全文获取类型
收费全文 | 2496篇 |
免费 | 112篇 |
国内免费 | 13篇 |
专业分类
化学 | 1780篇 |
晶体学 | 12篇 |
力学 | 76篇 |
数学 | 367篇 |
物理学 | 386篇 |
出版年
2024年 | 6篇 |
2023年 | 17篇 |
2022年 | 37篇 |
2021年 | 43篇 |
2020年 | 33篇 |
2019年 | 44篇 |
2018年 | 35篇 |
2017年 | 43篇 |
2016年 | 92篇 |
2015年 | 61篇 |
2014年 | 117篇 |
2013年 | 140篇 |
2012年 | 178篇 |
2011年 | 201篇 |
2010年 | 121篇 |
2009年 | 124篇 |
2008年 | 159篇 |
2007年 | 145篇 |
2006年 | 146篇 |
2005年 | 126篇 |
2004年 | 124篇 |
2003年 | 90篇 |
2002年 | 86篇 |
2001年 | 54篇 |
2000年 | 49篇 |
1999年 | 27篇 |
1998年 | 26篇 |
1997年 | 26篇 |
1996年 | 22篇 |
1995年 | 15篇 |
1994年 | 16篇 |
1993年 | 10篇 |
1992年 | 12篇 |
1991年 | 11篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 22篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 11篇 |
1976年 | 7篇 |
1975年 | 9篇 |
1974年 | 10篇 |
1973年 | 5篇 |
排序方式: 共有2621条查询结果,搜索用时 15 毫秒
81.
Léo Birbaum Dr. Laurent Gillard Prof. Hélène Gérard Prof. Hassan Oulyadi Dr. Guillaume Vincent Prof. Xavier Moreau Dr. Michael De Paolis Prof. Isabelle Chataigner 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(60):13688-13693
3-Nitroindoles are easily reacted with highly substituted γ-allenoates in the presence of a commercially available phosphine catalyst. For instance, allenoates derived from biomolecules such as amino and deoxycholic acids are combined for the first time with 3-nitroindole. The corresponding dearomatized (3+2) tricyclic cycloadducts are obtained as α-regioisomers exclusively. DFT computations shed light on this multi-step reaction mechanism and on the selectivities observed in the sequence. 相似文献
82.
It is known that under resonance conditions, a group of strongly interacting bosonic atoms, trapped in a double-well potential, mimics a single particle, performing Rabi oscillations between the wells. By implication, all atoms need to tunnel at roughly the same time, even though the Bose–Hubbard Hamiltonian accounts only for one-atom-at-a-time transfers. The mechanism of this collective behavior is analyzed, the Rabi frequencies in the process are evaluated, and the limitation of this simple picture is discussed. In particular, it is shown that the small rapid oscillations superimposed on the slow Rabi cycle result from splitting the transferred cluster at the sudden onset of tunnelling, and disappear if tunnelling is turned on gradually. 相似文献
83.
Dr. Julie Martin Dr. Mohammad Wehbi Dr. Cécile Echalier Dr. Sylvie Hunger Dr. Audrey Bethry Prof. Xavier Garric Dr. Coline Pinese Prof. Jean Martinez Dr. Lubomir Vezenkov Prof. Gilles Subra Prof. Ahmad Mehdi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(56):12839-12845
A simple and efficient way to synthesize peptide-containing silicone materials is described. Silicone oils containing a chosen ratio of bioactive peptide sequences were prepared by acid-catalyzed copolymerization of dichlorodimethylsilane, hybrid dichloromethyl peptidosilane, and Si(vinyl)- or SiH-functionalized monomers. Functionalized silicone oils were first obtained and then, after hydrosilylation cross-linking, bioactive polydimethylsiloxane (PDMS)-based materials were straightforwardly obtained. The introduction of an antibacterial peptide yielded PDMS materials showing activity against Staphylococcus aureus. PDMS containing RGD ligands showed improved cell-adhesion properties. This generic method was fully compatible with the stability of peptides and thus opened the way to the synthesis of a wide range of biologically active silicones. 相似文献
84.
Dr. Chenge Li Dr. Alison G. Tebo Marion Thauvin Marie-Aude Plamont Prof. Dr. Michel Volovitch Dr. Xavier Morin Prof. Dr. Sophie Vriz Prof. Dr. Arnaud Gautier 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18073-18079
Far-red emitting fluorescent labels are highly desirable for spectral multiplexing and deep tissue imaging. Here, we describe the generation of frFAST (far-red Fluorescence Activating and absorption Shifting Tag), a 14-kDa monomeric protein that forms a bright far-red fluorescent assembly with (4-hydroxy-3-methoxy-phenyl)allylidene rhodanine (HPAR-3OM). As HPAR-3OM is essentially non-fluorescent in solution and in cells, frFAST can be imaged with high contrast in presence of free HPAR-3OM, which allowed the rapid and efficient imaging of frFAST fusions in live cells, zebrafish embryo/larvae, and chicken embryos. Beyond enabling the genetic encoding of far-red fluorescence, frFAST allowed the design of a far-red chemogenetic reporter of protein–protein interactions, demonstrating its great potential for the design of innovative far-red emitting biosensors. 相似文献
85.
