全文获取类型
收费全文 | 35489篇 |
免费 | 5999篇 |
国内免费 | 4035篇 |
专业分类
化学 | 24475篇 |
晶体学 | 407篇 |
力学 | 2272篇 |
综合类 | 321篇 |
数学 | 4457篇 |
物理学 | 13591篇 |
出版年
2024年 | 87篇 |
2023年 | 702篇 |
2022年 | 1130篇 |
2021年 | 1263篇 |
2020年 | 1417篇 |
2019年 | 1400篇 |
2018年 | 1198篇 |
2017年 | 1163篇 |
2016年 | 1653篇 |
2015年 | 1662篇 |
2014年 | 2001篇 |
2013年 | 2615篇 |
2012年 | 3177篇 |
2011年 | 3256篇 |
2010年 | 2266篇 |
2009年 | 2220篇 |
2008年 | 2422篇 |
2007年 | 2098篇 |
2006年 | 1904篇 |
2005年 | 1565篇 |
2004年 | 1217篇 |
2003年 | 953篇 |
2002年 | 860篇 |
2001年 | 707篇 |
2000年 | 651篇 |
1999年 | 770篇 |
1998年 | 633篇 |
1997年 | 607篇 |
1996年 | 591篇 |
1995年 | 559篇 |
1994年 | 460篇 |
1993年 | 407篇 |
1992年 | 344篇 |
1991年 | 293篇 |
1990年 | 274篇 |
1989年 | 209篇 |
1988年 | 174篇 |
1987年 | 142篇 |
1986年 | 111篇 |
1985年 | 118篇 |
1984年 | 72篇 |
1983年 | 59篇 |
1982年 | 55篇 |
1981年 | 27篇 |
1980年 | 14篇 |
1979年 | 3篇 |
1976年 | 1篇 |
1959年 | 2篇 |
1957年 | 8篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
291.
采用气相沉积技术在Si衬底上生长了Zn-Zn2SiO4芯-壳结构纳米同轴线阵列。根部呈笋状的纳米同轴线,直径约100nm,长度可以超过10μm;同轴线芯直径约50nm、壳层厚约25nm。通过X射线衍射的表征以及能量色散谱的线扫描,确定纳米同轴线的芯为Zn,壳层为Zn2SiO4。我们提出了一种新的生长机制,同时也为生长均匀的纳米同轴线提供一种新的技术。观察阴极荧光谱发现,纳米同轴线有三个主要发光带:强度最大的中紫外300nm发光、较弱的可见光区560nm以及红外谱区865nm的发光。对纳米同轴线截面的300nm发光峰观测发现,中紫外发光来源于Zn2SiO4壳层。正是这种同轴线的结构,使得其具备特殊的光学性质。 相似文献
292.
Electrostatic spring softening is an important characteristic of electrostatically actuated dual-axis micromirror, since it lowers the resonant frequencies. This paper presents an approach based on approximating the electrostatic forces by the first-order Taylor's series expansion to investigate this characteristic. The dual-axis micromirror studied in this paper has three motion modes, two torsional (about x- and y-axis, respectively) and one translational (about z-axis). The stiffnesses of all these modes are softened by a DC bias voltage applied to the mirror plate. The resonant frequencies are lowered with the increment of the bias voltage. The relationship of the bias voltage and the resonant frequencies of all the motion modes is derived. The analytical results show that the resonant frequency curves are affected by the capacitor geometries, i.e. the gap between the mirror plate and the electrodes and the electrodes size. The lowering curves drop slowly when the bias voltage is small. While for large bias voltage, the lowering curves drop rapidly. The experiment results are consistent with those obtained by the analytical approach. 相似文献
293.
294.
Ding-Xuan Zhou 《Journal of Fourier Analysis and Applications》2002,8(6):565-580
Two-scale homogeneous functions are functions hh satisfying h(x) = \gl h(2 x)h(x) = \gl h(2 x) for some constant \gl\gl. They form a class of special functions and include homogeneous polynomials. In this article we investigate two-scale homogeneous functions that are contained in a shift-invariant space S(f)S(\phi) where f\phi is an rr-vector of functions and satisfies a vector refinement equation. The structure of these functions is analyzed. In particular, we establish a one-to-one correspondence between these two-scale homogeneous functions with order \gl\gl and the left eigenvectors of a finite matrix (derived from the mask for f\phi) associated with eigenvalue \gl\gl. 相似文献
295.
296.
