层状磁电复合材料谐振频率下的巨磁电容效应

对三明治复合结构Tb_xDy_1-xFe_2-y/Pb(Zr, Ti)O₃/Tb_xDy_1-xFe_2-y的电容与频率及磁场的函数关系进行了实验和理论研究. 实验发现,该复合材料样品的电容随频率的增加而出现多个谐振峰,并且其谐振点随磁场的增加而发生频移. 在谐振点附近,观察到样品的阻抗随磁场的增加由容抗性转变为感抗性,从而同时观察到巨大的正磁电容效应和负磁电容效应. 由复合材料的弹性力学本构方程出发,对该类样品的电容随频率及磁场的变化进行了理论模拟. 结果显示,模拟曲线与实验结果符合得很好. 理论表明该磁致伸缩/压电复合材料的磁电容效应源于磁场诱变的铁磁相柔顺系数. 关键词： 层状复合材料 界面弹性耦合 磁电容效应     

Electric field-induced stress birefringence in layered composites PbZr1-xTixO3/Polycarbonate

Electro-optical composites based on the product of electro-strictive and elasto-optical effects are developed.Layered composites of PbZr 1 x Ti x O 3 and polycarbonate are synthesised.Their electro-optical properties are studied.The nominal transverse electro-optical coefficient of the composite is observed to be about 3.6 times larger than that of LiNbO 3.Experiments and theoretical analyses show that the electro-optical effect of the composite has a strong ’size effect’.With the ratio of thickness/length decreasing or the width of elasto-optical phase increasing,the half-wave electric field intensity increases but the transverse electro-optical coefficient decreases for the layered composite.     

Resonance Energies,Absorption Oscillator Strengths and Ionization Potentials for the Element Hassium （Z = 108）

On the basis of successfully predicting low-lying energy levels for the element fermium （Z = 100）, we calculate the resonance energies, absorption oscillator strengths and the first ionization potential of the element hassium （Z = 108） by taking important relativistic and improved electron correlation effects into account using the multiconfiguration Dirac Fock method. These calculations are carried out with the aim of assisting experimental investigations of hassium.     

Theoretical study on decay of the 4d core-excited states of Cs III

In a recent XUV photoabsorption spectrum of Cs Ⅲ ions by Cummings and O＇Sullivan [2001 J. Phys. B 34 199], rather large linewidths were found for the 4d^95s^25p^6 - 4d^105s^25p^5 transition which are quite in disagreement with corresponding quasi-relativistic multiconfiguration Hartree Fock （MCHF） calculation. In the present work, a detailed multiconfiguration Dirac-Fock study has been carried out to explore this discrepancy. Owing to the detailed consideration of electron correlation effects, some ‘forbidden＇ Auger decay channels, such as 4d^105s^25p^35d and 4d^105s^05p^6, would become ‘open＇. As a result, remarkable improvement of the linewidths has been obtained in our calculation. Furthermore, the theoretical Auger spectrum of the 4d^ 95s^25p^6 core-excited states of Cs Ⅲ ions is Riven in the present work.     

类氢U91+离子的辐射复合及其辐射退激发过程的理论研究

基于多组态Dirac-Fock理论方法,利用GRASP92和RATIP以及在此基础上最新发展的RERR06程序,对类氢U⁹¹⁺（1s）离子的辐射复合截面以及辐射退激发过程进行了详细的理论研究.系统地计算了具有确定能量的连续电子被处于基态的类氢U⁹¹⁺（1s）离子俘获到nl （1≤n≤8, 0≤l≤6）轨道形成类氦U⁹⁰⁺（1snl）离子的辐射复合截面,并研究了这辐射复合末态退激发谱的相对强度.研究发现,类氢U⁹¹⁺（1s）离子辐射复合到不同轨道的截面随其主量子数的增大而显著减小;同时,辐射复合末态的退激发对Kα谱线的相对强度有重要影响. 关键词： 辐射复合 多组态Dirac-Fock理论方法 辐射退激发     

北京谱仪Ⅲ飞行时间计数器系统刻度中的关联分析

利用电子对事例对北京谱仪Ⅲ飞行时间的测量误差, 以及不同测量之间的关联因子随击中位置的变化进行了仔细的研究. 加权的飞行时间由不同的测量值及其相关的误差矩阵计算而得. 蒙特卡罗研究表明. 为北京谱仪Ⅲ开发的关联分析算法 可以正确地处理包含公有误差项的多个实验测量结果的合并, 并且能够为粒子鉴别提供可靠的飞行时间信息.     

