Absolute Orientation of Molecules with Competing Hydrophilic Head Groups at the Air/Water Interface Probed with Sum Frequency Generation Vibrational Spectroscopy

和频振动光谱(SFG-VS)研究中由基团在界面上取向所引起的光谱增强或相消的干涉现象为研究分子在界面上的绝对取向提供了一种直接的测量方法. 这一方法比SFG实验中复杂的相位测量方法更为直接和简单可行. 以在空气/水界面取向已知的对羟基苯腈(PCP)分子的氰基(-CN)基团为相位参考来获得3,5-二甲基对羟基苯腈(35DMHBN)和2,6-二甲基对羟基苯腈(26DMHBN)分子在空气/水界面的取向信息. 通过对这三种分子的水溶液和它们两两混合溶液界面上-CN基团和频振动光谱强度的比较,发现在空气/水界面的3     

Tm~(3+)/Yb~(3+)共掺激光晶体的本征光学双稳特性分析与参数优化

理论研究了650nm激光雪崩抽运Tm3+/Yb3+共掺激光晶体的本征光学双稳态.基于系统的非线性耦合速率方程理论,数值分析了Tm3+/Yb3+离子能级布居数的本征光学双稳性、系统参数对光学双稳态的影响和双稳迟滞回线的动态变化.数值结果给出了光子雪崩机制下Tm3+/Yb3+共掺激光晶体的可见与红外光谱发光的本征光学双稳态;指出了通过优化Tm3+/Yb3+离子浓度比,选取低声子能晶体基质和采用晶体冷却技术,以及调谐抽运光与Tm3+离子激发态跃迁能隙满足共振频率匹配,可以有效地增强本征光学双稳效应;通过微调谐抽运光波长和控制抽运光强变化速率,可以实现动态调控的本征光学双稳态.     

Extraordinary optical transmission through metal gratings with single and double grooved surfaces

We investigate the transmission properties of a normally incident TM plane wave through metal films with periodic parabolic-shaped grooves on single and double surfaces using the finite-difference-time-domain method. Nearly zero transmission efficiency is found at wavelengths corresponding to surface plasmon excitation on a flat surface in the case where the single surface is grooved. Meanwhile, resonant excitation of surface plasmon polariton (SPP) Bloch modes leads to a strong transmission peak at slightly larger wavelengths. When the grating is grooved on double surfaces, the transmission enhancement can be dramatically improved due to the resonant tunnelling between SPP Bloch modes.     

Mei symmetry and Mei conserved quantity of Appell equations for a variable mass holonomic system

Mei symmetry and Mei conserved quantity of Appell equations for a variable mass holonomic system are investigated. Appell equations and differential equations of motion for a variable mass holonomic system are established. A new expression of the total first derivative of the function with respect of time t along the systematic motional track curve, and the definition and the criterion of Mei symmetry for Appell equations under the infinitesimal transformations of groups are given. The expressions of the structural equation and Mei conserved quantity for Mei symmetry in Appell are obtained. An example is given to illustrate the application of the results.     

A three-step system calibration procedure with error compensation for 3D shape measurement

System calibration, which usually involves complicated and time-consuming procedures, is crucial for any three-dimensional （3D） shape measurement system based on vision. A novel improved method is proposed for accurate calibration of such a measurement system. The system accuracy is improved with considering the nonlinear measurement error created by the difference between the system model and real measurement environment. We use Levenberg-Marquardt optimization algorithm to compensate the error and get a good result. The improved method has a 50% improvement of re-projection accuracy compared with our previous method. The measurement accuracy is maintained well within 1.5% of the overall measurement depth range.     

轴对称-折叠组合腔CO_2激光器原理性实验研究(英文)

报道了轴对称-折叠组合腔CO2激光器原理性实验研究,激光器能在CW模式下成功运行。研究得到了激光器最佳的气体比率和气体压强。通过研究CO2激光器的不同方面,如激励门电压和输出功率等,发现它们随着放电电流的变化而变化。通过实验得到了激光光束的光斑和聚焦的实验光斑,并模拟了光强分布。激光器已经成功的组建、运行和调试,获得的最大输出功率为58 W。     

Synthesis and characterization of Sr3Al2O6：Eu2＋, Dy3＋ phosphors prepared by sol-gel-combustion processing

A type of red luminescent Sr3Al2O6:Eu2+, Dy3+ phosphor powder is synthesised by sol-gel-combustion processing, with metal nitrates used as the source of metal ions and citric acid as a chelating agent of metal ions. By tracing the formation process of the sol-gel, it is found that it is necessary to reduce the amount of NO3- by dropping ethanol into the solution for forming a stable and homogeneous sol-gel. Thermogravimetric and Differential Scanning Calorimeter Analysis, x-ray diffractionmeter, scanning electron microscopy and photoluminescence spectroscopy are used to investigate the luminescent properties of the as-synthesised Sr3Al2O6:Eu2+, Dy3+. The results reveal that the Sr3Al2O6 crystallises completely when the combustion ash is sintered at 1250 C. The excitation and the emission spectra indicate that the excitation broadband lies mainly in a visible range and the phosphors emit a strong light at 618 nm under the excitation of 472 nm. The afterglow of (Sr0.94Eu0.03Dy0.03)3Al2O6 phosphors sintered at 1250 ℃ lasts for over 1000 s when the excited source is cut off.     

120 W high repetition rate Nd:YVO<Subscript>4</Subscript> MOPA laser with a Nd:YAG cavity-dumped seed laser

A master oscillator power amplifier (MOPA) system in which the output from an end-pumped Nd:YAG oscillator cavity dumped at 500 kHz is scaled up by a four-stage Nd:YVO₄ amplifier is reported. Decrease in extraction efficiency of the amplifier chain with crystals different from that in the oscillator was analyzed. With the 5.4 W seed output, 118 W of power was extracted from the amplifier chain at the pump power of 345 W, with an extraction efficiency of 34.2% and an overall optical–optical efficiency of 30.9% for the MOPA system. The beam quality factors were measured as M _x ²=1.45 and M _y ²=1.59 in two orthogonal directions, respectively.     

基于道格拉斯格式的宽角有限差分光束传播法分析大角度交叉波导

交叉波导是集成光学中的一种重要的器件单元，针对大角度交叉波导的结构及折射率分布，运用基于广义道格拉斯算子的宽角多步有限差分光束传播法模拟大角度交叉波导的传输特性，数值计算出波导中的光场的分布。与Crank-Nicholson格式的有限差分光束传播法相比，该算法在几乎不增加计算时间和计算机内存资源的情况下，结合了广义道格拉斯格式的有限差分光束传播法截断误差小[只有o(△x)^4]和宽角多步法所具有较高精度的优点，是光波导器件理想的数值模拟工具。在此基础上计算分析了大角度交叉波导的输出分支波导的能量与交叉角度的关系，以及交叉角度对波导间能量耦合的影响。这为实际的设计制作光器件的工作提供了极好的基础。