采用高斯分解法(GD)对大非线性相移下的Z扫描特性进行了分析,通过对数值算法的优化,将GD推广到对脉冲入射激光下大非线性相移下的Z扫描理论分析.对不同条件下大非线性相移Z扫描曲线峰谷结构的比较,发现在大非线性相移的情况下,Z扫描曲线的峰和谷随透过光阑或入射光强变化表现出某些新的特性.随着透过光阑孔径的增加,Z扫描曲线峰的变化要明显快于谷的变化,而且在谷明显存在的情况下,峰很快消失.采用皮秒脉冲激光下的纯二硫化碳实验对理论结果加以验证,实验结果和理论分析相一致.我们的分析结果对大非线性相移下Z扫描测量有一定的指导性意义,避免在大非线性相移下对Z扫描结果产生错误的分析.
关键词:
大非线性相移
高斯分解法
Z扫描 相似文献
297.
This paper presents a variational inequality (VI) approach to the problem of minimizing a sum of p-norms. First the original problem is reformulated as an equivalent linear VI. Then an improved extra-gradient method is presented
to solve the linear VI. Applications to the problem of p-norm Steiner Minimum Trees (SMT) shows that the proposed method is effective. Comparison with the general extra-gradient
method is also provided to show the improvements of the new method. 相似文献
298.
Phenylene vinylene‐based electroluminescent polymers with electron transport block in the main chain
Honghao Sun Chongyu Mei Quanguo Zhou Ze Liu Dongge Ma Lixiang Wang Xiabin Jing Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3469-3478
We report a new route for the design of soluble phenylene vinylene (PV) based electroluminescent polymers bearing electron‐deficient oxadizole (OXD) and triazole (TZ) moieties in the main chains with the aryloxy linkage. Both series of the PV‐based polymers were prepared by Wittig reaction. By properly adjusting the OXD and/or TZ content through copolymerization, we can achieve an enhanced balance of hole‐ and electron injections, such that the device efficiency is significantly improved. Light‐emitting diodes fabricated from P1, P2, P3, P4, P5, P6, and P7 with the configuration of Indium–Tin Oxide (ITO)/Poly (styrene sulfonic acid) doped poly (ethylenedioxythiophene) (PEDOT)/polymer/Ca/Al, emit bright green light with the maximum peak around 500 nm. For the device using the optimal polymer (P4) as emitting layer, a maximum brightness of 1300 cd/m2 at 20 V and a maximum luminance efficiency of 0.325 cd/A can be obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3469–3478, 2006 相似文献
299.
Nianchen Zhou Wenjian Xu Yu Zhang Jian Zhu Xiulin Zhu 《Journal of polymer science. Part A, Polymer chemistry》2006,44(4):1522-1528
2,2,6,6‐Tetramethyl‐4‐[d‐(+)‐10‐camphorsulfonyl]‐1‐piperidinyloxy was synthesized and used as a chiral nitroxide for the bulk polymerizations of styrene initiated with benzoyl peroxide (BPO), tetraethylthiuram disulfide (TETD), and thermal initiation. The results showed that the polymerizations proceeded in a controlled/living way; that is, the kinetics presented approximately first‐order plots, and the number‐average molecular weights of the polymers with narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight) increased with the monomer conversion linearly. The molecular weight distributions in the case of thermal initiation were narrower than those in the case of BPO and TETD, whereas the polymerization rate with BPO or TETD as an initiator was obviously faster than that with thermal initiation. In addition, successful chain‐extension reactions were carried out, and the structures of the obtained polymers were characterized by gel permeation chromatography and 1H NMR. The specific rotations of the polymers were also measured by polarimetric analysis. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1522–1528, 2006 相似文献
300.
Yunchun Zhou Jianxin Geng Gao Li Enle Zhou Liang Chen Wanjin Zhang 《Journal of Polymer Science.Polymer Physics》2006,44(4):764-769
A series of crystals of phenyl‐capped tetraaniline in the leucoemeraldine oxidation state were obtained at different isothermal temperatures and were observed directly under transmission electron microscope. The crystals obtained at higher temperatures exhibit more perfect structures than those obtained at lower temperatures. Both the lamella thickness and the crystal size increase with crystallization temperature. The tetraaniline is apt to form larger scale crystals under lower degree of supercooling. However, their crystal structures keep steady with the crystallization temperature. The tetramer was found to adopt a monoclinic lattice with unit cell parameter of a = 13.93 Å, b = 8.82 Å, c = 23.20 Å, and β = 95.03°, as determined using electron diffraction tilting method combined with wide‐angle X‐ray diffraction experiment. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 764–769, 2006 相似文献