86.
Nicolas P. Cheval Barbara Hoffmann Anna Dikova Fatih Sirindil Philippe Bertus Aurélien Blanc Jean-Marc Weibel Patrick Pale 《Tetrahedron》2018,74(50):7111-7119
Vinyl nosylates, readily obtained from β-dicarbonyl derivatives, could be efficiently engaged in Sonogashira cross-coupling reactions, either cocatalyzed by copper or silver salts. The para-nitrobenzenesulfonate (nosylate) group allows this coupling to be performed under very mild conditions (room temperature). These new leaving group and mild conditions could be applied to the synthesis of acetylenic coumarinyl derivatives and to the total synthesis of an acetylenic monoterpene natural product, named cleviolide. 相似文献
87.
Xavier Buff Arnaud Ché ritat 《Proceedings of the American Mathematical Society》2007,135(4):1073-1080
In the family of quadratic polynomials with an irrationally indifferent fixed point, we show the existence of Siegel disks with a fine control on the degree of regularity of the linearizing map on their boundary. A general theorem is stated and proved. As a particular case, we show that in the quadratic family, there are Siegel disks whose boundaries are but not Jordan curves.
88.
S. A. Leonel A. C. R. Mendes W. Oliveira G. L. Silva L. M. V. Xavier 《Brazilian Journal of Physics》2014,44(1):108-118
We discuss the two-dimensional isotropic antiferromagnet in the framework of gauge invariance. Gauge invariance is one of the most subtle useful concepts in theoretical physics, since it allows one to describe the time evolution of complex physical system in arbitrary sequences of reference frames. All theories of the fundamental interactions rely on gauge invariance. In Dirac’s approach, the two-dimensional isotropic antiferromagnet is subject to second-class constraints, which are independent of the Hamiltonian symmetries and can be used to eliminate certain canonical variables from the theory. We have used the symplectic embedding formalism developed by a few of us to make the system under study gauge invariant. After carrying out the embedding and Dirac analysis, we systematically show how second-class constraints can generate hidden symmetries. We obtain the invariant second-order Lagrangian and the gauge-invariant model Hamiltonian. Finally, for a particular choice of factor ordering, we derive the functional Schröodinger equations for the original Hamiltonian and for the first-class Hamiltonian and show them to be identical, which justifies our choice of factor ordering. 相似文献
89.
Double-quantum filtered MAS NMR spectra of an isolated homonuclear spin-1/2 pair are considered, at and away from rotational resonance conditions. The pulse sequence used is the solid-state NMR equivalent of double-quantum filtered COSY, known from solution-state NMR. The 119Sn spin pair in [(chex3Sn)2S] is characterized by a difference in isotropic chemical shielding smaller than the two chemical shielding anisotropies and by direct dipolar and isotropic J-coupling constants of similar magnitudes. At rotational resonance, one-dimensional double-quantum filtered 119Sn lineshapes yield the relative orientation of the two 119Sn chemical shielding tensors. Good double-quantum filtration efficiencies are found at and away from rotational resonance conditions, despite the presence of large chemical shielding anisotropies. Numerical simulations illustrate the interplay of the direct dipolar and J-coupling pathways and identify the latter as the main pathway even at rotational resonance conditions. 相似文献
90.
Bornheim A Lipeles E Pappas SP Shapiro A Sun WM Weinstein AJ Masek G Paar HP Mahapatra R Morrison RJ Briere RA Chen GP Ferguson T Tatishvili G Vogel H Adam NE Alexander JP Bebek C Berkelman K Blanc F Boisvert V Cassel DG Drell PS Duboscq JE Ecklund KM Ehrlich R Gibbons L Gittelman B Gray SW Hartill DL Heltsley BK Hsu L Jones CD Kandaswamy J Kreinick DL Magerkurth A Mahlke-Krüger H Meyer TO Mistry NB Nordberg E Palmer M Patterson JR Peterson D Pivarski J Riley D Sadoff AJ Schwarthoff H 《Physical review letters》2002,88(23):231803
We report a new measurement of the Cabibbo-Kobayashi-Maskawa parameter Vub made with a sample of 9.7 x 10(6) BB- events collected with the CLEO II detector. Using heavy quark theory, we combine the observed yield of leptons from semileptonic B decay in the end-point momentum interval 2.2-2.6 GeV/c with recent CLEO II data on B-->X(s)gamma to find Vub = (4.08+/-0.34+/-0.44+/-0.16+/-0.24)x10(-3), where the first two uncertainties are experimental and the last two are from theory. 相似文献