示》,以测定花生油中邻苯二甲酸二(2-乙基)己酯(DEHP)为例,对整个测量过程中不确定度的来源进行了分析,并对不确定度各个分量进行了评定和合成,取包含因子k=2(约95%置信概率),花生油中DEHP含量为11.8 mg/kg时,扩展不确定度U=1.2 mg/kg。结果表明,随机效应和曲线拟合是影响邻苯二甲酸酯检测过程中的主要因素。     

In vitro growth and activity of chondrocytes on three dimensional polycaprolactone/chitosan scaffolds

Porous polycaprolactone/chitosan blend scaffolds with various compositional proportions were prepared using a particulate‐leaching method. The pore parameters of resultant scaffolds were found to be mainly modulated by porogen. The compressive mechanical properties and hydrophilicity of scaffolds were examined by measuring their compressive modulus and stress strength as well as swelling index. Selected chondrocytes isolated from articular cartilage of knee joints of rabbits were seeded on these scaffolds, and further in vitro cultured for various periods. The growth and activity of seeded cells were estimated by counting numbers of cells proliferated on scaffolds and measuring the amounts of proteoglycans and type II collagen synthesized by the seeded cells. It was found that some scaffolds composed of proper component ratios and having appropriate pore parameters exhibited promising characteristics for the adhesion and proliferation of seeded cells while maintaining the phenotype and activity of the cells. Copyright © 2010 John Wiley & Sons, Ltd.     

不确定结构动力区间分析方法研究

将结构中的不确定性参数用区间数来表示,建立了系统的区间动力特征方程和动力控制方程.通过将Monte Carlo方法引入到区间分析中来,并改进了一般Monte Carlo方法在区间模拟中存在的缺陷,对区间动力特征方程和动力控制方程进行了求解,得到了结构的固有频率、位移响应和应力响应的区间计算结果.算例表明改进的Monte Carlo方法求解简单,具有普适性,能够给出较高精度的响应区间.     

消声器声学性能预测的子结构快速多极子边界元法

鉴于快速多极子边界元法的应用主要局限于单区域声学问题计算,发展基于子结构技术的快速多极子边界元法以计算多区域声场问题,介绍基本原理、具体实施过程以及优缺点.以带有插进口管的膨胀腔消声器为例,应用子结构快速多极子边界元法和传统边界元法计算其传递损失,通过与实验测量结果的比较,验证方法的有效性和计算精度.研究表明,快速多极子边界元法与传统边界元法相比,节点数越多,其在节省计算时间,减少计算量等方面的优势越明显.     

The normal state of high temperature oxide superconductor

Looking back on the experiments about the normal state of the high temperature superconductor (HTS), the authors point out nine important experimental results. On the basis of these results, the authors have argued that the two-dimension, two-subsystem Hamiltonian is the appropriate starting point for describing the normal state of HTS. By this Hamiltonian, using the decoupling approximation of Green’s function method by Kaga through numerical calculations, the authors have obtained the temperature dependent pseudogap in the density of states (DOS), which is consistent qualitatively with the experimental results by angle-resolved photoemission spectroscopy (ARPES). Theoretically, this Hamiltonian has the superconducting order parameter of d + s symmetry with d-wave as the main component, which is consistent with experiments. Further, the quantum electronic liquid in HTS is a near Fermi liquid in which there is coexistence of the delocalized states and nearly localized states, and there is finite probability for the nearly localized carriers to form the nearly localized carrier pairs at any finite temperature.     

磁性聚苯胺纳米微球的合成与表征

报道了具有核壳结构的Fe3O4-聚苯胺磁性纳米微球的合成方法和表征结果.微球同时具有导电性和磁性能.在优化的实验条件下,可得到饱和磁化强度Ms为55.4 emu/g,矫顽力Hc为62 Oe的磁性微球.微球的导电性随着微球中Fe含量的增加而下降.微球的磁性能则随着Fe含量的增加而增大.Fe3O4磁流体的粒径和磁性聚苯胺微球的粒径均在纳米量级.纳米Fe3O4粒子能够提高复合物的热性能.实验表明,磁流体和聚苯胺之间可能存在着一定的相互作用,但这种相互作用较为复杂,难于研究     

用频率识别平面刚架结构裂纹的遗传算法

给出含单个裂纹结构的动力有限元方程,根据结构前５阶频率的变化,来识别裂纹的位置和深度。将识别转化为多峰值的全局优化问题,给出跗算法解法此识别的运算步骤。以结构含单一裂纹的两处算例,作裂纹识别的数值试验,计算结果表明此方法是可行的,对裂纹参数的识别有较好的精神和可靠性。     

A guide to use fluorinated aromatic bulky cations for stable and high-performance 2D/3D perovskite solar cells: The more fluorination the better?

While serious stability issues impede the commercialization of perovskite solar cells(PSCs),twodimensional(2 D) perovskites based on fluorinated bulky cations have emerged as more intrinsically stable materials.However,the influence of fluorination degree of the bulky aromatic cation on the performance of resulting PSCs has not been scrutinized.Here,2 D perovskites(FxPEA)2 PbI₄(x=1,2,3,5) are grown in situ on the surface of the three-dimensional(3 D) perovskite and demonstrate effecti...     

Andrographolide Inhibits Biofilm and Virulence in Listeria monocytogenes as a Quorum-Sensing Inhibitor

Listeria monocytogenes is a major foodborne pathogen that can cause listeriosis in humans and animals. Andrographolide is known as a natural antibiotic and exhibits good antibacterial activity. We aimed to investigate the effect of andrographolide on two quorum-sensing (QS) systems, LuxS/AI-2 and Agr/AIP of L. monocytogenes, as well as QS-controlled phenotypes in this study. Our results showed that neither luxS expression nor AI-2 production was affected by andrographolide. Nevertheless, andrographolide significantly reduced the expression levels of the agr genes and the activity of the agr promoter P₂. Results from the crystal violet staining method, confocal laser scanning microscopy (CLSM), and field emission scanning electron microscopy (FE-SEM) demonstrated that andrographolide remarkably inhibited the biofilm-forming ability of L. monocytogenes 10403S. The preformed biofilms were eradicated when exposed to andrographolide, and reduced surviving cells were also observed in treated biofilms. L. monocytogenes treated with andrographolide exhibited decreased ability to secrete LLO and adhere to and invade Caco-2 cells. Therefore, andrographolide is a potential QS inhibitor by targeting the Agr QS system to reduce biofilm formation and virulence of L. monocytogenes.     

左手材料设计及透明现象研究进展

左手材料具有负的介电常数, 磁导率和折射率,它与电磁波相互作用的规律与传统材料有本质的区别.首先讨论了金属线点阵结构实现负介电常数和开口谐振环点阵结构实现负磁导率的内在机理,综述了目前实现左手材料的设计与制备方法,讨论了左手材料研究中能量如何定义以满足守恒律, 左手材料的宏观等效参数的确定,以及影响左手材料负折射相对频带带宽的因素。最后对左手材料在光子隧道效应和电磁波透明方面的应用进行了介绍,重点讨论了利用力学中的``中性夹杂'概念对电磁波透明的设计.论文还探讨了声波左手材料的概念和物理意义,介绍了用声波左手材料实现声波透明的方法.