HG-AAS测定废水中微量As(Ⅲ)和As(Ⅴ)

在自然界水体中砷主要以无机的As(Ⅲ)和As(Ⅴ)的形态存在,而As(Ⅲ)的毒性比As(Ⅴ)大得多[1],因此必须对As(Ⅲ)和As(Ⅴ)分别测定才能可靠评价砷的毒性及其生物重要性[2-4]。目前砷的化学形态分析方法很多,萃取法、巯基棉富集分离法、离子交换法[5]等可实现砷的形态分析,但操作复     

基于同步辐射原位CT的水牛角结构性能关系研究

为探究水牛角的结构性能关系,基于上海同步辐射光源搭建了高分辨原位CT系统,对水牛角角鞘进行初始表征和准静态压缩下的实时表征,并通过Top-Hat方法提取了角鞘内孔洞三维形貌.结果显示,水牛角角鞘孔隙率在1％左右,椭圆柱状孔洞沿牛角生长方向排列成线,首尾相连却并未连通,均匀分布在波浪状片层之间.孔洞特征椭球的轴长分布满足...     

Theoretical Study on Enol-keto Tautomerism of α-Fluorine-β-diketones

Density Functional Theory method is applied to investigate the enol-keto tautome- rism of both acyclic and cyclic α-fluorine-β-diketones. It is shown that, for acyclic cases, α-fluorine could improve the relative stability of keto tautomer by lessening intramolecular hydrogen bond of enol form, whereas the relative stability of cyclic enol could be attributed to two factors: destabi- lization of keto and stabilization of enol. Furthermore, the relative stabilities of all enol tautomers are improved in THF to different extents.     

Synthesis and Crystal Structure of 4,4′-(4-(1-Naphthyl)-4-phenyl- 1,3-butadienylidene)-bis[N,N-diethylbenzenamine]

The title compound (C40H42N2) has been synthesized by the reaction of 1-(1-naphthyl)-1-phenyl-3-chloropropylene and bis(4-(diethylamino) phenyl)methanone, and characterized by IR, 1H NMR, MS and X-ray diffraction analysis. The crystal belongs to the monoclinic system, space group P21/c with a = 17.047(3), b = 10.807(2), c = 1&494(4) (A), β = 105.727(4)°, V=3279.4(11) A3, Mr = 550.76, Z = 4, Dc = 1.115 g/cm3, μ(MoKα) = 0.085 mm-1, F(000) = 1184, the final R = 0.0625 and wR = 0.1384 for 2276 observed reflections (I ＞ 2σ(Ⅰ)). X-ray analysis reveals that the butadiene fragment adopts a planar cisiod conformation and makes a dihedral angel of 69.4(2)° with the naphthalene ring.     

Synthesis, Spectroscopic Properties and Crystal Structural Characterization of a Triphenyltin(Ⅳ) Complex with 5-Bromonicotinic Acid

A novel organotin complex [Ph3Sn(C2H5OH)(OCOC5H3NBr)SnPh3(OCOC5H3NBr)]has been synthesized by the reaction of 5-bromonicotinic acid with triphenyltin hydroxide in ethanol and characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to the monoclinic system, space group P21/c with a = 15.564(2), b = 24.975(4), c = 12.2973(19) (A), β = 92.224(2)°, Z = 4, V = 4776.5(13) (A)3, Dc = 1.596g/cm3, μ(MoKα) = 2.765 mm-1, F(000) = 2264, R = 0.0385 and wR = 0.0667. In the molecular structure of the title complex, the tin atoms are five-coordinated in a trigonal bipyramidal geometry.     

Lamb波频域逆散射全聚焦成像方法研究

Lamb波因其传播距离远、衰减小常被用于板状结构的无损检测中,在基于Lamb波损伤检测的诸多成像技术中,全聚焦方法(Total Focus Method,TFM)方法因其成像分辨率高、信噪比高而受青睐.然而Lamb波的频散效应导致时域延时量不能被准确计算,进而影响传统TFM方法对损伤定位及成像的精度;此外,既有的TFM...     

Synthesis and Crystal Structure of a New Mononuclear Nickel(Ⅱ) Mixed Complex Derived from 2-Aminoethyl-bi(3-bi-aminopropyl)amine with 1,10-Phenanthroline

The mixed complex [Ni(L)(L')](ClO4)2 has been synthesized using 2-aminoethyl- bi(3-bi-aminopropyl)amine with phen (1,10-phenanthroline) in the presence of Ni(II) ion, and its structure was determined by X-ray diffraction. The crystal crystallizes in monoclinic, space group P21/c with a = 13.713(2), b = 13.1466(19), c = 14.780(2) (A), β = 97.620(3)°, V = 2640.9(7)(A)3, F(000) = 1272, Z = 4, Dc = 1.540 g/cm3, R = 0.0536 and wR = 0.1207. The Ni2+ ion is six- coordinated to furnish a distorted octahedral geometry.     

完全三部图K(n-k,n,n)的色唯一性

通过对图的特征子图个数的比较,给出了图K(n-k,n,n)色唯一性的数值条件.     

MATLAB曲面绘制中的挖补方法

在MATLAB绘图中,将函数数据的某一部分换成内置变量NaN(或Inf),或者将函数数据中的NaN换成适当的实数,可分别实现绘图中的挖、补方法.并且给出一些具体的应用实例.     

硫化丁苯橡胶纳观界面耐磨机理及参数影响分析

硫化橡胶因其良好的力学和物理化学性能而被广泛作为摩擦副的基础材料. 本文提出了一种硫化交联算法, 实现了C—C键的硫化互交联和自交联, 构建了硫化丁苯橡胶的分子动力学磨损模型, 从微观摩擦学的角度阐明了硫化交联结构对改善丁苯橡胶磨损性能的机理, 研究了不同界面参数对硫化橡胶微观磨损性能的影响. 结果发现 硫化使丁苯橡胶分子链的界面黏附能力和活动能力更弱, 拉伸和解缠能力更低, 磨损过程中界面累积能量更低, 更不容易脱离橡胶基体, 因此可以表现出更好的摩擦学性能, 更强的抗磨损性能; 随着速度的增大, 硫化橡胶的磨损率降低, 与宏观实验结果一致, 原因是硫化橡胶的原子分布函数和相互作用能随着速度增大而降低, 说明橡胶分子链的黏附能力和活动能力随着速度增加趋弱, 温升更低, 导致较低的磨损率; 压入深度对磨损率的影响规律则呈现相反的结果和趋势.