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31.
Jayachandran Jayakumar Kanniyappan Parthasarathy Yi‐Hsiang Chen Tai‐Hua Lee Shih‐Ching Chuang Chien‐Hong Cheng 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(37):10047-10050
A new method for the synthesis of highly substituted naphthyridine‐based polyheteroaromatic compounds in high yields proceeds through rhodium(III)‐catalyzed multiple C H bond cleavage and C C and C N bond formation in a one‐pot process. Such highly substituted polyheteroaromatic compounds have attracted much attention because of their unique π‐conjugation, which make them suitable materials for organic semiconductors and luminescent materials. Furthermore, a possible mechanism, which involves multiple chelation‐assisted ortho C H activation, alkyne insertion, and reductive elimination, is proposed for this transformation. 相似文献
32.
JavaStatSoft, implemented using Java, is an open-source software for performing statistics. The current features of JavaStatSoft
are described. Several well-known patterns the software used are introduced. In addition, based on these patterns and the
experience in developing the software, a new framework, referred to as Data Analysis Module, is proposed to help programmers
develop a user-friendly software for data analysis. 相似文献
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34.
Tung‐Kung Wu Cheng‐Hsiang Chang Yuan‐Ting Liu Tsai‐Ting Wang 《Chemical record (New York, N.Y.)》2008,8(5):302-325
The oxidosqualene cyclases (EC 5.4.99‐) constitute a family of enzymes that catalyze diverse cyclization/rearrangement reactions of (3S)‐2,3‐oxidosqualene into a distinct array of sterols and triterpenes. The relationship between the cyclization mechanism and the enzymatic structure is extremely complex and compelling. This review covers the historical achievements of biomimetic studies and current progress in structural biology, molecular genetics, and bioinformatics studies to elucidate the mechanistic and structure–function relationships of the Saccharomyces cerevisiae oxidosqualene‐lanosterol cyclase‐catalyzed cyclization/rearrangement reaction. © 2008 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 8: 302–325; 2008: Published online in Wiley InterScience ( www.interscience.wiley.com ) DOI 10.1002/tcr.20157 相似文献
35.
Yu‐Pin Wang Hsien‐Li Leu Tso‐Shen Lin Yu Wang Gene‐Hsiang Lee 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(3):m131-m134
In the structures of each of the title compounds, [CrBr(C6H5O2)(NO)2], (I), and [CrBr(C12H9O)(NO)2], (II), one of the nitrosyl groups is located at a site away from the exocyclic carbonyl C atom of the cyclopentadienyl (Cp) ring, with twist angles of 174.5 (3) and 172.5 (1)°. The observed orientation is surprising, since the NO group is expected to be situated trans to an electron‐rich C atom in the ring. The organic carbonyl plane is turned away from the Cp ring plane by 5.6 (8) and 15.2 (3)°in (I) and (II), respectively. The exocyclic C—C bond in (I) is bent out of the Cp ring plane towards the Cr atom by 2.8 (3)°, but is coplanar with the Cp ring in (II); the angle is 0.1 (1)°. 相似文献
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38.
Density contrasts in the universe are governed by scalar cosmological perturbations which, when expressed in terms of gauge-invariant variables, contain a classical component from scalar metric perturbations and a quantum component from inflaton field fluctuations. It has long been known that the effect of cosmological expansion on a quantum field amounts to squeezing. Thus, the entropy of cosmological perturbations can be studied by treating them in the framework of squeezed quantum systems. Entropy of a free quantum field is a seemingly simple yet subtle issue. In this paper, different from previous treatments, we tackle this issue with a fully developed nonequilibrium quantum field theory formalism for such systems. We compute the covariance matrix elements of the parametric quantum field and solve for the evolution of the density matrix elements and the Wigner functions, and, from them, derive the von Neumann entropy. We then show explicitly why the entropy for the squeezed yet closed system is zero, but is proportional to the particle number produced upon coarse-graining out the correlation between the particle pairs. We also construct the bridge between our quantum field-theoretic results and those using the probability distribution of classical stochastic fields by earlier authors, preserving some important quantum properties, such as entanglement and coherence, of the quantum field. 相似文献
39.
Wen Hsiang Wei 《Annals of the Institute of Statistical Mathematics》2009,61(2):291-308
A class of regression model selection criteria for the data with correlated errors is proposed. The proposed class of selection
criteria is an estimator of weighted prediction risk. In addition, the proposed selection criteria are the generalizations
of several commonly used criteria in statistical analysis. The theoretical and asymptotic properties for the class of criteria
are established. Further, in the medium-sample case, the results based on a simulation study are quite consistent with the
theoretical ones. The proposed criteria perform well in the simulations. Several applications are also given for a variety
of statistical models. 相似文献
40.
Tzy‐Hsiang Su Sheng‐Huei Hsiao Guey‐Sheng Liou 《Journal of polymer science. Part A, Polymer chemistry》2005,43(10):2085-2098
We report the preparation and characterization of a series of novel electrochromic, aromatic poly(amine amide)s with pendent triphenylamine units. The synthesis proceeded via direct phosphorylation polycondensation between a novel diamine, N,N‐bis(4‐aminophenyl)‐N′,N′‐diphenyl‐1,4‐phenylenediamine, and various aromatic dicarboxylic acids. All the poly(amine amide)s were amorphous and readily soluble in many common organic solvents and could be solution‐cast into transparent, tough, and flexible films with good mechanical properties. They exhibited good thermal stability and 10% weight‐loss temperatures above 540 °C. Their glass‐transition temperatures were 263–290 °C. These polymers in N‐methyl‐2‐pyrrolidinone solutions exhibited strong ultraviolet–visible absorption peaks at 307–358 nm and photoluminescence peaks around 532–590 nm in the green region. The hole‐transporting and electrochromic properties were studied with electrochemical and spectroelectrochemical methods. Cyclic voltammograms of poly(amine amide) films prepared by the casting of polymer solutions onto an indium tin oxide coated glass substrate exhibited two reversible oxidation redox couples at 0.65 and 1.03 V versus Ag/AgCl in an acetonitrile solution. All the poly(amine amide)s showed excellent stability with respect to their electrochromic characteristics; the color of the films changed from pale yellow to green and then blue at 0.85 and 1.25 V, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2085–2098, 2005 相似文献