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41.
用第一性原理的FP-LMTO能带计算方法研究了重费米子化合物LiV2O4的电子结构.结果表明:费米面附近的导带是由V原子的3d电子形成的宽度为2.5eV的窄能带,是3d态在立方晶体场中具有t2g对称性的子带;它与O的2p轨道构成的能带有近1.9eV的能隙.计算得出的费米能处电子态密度和线性电子比热系数分别是11.1 states/eV f.u.和26.7 mJ/molK2.费米面处的能带色散具有电子型和空穴型两种,呈现出一种复杂的费米面结构.LSDA以及LDA+GGA计算表明, LiV2O4有一个磁矩为每个钒原子1.13μB,总能比LDA基态低约148 meV/f.u.的铁磁性基态.由目前的能带结构计算的结果无法确定这一类Kondo体系的局域磁矩的来源,表明这一化合物中的重费米子行为可能有别于在含有4f和5f稀土的重费米子合金中观察到的局域磁矩与传导电子的交换作用机制,其中存在量子相变的可能. 相似文献
42.
Cardiac pacing is a medical device to help human to overcome arrhythmia and to recover the regular beats of heart. A helical
configuration of electrode tip is a new type of cardiac pacing lead distal tip. The helical electrode attaches itself to the
desired site of heart by screwing its helical tip into the myocardium. In vivo experiments on anesthetized dogs were carried
out to measure the acute interactions between helical electrode and myocardium during screw-in and pull-out processes. These
data would be helpful for electrode tip design and electrode/myocardium adherence safety evaluation. They also provide reliability
data for clinical site choice of human heart to implant and to fix the pacing lead. A special design of the helical tip using
strain gauges is instrumented for the measurement of the screw-in and pull-out forces. We obtained the data of screw-in torques
and pull-out forces for five different types of helical electrodes at nine designed sites on ten canine hearts. The results
indicate that the screw-in torques increased steplike while the torque–time curves presente saw-tooth fashion. The maximum
torque has a range of 0.3–1.9 N mm. Obvious differences are observed for different types of helical tips and for different
test sites. Large pull-out forces are frequently obtained at epicardium of left ventricle and right ventricle lateral wall,
and the forces obtained at right ventricle apex and outflow tract of right ventricle are normally small. The differences in
pull-out forces are dictated by the geometrical configuration of helix and regional structures of heart muscle. 相似文献
43.
The nonlinear Schrödinger equation is of tremendous interest in both theory and applications. Various regimes of pulse propagation in optical fibers are modeled by some form of the nonlinear Schrödinger equation. In this paper we introduce sequential and parallel split-step Fourier methods for numerical simulations of the nonlinear Schrödinger-type equations. The parallel methods are implemented on the Origin 2000 multiprocessor computer. Our numerical experiments have shown that these methods give accurate results and considerable speedup. 相似文献
44.
Reaction of O-acyl-protected glycosylthiols with dichloromethane afforded readily glycosylthiomethyl chlorides, which gave with sodium azide the corresponding glycosylthiomethyl azides 17-22. Reaction of these azides with dicyclopentadiene as dipolarophile led to tandem 1,3-dipolar cycloaddition/retro-Diels-Alder reaction furnishing the parent 1-glycosylthiomethyl-1,2,3-triazoles 23-25. Reaction of azides with acetylene derivatives gave directly 1-glycosylthiomethyl-1,2,3-triazoles which are ring-substituted. 相似文献
45.
界面张力在基板诱导共混物分散相粒子粗化生长加速现象中的作用 总被引:1,自引:0,他引:1
通过相差显微镜和计算机图像处理来研究两相聚合物体系的粗化过程 .将具有不同聚比的乙烯 聚醋酸乙烯酯 (EVAc)共聚物与聚丙烯 (PP)共混 ,制备不同相界面张力的系列共混物薄膜 .观察了在玻璃基板的作用下 ,不同界面张力体系的分散相粒子粗化行为 ,发现界面张力在约 0 4 8·1 0 - 5N cm以上的体系中分散相粒子的粗化有明显的加速现象 ,粒子体积生长与时间关系的指数大于 1 0 ;而两相界面张力较低的情况下 ,选择具有不同表面极性的基板对同一体系试验 ,我们均未发现有粗化加速现象产生 ,且采用不同基板之间的试验结果差异很小 ,亦即当高分子共混物的相界面张力大于一定值时 ,仅与基板存在有关 ,粒子的粗化行为被加速 相似文献
46.