新的氨基酸受体的合成和分子识别性质研究

从双氨基甲基手性双环胍出发,经三步反应合成了由稳定的共价键桥联双环胍、氮杂冠醚和萘环的氨基酸受体1.液-液竞争萃取和^1HNMR实验表明受体对氨基酸两性离子具有较好的侧链选择性和对映选择性,能够选择性地将L-芳香族氨基酸从水相转移到二氯甲烷有机相。     

Pd(0)/iodide salt-mediated Heck reaction of aryl nonaflates: Application to the synthesis of 2-(1-alkenyl)phenylphosphonates

Iodide salt, such as NaI, KI or n-Bu₄NI (TBAI), rather than bromide or chloride salt, was found to play a key role in the Pd(0)-catalyzed Heck reaction of aryl nonaflates and terminal alkenes. In the presence of PdCl₂(PPh₃)₂, NaI or TBAI in DMF, a class of 2-(1-alkenyl)phenylphosphonates was first synthesized via the reaction of o-phosphonylphenyl nonaflates with alkenes, the yields, regioselectivities and stereoselectivities were much dependent on the nature of the substituents. In case of the aryl nonaflates without bearing the sterically hindered phosphonyl group with the alkenes, the reactions proceeded more smoothly under the same conditions, leading to the linear products regioselectively in good to excellent yields. A rationale for this reaction is discussed.     

加速溶剂萃取-高效液相色谱法测定皮革和纺织品中含氯苯酚的含量

建立了测定皮革和纺织品中含氯苯酚的高效液相色谱/二极管阵列检测器(HPLC/DAD)分析方法.采用加速溶剂萃取法萃取不同类型的皮革和纺织品样品,以正己烷为提取剂,在10.34 MPa和120 ℃下静态循环提取3次,提取液经氮吹仪浓缩近干,以正己烷溶解并定容;采用C18柱,以乙腈/0.5%乙酸溶液为流动相,DAD波长为214 nm进行高效液相色谱分离与分析.结果表明: 四氯苯酚和五氯苯酚质量浓度在0.1～20 mg/L范围内具有良好的线性关系(r＞0.9999);平均回收率在 96.0%～101.5% 之间;相对标准偏差为 0.50%～5.5% (n=7);方法的检出限为0.02 mg/kg,符合欧盟指令0.05 mg/kg的限量规定.本方法高效、简便、自动化程度高,准确可靠,是一种可同时快速测定皮革和纺织品中含氯苯酚的新方法.     

高岭石/苯甲酰胺插层复合物的热分解行为及脱嵌反应动力学

以高岭石/二甲基亚砜为前驱体,利用置换法制备了高岭石/苯甲酰胺插层复合物。XRD和FTIR分析表明苯甲酰胺进入高岭石层间并与其形成新的氢键。采用TG、DSC研究了插层复合物的热分解行为。结果表明复合物在加热过程中发生两步分解,第一步是插层复合物的分解,即插层剂分子于231℃发生脱嵌,第二步为高岭石脱羟基的过程。针对第一阶段的脱嵌反应,采用等转化率法改进后的迭代法、Malek法以及Dollimore法等动力学方法计算得到了完整的动力学三因子:活化能Ea=75.4kJ.mol-1,指前因子A的范围为4.9×1010~8.8×1010s-1,动力学方程为:G(α)=[1-(1-α)1-n]/(1-n),f(α)=(1-α)n。