Theoretical studies on the one- and two-photon absorption properties of azulenylporphyrins and azulene-fused porphyrins

The electronic structures, one-photon absorption (OPA) and two-photon absorption (TPA) properties of the azulenylporphyrins and azulene-fused porphyrins have been comparatively studied by using DFT/B3LYP/6-31G(d) and the ZINDO/SDCI method. With the number of azulenyl groups increasing, the OPA wavelengths of all molecules are red-shifted in 400--600~nm and the two-photon absorption cross section is gradually enlarged. The azulene-fused structures facilitate an expanding conjugated area and increasing TPA cross section. The origin of TPA properties of studied compounds is studied with a two-level model. In summary, the azulene-fused porphyrins exhibit strong two-photon absorption.     

含碳能源直接制氢的热力学分析与实验研究

本文在对构建的含碳能源直接制氢体系进行热力学分析的基础上,建造了含碳能源直接制氢近零排放定容实验系统,并进行了不同参数下的实验研究。热力学分析表明本文构建的系统不仅存在合适的反应条件,而且在此反应条件下可以实现体系的热平衡。实验结果表明了该系统的可行性,实现了气态产物中氢含量大于80％,二氧化碳及一氧化碳含量均小于0.1％,达到了直接制氢和近零排放的目标。     

近垒能区6Li+208Pb熔合激发函数测量

测量了6Li+208Pb熔合反应近垒能区全熔合截面,并与考虑非弹道耦合和不考虑耦合的CCFUS程序计算做了比较. 结果表明在垒上能区,破裂使熔合截面减小,在垒下能区,破裂对熔合截面的影响基本上可以忽略.     

探讨实验数据处理的认知结构深化物理实验教学改革

应用教育心理学的理论和方法，研究了学生实验数据处理能力的认知结构，并在此基础上对大学物理实验的教学提出了建议．     

再谈恢复系数的物理意义

1998年第4期<物理通报>发表了徐志和的文章"恢复系数的意义及范围"[1],这篇文章是从动量的角度讨论恢复系数的物理意义,<大学物理>上也发表过有关恢复系数的文章[2～3],他们也只是从速度或者动量的角度去讨论恢复系数,并没有从能量方面去探讨.本文完全从能量的角度去讨论这个问题,而且结论简单富有意义,使得恢复系数的物理含义更加丰富多彩.     

BFEL高压脉冲调制器幅度稳定性的改进

 北京自由电子激光装置(BFEL)的高功率脉冲调制器中,采用de-Qing电路作为主要脉间稳幅手段,在不改变高压大功率元件的条件下,通过定量分析及细致实验,使稳幅精度 从0.5%提高到小于0.1%,从而提高了BFEL激光输出的稳定性。     

空间有源消声的微机控制

本文讨论用通用微机控制空间有源消声．以修正的PID（比例、积分、微分）算法加上逻辑判断构成的控制软件，使得系统收敛迅速，跟踪速度快，消声效果令人满意，而且系统工作稳定可靠，     

Generalized Goodman–Harpe–Jones Construction of Subfactors, II

We build some exceptional representations of Birman–Wenzl algebras from the data of certain conformal embeddings. As a result we construct new finite depth subfactors whose principal graphs are completely determined. Received: 16 February 1996 / Accepted: 25 July 1996     

Angular momentum effect in prescission particle multiplicities for a light system by diffusion model

The effect of angular momentum on the competition between fission and particle emission during light system fission process was studied via fission diffusion model. The prescission particle multiplicities were found to increase with decreasing angular momentum. The experimental prescission proton and α particle multiplicities can be fitted for 10.6 MeV/nucleon ⁸⁴Kr(²⁷Al,binary fission) reaction with this model. Entrance channel effect found in [1] is proved to be angular momentum effect.     

Paul阱中两个超冷离子的量子统计特性

讨论两个囚禁在Ｐａｕｌ阱的对称轴上的超冷离子的量子统计特性，可以发现，它们的稳定囚禁不仅与阱的稳定区有关，而且与它们自身的自旋和电荷数大小有关。