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221.
A new method for the analysis of thermal desorption spectra is presented, based on the experimental peak maximum functions
for temperatureT
m(β) and pressureP
m(β) and a rigorous mathematical treatment. The resonant heating rate βr is determined, satisfyingT
m(βr)=T
r, whereT
r is the resonant temperature defined byA exp(−E
d/(RT
r))=1. Desorption energyE
d and frequency factorA can be determined simultaneously with relatively high robustness towards statistical experimental errors as demonstrated
by computer-simulated thermal desorption spectra. 相似文献
222.
We study the large-sample properties of a class of parametric mixture models with covariates for competing risks. The models allow general distributions for the survival times and incorporate the idea of long-term survivors. Asymptotic results are obtained under a commonly assumed independent censoring mechanism and some modest regularity conditions on the survival distributions. The existence, consistency, and asymptotic normality of maximum likelihood estimators for the parameters of the model are rigorously derived under general sufficient conditions. Specific conditions for particular models can be derived from the general conditions for ready check. In addition, a likelihood-ratio statistic is proposed to test various hypotheses of practical interest, and its asymptotic distribution is provided. 相似文献
223.
224.
崔霞 《高等学校计算数学学报(英文版)》2002,11(1):76-88
A new alternating direction (AD) finite element (FE) scheme for 3-dimensional nonlinear parabolic equation and parabolic integro-differential equation is studied. By using AD, the 3-dimensional problem is reduced to a family of single space variable problems, calculation work is simplified; by using FE, high accuracy is kept; by using various techniques for priori estimate for differential equations such as inductive hypothesis reasoning, the difficulty arising from the nonlinearity is treated. For both FE and ADFE schemes, the convergence properties are rigorously demonstrated, the optimal H1-and L2-norm space estimates and the 0((△t)2) estimate for time variable are obtained. 相似文献
225.
设 G=(A,△)为紧矩阵量子群,G为A的所有有限维光滑的、不可约余表示等价类的集合.本文通过(A,△)的一个余表示Vo构造了两个相互配对的集合,利用Hilbert C*-模的理论证明它们分别为A和Baaj与Skandalis构造的量子群A,并且证明了对任意的α∈G,在A中都对应一个有限维投影算子Pα,满足 dim(α)=dim(pα). 相似文献
226.
227.
采用热处理方法提高MEH-PPV单层聚合物有机发光二极管发光性能的研究 总被引:2,自引:1,他引:1
对以MEH-PPV为发光层的单层聚合物有机发光二极管(OLED)器件在最佳条件下进行真空热处理,并用金相显微镜观察施加电压后器件的阴极表面形貌。发现处理后的器件阴极表面的气泡及黑斑明显减少。器件的发光性能显著提高。与未经处理的器件相比,最大相对发光强度提高了一个数量级、启亮电压降低了2.0V,半寿命提高了12.7倍。初步分析表明热处理方法提高器件发光性能的主要原因在于有效地减少了器件在工作过程中由于焦耳热产生的某些气体,从而减少阴极表面气泡及黑斑的出现,另一方面,热处理方法也增强了有机发光层与阴极接触界面的结合力,提高电子注入水平。 相似文献
228.
The study of bed-load transport is of great significance both in theory and in practice. This paper discusses the saltation
of bed-load solid grains in flowing water. Experiments and theoretic analysis have been made by means of high-speed photographing
and advanced data processing technique with a combined method based on mechanical and statistical theories. It indicates that
the saltation is the main form of the bed-load transport under ordinary flowing conditions. In the meantime, taking successive
saltation as the model of bed-load transport, systematic analysis has been made with regard to the kinematic properties and
mechanism of saltation. The statistical analysis shows that the probability density functions of the relative height and length
of saltation are in conformity with Γ-type distribution, while the probability density functions of the relative velocities
of saltation are in conformity with the Gaussian distribution.
The project supported by National Natural Science Foundation of China 相似文献
229.
Wei Zhou Ruonong Fu Rongji Dai Zaifu Huang Yanfei Chen 《Journal of separation science》1994,17(10):719-722
A new kind of side chain liquid crystalline polysiloxane containing a crown ether with a longer spacer (PSC-11) has been prepared and coated on a fused silica capillary column. The main chroma-tographic characteristics including efficiency, polarity, and selectivity have been examined. The phase exhibits the retention properties of both liquid crystal and crown ether stationary phases and possesses higher efficiency and better selectivity than PSC-3, which has a shorter spacer between the main polysiloxane chain and liquid crystalline side chain. 相似文献
230.
本利用矩阵给出了几类数列的通项公式的求法,把数列通项公式的求法转化为矩阵幂的计算,思路简单、计算简便,并能判别其敛散性。 相似文献