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71.
Roser Cervellera Xavier Ramis Josep Maria Salla Ana Mantecn Angels Serra 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):2873-2882
N,N‐Dimethylaminopyridine (DMAP) was used as initiator to cure mixtures of diglycidylether of bisphenol A (DGEBA) and 1,3‐dioxan‐2‐one (TMC) or 5,5‐dimethyl‐1,3‐dioxan‐2‐one (DMTMC). The curing was studied by differential scanning calorimetry (DSC) and Fourier transform infrared in the attenuated‐total‐reflection mode (FTIR/ATR). FTIR/ATR was used to monitor the competitive reactive processes and to quantify the evolution of the groups involved in the curing. We observed the formation of five‐membered cyclic carbonates and anionic carbonate groups that remain unreacted at the chain ends. The formation of these groups was explained by the attack of the anionic propagation species on the methylene carbon of the carbonate group, which leads to an alkyl‐oxygen rupture. By performing the cure in the thermobalance we could evaluate the loss of CO2 produced in the samples containing carbonates. The kinetics were studied by DSC and analyzed with isoconversional procedures. The addition of carbonates slows down the curing rate. Thermogravimetric analysis (TGA) and dynamic mechanical thermal analysis (DMTA) experiments were used to evaluate the properties of the materials obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2873–2882, 2006 相似文献
72.
Olga Ordeig Craig E Banks Trevor J Davies F Javier del Campo Francesc Xavier Mu?oz Richard G Compton 《Analytical sciences》2006,22(5):679-683
Gold ultra-microelectrode arrays are used to explore the electrochemical oxidation of hydroxide ions and are shown to be analytical useful. Two types of ultra-microelectrode arrays are used; the first consist of 256 individual electrodes of 5 microm in radius, 170 of which are electrochemically active in a cubic arrangement which are separated from their nearest neighbour by a distance of 100 microm. The second array compromises 2597 electrodes of 2.5 microm in radius and of which 1550 of which are electrochemically active in a hexagonal arrangement separated by the nearest neighbour by 55 microm. Well defined voltammetric waves are found with peak currents proportional to the concentration of hydroxide ions in the range 50 microM to 1 mM. Detection limits of 20 microM using the 170 ultra-microelectrode and 10 microM with the 1550 ultra-microelectrode array are shown to be possible but with a higher sensitivity of 4 mA M(-1) observed using the 1550 ultra-microelectrode array compared to 1.2 mA M(-1) with the 170 ultra-microelectrode array. 相似文献
73.
The stoichiometric reactions of trimethylaluminum with 2,6‐(MeOCH2)2C6H3OH (LH) revealed compounds L3Al ( 1 ) and L2AlMe ( 2 ). On the other hand reaction of 1 equiv. of LH with trimethylaluminum did not lead to the formation of complex LAlMe2 ( 3 ), rather 2 together with Me3Al were observed as a result of a disproportionation of 3 . Compounds 1 and 2 were characterized by elemental analysis, 1H and 13C NMR spectroscopy and in the case of 1 by X‐ray diffraction. Derivative 2 underwent transmetalation with Ph3SnOH, giving LSnPh3 ( 4 ) as the result of a migration of ligand L from the aluminum to the tin atom. The identity of 4 was established by elemental analysis, 1H, 13C and 119Sn NMR spectroscopy and 1H, 119Sn HMBC experiments. The system 2 and B(C6F5)3 in a 1:1 molar ratio was shown to be active in the polymerization of propylene oxide and ε‐caprolactone. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
74.
75.
This paper presents the results of plasma temperature and pressure calculations in the parallel plate accelerator during the accelerating process. The plasma pressure is calculated by means in Dalton's law. 相似文献
76.
77.
Continuous solutions of the functional equation ?(x?(x)) = (?(x))2 for x ∈ [0,∞) have been characterized by Dhombres. They form a simple, two-parametric family and the result can be easily extended to solutions on the whole real line. However, the class of all solutions is much larger. We show that there is a solution ? whose graph has, among others, the full outer two-dimensional Lebesgue measure. It turns out that partial restrictions, like boundedness, monotonicity and/or continuity on a subinterval do not imply the continuity of solutions. In particular, the class of monotonic solutions has interesting properties. We provide some techniques of constructing such solutions and show that, among others, there is a strictly increasing solution ? whose points of discontinuity form a dense set in R. 相似文献
78.
It is proved that if the intrinsic zero-index of the Sasaki metric of a tangent bundleTM
n
isk, thenk is even andM
n
is the metric product of a Riemannian manifoldM
n–k/2 by a Euclidean spaceE
k/2, whileTM
n
is the metric product ofTM
n–k/2 byE
k
. An expression is obtained for the second fundamental forms of the imbeddingTF
l
TM
n
in terms of the second fundamental forms of the imbeddingF
l
M
n
and the curvature tensor ofM
n
. It is proved thatTF
l is totally geodesic inTM
n
if and only ifF
l
is totally geodesic inM
n
.Translated from Ukrainskií Geometricheskií Sbornik, Issue 28, 1985, pp. 12–32. 相似文献
79.
Z. Kožíšek 《Czechoslovak Journal of Physics》1990,40(6):592-604
The kinetic equation of the classical homogeneous nucleation theory is rewritten in dimensionless form and it is shown that the numerical computation of the dimensionless kinetic equation is approximately 20 times faster in comparison with the original kinetic equation. The results are compared with known analytical results and with previous numerical results in the case of the constant and variable temperature for the model Li2O.2 SiO2 melt. It is shown, e.g., that under non-isothermal conditions the nucleation rate is greater than the quasistationary nucleation rate and the cluster distribution function is greater than the corresponding quasiequilibrium cluster distribution function. 相似文献
80.