原子特征谱线对法测量火焰温度的温标元素研究

研究发现煤炭、木材、汽油、柴油等燃料的火焰光谱中都存在Na(589.,589. nm)和K(766.,769. nm)特征辐射谱线对,谱线对的相对强度比与温度有关,由此可以测量火焰温度.本文介绍了测量原理和方法,对K、Na、Fe、Zn作为温标元素时的误差传递进行了分析,得出K、Na作为温标元素时误差传递大,测量精度低; Fe、Zn作为温标元素时误差传递小,测量精度高.     

Development of Yangbajing air shower core detector for a new EAS hybrid experiment

Aiming at the observation of cosmic-ray chemical composition in the "knee" energy region, we have been developing a new type of air-shower core detector(YAC, Yangbajing Air shower Core detector array) to be set up at Yangbajing(90.522?E, 30.102?N, 4300 m above sea level, atmospheric depth: 606 g/m2) in Tibet, China.YAC works together with the Tibet air-shower array(Tibet-Ⅲ) and an underground water Cherenkov muon detector array(MD) as a hybrid experiment.Each YAC detector unit consists of lead plates of 3.5 cm thickness and a scintillation counter which detects the burst size induced by high energy particles in the air-shower cores.The burst size can be measured from 1 MIP(Minimum Ionization Particle) to 106 MIPs.The first phase of this experiment, named"YAC-Ⅱ ", consists of 16 YAC detectors each with a size of 40 cm×50 cm and distributed in a grid with an effective area of 10 m2.YAC-Ⅱ is used to check hadronic interaction models.The second phase of the experiment, called"YAC-Ⅱ ", consists of 124 YAC detectors with coverage of about 500 m2.The inner 100 detectors of 80 cm×50 cm each are deployed in a 10×10 matrix with a 1.9 m separation; the outer 24 detectors of 100 cm×50 cm each are distributed around these to reject non-core events whose shower cores are far from the YAC-Ⅱ array.YAC-Ⅱ is used to study the primary cosmic-ray composition, in particular, to obtain the energy spectra of protons, helium and iron nuclei between 5×1013eV and 1016 eV, covering the "knee" and also connected with direct observations at energies around 100 TeV.We present the design and performance of YAC-Ⅱ in this paper.     

第28届全国高中化学竞赛(决赛)有机化学试题解析

利用有机合成反应及反应机理对第28届全国高中生化学竞赛（决赛）有机化学试题部分做了较为详细的解析,以供相关化学同行及参赛学生参考。     

高离化态金离子的辐射复合及其退激发过程的理论研究

利用基于多组态Dirac-Fock方法的程序包GRASP92和RATIP以及最新发展的RERR06程序,详细计算了高离化态金离子(类镍Au51+、类铜Au50+和类锌Au49+)俘获一个自由电子到nl(n=4—8,l=0—3)壳层的辐射复合谱以及相应的辐射退激发谱.理论计算的辐射复合谱很好地重现了实验谱.研究结果表明:对类镍Au51+、类铜Au50+和类锌Au49+而言,将一个自由电子俘获到n=4壳层的概率最大;在辐射复合过程之后,处在n=4壳层的俘获电子的辐射退激发谱线最强,并且体现了整个辐射退激发谱的主要特征.     

质子辐照对永磁合金微观结构演化的研究

钐钴和钕铁硼稀土永磁合金已经广泛应用于粒子加速器的波荡器和其他器件中,作为加速器的重要组成部分,永磁合金在辐照环境中长期服役会出现磁性能损失的现象,这会影响束流的品质.为了探讨产生这个现象的微观机理,采用透射电镜对质子辐照前后的钐钴和钕铁硼稀土永磁合金进行了微观结构演化的表征和分析,统计了由辐照析出的纳米晶体积密度和粒径分布,并讨论了微观结构演化对宏观磁性能损失的影响.结果表明,随着质子辐照损伤程度的增加,永磁合金的微观结构从单晶结构转变为纳米晶多晶结构,且纳米晶和基体的晶体结构相同.钕铁硼的纳米晶体积密度先增大后减小,粒径分布先增大后不变;钐钴的纳米晶体积密度逐渐减小,粒径逐渐增大.在2 dpa的质子辐照损伤程度下,钕铁硼稀土永磁合金比钐钴永磁合金的非晶化趋势更明显.     

Spacing-adjustable and wavelength-tunable multiwavelength fibre laser with nonlinear Brillouin gain and birefringence fibre loop mirror

This paper demonstrates a room-temperature multiwavelength fibre laser with spacing-adjustability and wavelength-tunability. The nonlinear gain of self-excited stimulated Brillouin scattering can suppress mode competition induced by homogeneous broadening of Erbium-doped fibre. With the use of a birefringence fibre loop filter, the wavelength spacing can be adjusted by changing the length of the used birefringence fibre, and the lasing wavelengths can be finely tuned through modifying the filtering profile of the birefringence filter. Multiwavelength output with spectral spacing as small as 0.076~nm and a wavelength number of more than 80 has been successfully produced.     

Xe原子的等核及等电子系列离子径向波函数的性态研究

基于相对论多组态Dirac-Fock方法(MCDF方法),详细研究了Xe及类Xe离子的束缚和连续的f轨道波函数的性态,分析了沿等核系列和等电子系列f轨道径向波函数的塌缩现象.在此基础上,进一步讨论了轨道波函数的塌缩导致的强弛豫效应及其对类Xe离子的4d10-4d94f跃迁能和振子强度的影响.     

锂原子光电离过程中的弛豫效应

利用基于多组态Dirac-Fock方法的程序包GRASP92和RATIP以及在此基础上最新发展的RERR06程序,计算了锂原子1s²nl(n=2,3; l=s, p) 的内壳层和外壳层的光电离截面. 计算中详细考虑了光电离过程中的弛豫效应. 结果表明：在锂原子内壳层电子的光电离过程中弛豫效应较强,而在外壳层电子的光电离过程中弛豫效应较弱. 另外,相应于不同态的内壳层光电离过程,其弛豫效应的影响也不同,对激发态的影响比对基态的影响大,对高激发态 关键词： 多组态Dirac-Fock方法 光电离截面 弛豫效应     

PbS纳米棒的水热合成与表征

以乙酸铅和硫脲为主要原料,十二烷基磺酸钠和十六烷基三甲基溴化铵为表面活性剂,在120℃反应12h,水热法制备了PbS纳米棒.并利用X射线粉末衍射(XRD)、透射电子显微镜(TEM)和高分辨电子显微镜(HRTEM)等手段对产物进行了表征,实验结果表明：产物为纯相立方结构的PbS单晶纳米棒.考察了乙酸铅和硫脲间的摩尔比以及反应温度对合成产物的影响,并初步探讨其形成机理.     

磁场中拓扑物态的量子输运

拓扑物态包括拓扑绝缘体、拓扑半金属以及拓扑超导体.拓扑物态奇异的能带结构以及受拓扑保护的新奇表面态,使其具有了独特的输运性质.拓扑半金属作为物质的一种三维拓扑态具有无能隙的准粒子激发,根据导带和价带的接触类型分为外尔半金属、狄拉克半金属和节线半金属.本文以拓扑半金属为主回顾了在磁场下拓扑物态中量子输运的最新工作,在不同...