首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   76篇
  免费   49篇
  国内免费   87篇
化学   95篇
晶体学   3篇
力学   2篇
数学   2篇
物理学   110篇
  2023年   3篇
  2022年   1篇
  2021年   5篇
  2020年   3篇
  2019年   4篇
  2018年   6篇
  2017年   5篇
  2016年   8篇
  2015年   6篇
  2014年   6篇
  2013年   6篇
  2012年   9篇
  2011年   13篇
  2010年   22篇
  2009年   13篇
  2008年   20篇
  2007年   13篇
  2006年   9篇
  2005年   8篇
  2004年   13篇
  2003年   6篇
  2002年   10篇
  2001年   5篇
  2000年   9篇
  1999年   2篇
  1998年   1篇
  1997年   1篇
  1994年   2篇
  1993年   2篇
  1992年   1篇
排序方式: 共有212条查询结果,搜索用时 15 毫秒
91.
Gluon propagator is investigated for pure Yang-Mills SU(3) gauge theory in field-strength approach. It isfound that instantohs provide a homogeneous solid-like medium background which generates finite nonzero momentumgluon propagator and gluon receives effective mass.  相似文献   
92.
Carbon nanotubes (CNTs) were synthesized by the catalytic decomposition of methane at 773, 873 and 973 K. Structures of these carbon nanotubes were characterized by TEM, HRTEM, XRD and Raman spectra, respectively. The results showed that with the increase of preparation temperature, the d 002 value of the CNTs decreased, while the L a values and the degree of crystallinity of the samples increased. Electrochemical lithium insertion properties of the CNTs used as positive electrodes in CNTs/Li cells were also investigated. The first charge capacities of CNTs/Li cells were 290, 254 and 202 mAh/g for samples produced at 773, 873 and 973 K, respectively. The sample from 773 K showed a larger charge capacity, which is attributed to the accommodation of lithium at microcavities, at edges of graphitic layers and at the surface of single graphitic layers. Its potential hysteresis during Li insertion and deinsertion processes may be related to the interstitial carbon atoms. Electronic Publication  相似文献   
93.
对化学反应进行模拟的关键是找到准确的化学反应抽样几率及位阻因子.本文对国内外应用较普遍的两种计算复合反应位阻因子的方法,即正、逆反应速率法进行了详细的比较,并用不同的分子对这两种方法分别进行了模拟.最后将模拟结果与理论计算结果进行了比较,发现随着稀薄程度的增加;正反应速率法的模拟结果与理论吻合较好.  相似文献   
94.
采用充放电测试和交流阻抗测试研究了硝酸锂作电解液添加剂对锂硫电池电化学性能的影响. 采用电子扫描显微镜观察分析了添加剂对锂负极的影响, 探讨了硝酸锂的作用机理.  结果表明, 采用硝酸锂作为锂硫电池电解液的添加剂, 可以在锂负极表面形成具有钝化负极活性表面及保护锂负极的界面膜.  该膜可以抑制电解液中高价态聚硫离子与锂负极的副反应, 避免在锂负极表面形成不可逆的硫化锂, 从而提高锂硫电池的循环性能和放电容量. 采用硝酸锂作添加剂的锂硫电池首次放电比容量达1172 mA?h/g, 循环100次比容量保持为629 mA?h/g.  相似文献   
95.
建立一种测定噻菌灵的荧光分析新方法.铽(Ⅲ)为弱荧光物质,噻菌灵的加入对其荧光强度有显著的增强效应.实验结果表明,荧光增强值△F与噻菌灵的浓度在2-200nmol/L内呈良好的线性关系,r=0.9970,检出限为0.83nmol/L.本法用于实际样本中噻菌灵的测定,结果令人满意.  相似文献   
96.
为了抑制光码分多址中的多址干扰及多噪音,提出了一种引入光硬限幅器及基于最大值判决的并行干扰抑制器的光码分多址系统.在系统中存在APD噪音及热噪音的情况下,研究了系统对多址干扰的抑制作用.系统采用光正交码作为地址码,APD作为光电检测器,分析推导了系统的误码率表达式.根据所得的误码率表达式,进行了数值仿真,比较了该方法与其他方法的多址干扰抑制效果.研究结果表明:与现有其他有效方法(单比特引入一个光硬限幅器、单比特引入两个光硬限幅器、多比特传输、多比特引入光硬限幅器、基于最大值判决的并行干扰抑制器等)相比,本系统对多址干扰的抑制作用优于并行干扰抑制器、多比特传输、多比特引入光硬限幅器方法|当接收功率较低时,该系统优于引入双光硬限幅器的方法,因此可以有效的抑制多址干扰及多噪音.  相似文献   
97.
Cui  Wen  Liu  Chao  Zhuo  Xiao-Bin 《Chemistry of Natural Compounds》2021,57(6):1086-1089
Chemistry of Natural Compounds - The first total synthesis of anti-inflammatory cyclic peptide fanlizhicyclopeptide B based on the Mitsunobu reaction is reported. The pre-made Fmoc-Tyr-OAllyl...  相似文献   
98.
Starting from famous Schr\"{o}dinger equation within the framework of semi-classical theory of light-matter interaction, we firstly obtain the analytical non-resonant solutions of the driven bipartite system's entanglement dynamics in independent and coherent double pathways. Numerical simulations show that under non-resonant condition, entanglement sudden death and revival between these transition patterns behave quite differently, indicating the utmost importance of transition pathways' interference. Furthermore, the laser pulse's area and detuning exert significant but quite distinct influences on the entanglement dynamics. Our analyses are helpful in manipulating entanglement in current experimental technology.  相似文献   
99.
Data quality monitoring (DQM) plays an important role in data taking at the BESⅢ experiments. DQM is used to monitor detector status and data quality. A DQM framework (DQMF) has been developed to make it possible to reuse the BESⅢ offline reconstruction system in the online environment. In this framework, the DQMF can also simulate a virtual data taking environment, transfer events to the event display, publish histograms to a histogram presenter in a fixed interval, and dump histograms into a ROOT file. The DQMF has been stably running throughout BESⅢ data taking.  相似文献   
100.
The VUV double photoionizations of small molecules (NO,CO,CO2 ,CS2 ,OSC and NH3 ) were investigated with photoionization mass spectroscopy using synchrotron radiation. The double ionization energies of molecules were determined with photoionization efficiency spectroscopy. The total energies of these molecules and their parent dications (NO2+ ,CO2+ ,CO2+2 ,CS2+2 ,OSC2+ and NH2+3 ) were calculated using the Gaussian 03 program and Gaussian 2 calculations. Then,the adiabatic double ionization energies of the molecules were predicated by using high accuracy energy mode. The experimental double ionization energies of these small molecules were all in reasonable agreement with their respective calculated adiabatic double ionization energies. The mechanisms of double photoionization of these molecules were discussed based on a comparison of our experimental results with those predicted theoretically. The equilibrium geometries and harmonic vibrational frequencies of molecules and their parent dications were calculated by using the MP2 (full) method. The differences in configurations between these molecules and their parent dications were also discussed on the basis of theoretical calculations.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号