Weihua Pu Xiangming He Li Wang Zheng Tian Changyin Jiang Chunrong Wan 《Journal of membrane science》2006,280(1-2):6-9
A novel process was proposed for preparation of microporous poly(acrylonitrile–methyl methacrylate) (P(AN–MMA)) membranes by phase inversion techniques using ultrasonic humidifier. Being prepared by dissolving the polymer (PAN–MMA) in the N,N-dimethylformamide (DMF) solution with mechanical stirring, the homogenous casting solution was cast onto a clean glass plate. Successively, the glass plate was exposed to the water vapor produced by ultrasonic humidifier, inducing the phase inversion. It is found the pore size is much more uniform across the cross-section of the membrane than that of the porous membrane prepared by conventional water bath coagulation technique. The microporous membranes were directly obtained after the washing and drying. It had about 1–5 μm of pores and presented an ionic conductivity of 2.52 × 10−3 S/cm at room temperature when gelled with 1 M LiPF6/EC-DMC (1:1 vol.%) electrolyte solution. The test cells with the gel electrolytes prepared from as-prepared microporous membranes showed stable cycling capacities, indicating that the microporous membrane, which was prepared from cheap starting materials acrylonitrile and methyl methacrylate, can be used for the gel electrolyte of lithium batteries. 相似文献
47.
希土硝酸盐冠醚Yb(NO3)3·3H2O/B15C5配合物的研究 总被引:2,自引:0,他引:2
用改进的半微量相平衡方法研究了Yb(NO_3)_3·3H_2O-Bl5C5-CH_3COCH_3三元体系在18℃时的溶解度,测定了各液相的折光率。结果指出只有一种化学计量的配合物(Yb(NO_3)_3·B15C5·3H_2O·2CH_3COCH_3)生成。分离、洗涤、浓硫酸干燥器中恒重后,经化学分析,确定配合物的组成为:Yb(NO_3)_3·B15C5·3H_2O·065CH_3COCH_3。用红外光谱、DTG、TG及DSC等对配合物进行了研究。测得配合物的脱溶剂与热分解的热焓值(△H)。按照Kissinger法,求得配合物热分解过程的表现活化能。 相似文献
48.
49.
Sodium hydrogen sulfite was used to promote condensation of o-phenylenediamine with aromatic aldehydes in dimethylformamide to obtain the corresponding 2-arylbenzimidazoles. The procedure
is simple and convenient, and it implies inexpensive promoter and is characterized by short reaction time and easy purification
of the final products.
Published in Russian in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 6, pp. 872–874.
The text was submitted by the authors in English. 相似文献
50.
Jiangang Li Maosong Fan Xiangming He Rusong Zhao Changyin Jiange Chunrong Wan 《Ionics》2006,12(3):215-218
TiO2-coated LiNi1/3Co1/3Mn1/3O2 materials were prepared by the hydrolyzation of Ti(OBu)4. The impact of TiO2 coating on the structure and electrochemical properties of LiNi1/3Co1/3Mn1/3O2 was investigated using X-ray diffraction, scanning electron microscope, and charge–discharge tests. The results indicated that TiO2 coating did not affect the lattice of LiNi1/3Co1/3Mn1/3O2, but exhibited obvious effects on its discharge capacity and cycling stability. As coated TiO2 increased from 0.0 to 2.0 mol%, the initial capacity of samples decreased slightly, but the cycling stability over 2.5∼4.3 V increased remarkably. The capacity retention reached 99.5% at the 50th cycle at a coating amount of 2.0 mol%. 相似文献