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101.
J. Kvapil B. Perner Jos Kvapil B. Mánek K. Hamal M. Košelja V. Kubeček 《Czechoslovak Journal of Physics》1988,38(11):1281-1287
YAP:Nd, Cr grown under Ar-H2 or Ar-He-H2 atmosphere possesses good energy transfer from Cr3+ to Nd3+ but suffers from the colour centre formation. The centre formation was completely prevented using further admixture of Ce3+ and 10–4–10–3 wt. % Fe. Small luminescence quenching of Cr3+ or Nd3+ due to iron ions is negligible in the presence of Ce3+. The crystals may be also heavily doped with Nd3+ because the increased pumping efficiency compensates the shortening of the luminescence lifetime. YAP: Nd, Ce, Cr, Fe is advisible active laser material particularly for all the types of pulsed lasers. 相似文献
102.
Eungil Ko 《Integral Equations and Operator Theory》1997,28(4):492-499
In this paper we shall prove that if an operatorT∈L(⊕ 1 2 H) is an operator matrix of the form $$T = \left( {\begin{array}{*{20}c} {T_1 } & {T_2 } \\ 0 & {T_3 } \\ \end{array} } \right)$$ whereT 1 is hyponormal andT 3 k =0, thenT is subscalar of order 2(k+1). Hence non-trivial invariant subspaces are known to exist if the spectrum ofT has interior in the plane as a result of a theorem of Eschmeier and Prunaru (see [EP]). As a corollary we get that anyk-quasihyponormal operators are subscalar. 相似文献
103.
Zbyněk Brůža Dr. Jiří Kratochvíl Prof. Jeremy N. Harvey Dr. Lubomír Rulíšek Dr. Lucie Nováková Jana Maříková Dr. Jiří Kuneš Prof. Pavel Kočovský Prof. Milan Pour 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(34):8053-8060
Pyran-2-ones 3 undergo a novel Pd0-catalyzed 1,3-rearrangement to afford isomers 6 . The reaction proceeds via an η2-Pd complex, the pyramidalization of which (confirmed by quantum chemistry calculations) offers a favorable antiperiplanar alignment of the Pd−C and allylic C−O bonds ( C ), thus allowing the formation of an η3-Pd intermediate. Subsequent rotation and rate-limiting recombination with the carboxylate arm then gives isomeric pyran-2-ones 6 . The calculated free energies reproduce the observed kinetics semi-quantitatively. 相似文献
104.
Monika Kořenková Dr. Ing. Martin Hejda Prof. Milan Erben Dr. Ing. Robert Jirásko Prof. Dr. Roman Jambor Prof. Aleš Růžička Dr. Elena Rychagova Prof. Sergey Ketkov Prof. Libor Dostál 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(56):12884-12888
The reaction of N,C,N-chelated stibinidene ArSb ( 1 ) (Ar=C6H3-2,6-(CH=NtBu)2) with selected N-alkyl/aryl-maleimides RN(C(O)CH)2 (R=Me, tBu, Ph) gave the addition products with bridged bicyclic [2.2.1] structure containing an antimony atom at the bridgehead position, fused with a 6-membered benzene and a 5-membered N-alkyl/aryl-pyrrolidine ring. These compounds were completely characterized. More importantly, additional studies showed that these reactions are reversible in solution, thereby representing an unprecedented reversible activation of a C=C bond by an antimony(I) compound. 相似文献
105.
106.
Vasilieva T. M. Vasiliev M. N. Garaeva V. V. Zlobin I. S. Mint Zaw Ye Htau Khin Maung Kyaw Htet Wai Yan Zaw Htet Ko Ko 《Russian Physics Journal》2020,62(11):2092-2100
Russian Physics Journal - Different schemes and designs of generators of low-temperature hybrid plasma produced by simultaneous ionization of plasma-generating medium by an electron beam with... 相似文献
107.
An Object-Based Shale Permeability Model: Non-Darcy Gas Flow,Sorption, and Surface Diffusion Effects
Shale samples consist of two major components: organic matter (OM) and inorganic mineral component (iOM). Each component has its distinct pore network topology and morphology, which necessitates generating a model capable of distinguishing the two media. We constructed an object-based model using the OM and iOM composition of shale samples. In the model, we integrated information such as OM population and size distribution, as well as its associated pore-size distribution. For the iOM part, we used mineralogy and pore-size information derived from X-ray diffraction, scanning electron microscopy, and nitrogen sorption measurements. Our proposed model results in millimeter-scale 2D realizations of shale samples by honoring OM and mineral types, their compositions, shapes, and size distributions. The model can capture heterogeneities smaller than 1 mm. We studied the effects of different gas flow processes and found that Knudsen diffusion and gas slippage dominate the flow, but surface diffusion has little impact on total gas flow. 相似文献
108.
The deposit of carbon and oxygen adatoms on Mo(100) was characterized by AES and LEED. Carbon was introduced by the thermal cracking of ethylene; several ordered structures were observed as a function of coverage with carbon atoms residing on four-fold sites. The Mo(100)—O system exhibited two different sequences of LEED patterns depending on the adsorption temperature of oxygen. The effects of adsorbed carbon and oxygen on the chemisorption properties of Mo(100) was investigated by FDS. The presence of either carbon or oxygen severely hindered the ability of Mo(100) to dissociatively adsorb hydrogen or carbon monoxide. The amount of CO dissociated was directly related to the available four-fold sites on the carbide surfaces. The molecular adsorption of CO was not significantly affected by the adlayers. It was found that one monolayer of adsorbed oxygen reduced the binding energy of molecular CO considerably more than the same amount of adsorbed carbon. A continuous shift in the binding energy of CO with the C/O ratio on the surface was observed. 相似文献
109.
We give a construction for Gorenstein ideals of codimension 4 which we believe have maximal graded Betti numbers for their Hilbert function. 相似文献
110.
Ko Sanders 《Communications in Mathematical Physics》2010,295(2):485-501
We prove that the singularity structure of all n-point distributions of a state of a generalised real free scalar field in curved spacetime can be estimated if the two-point
distribution is of Hadamard form. In particular this applies to the free field and the result has applications in perturbative
quantum field theory, showing that the class of all Hadamard states is the state space of interest. In our proof we assume
that the field is a generalised free field, i.e. that it satisfies scalar (c-number) commutation relations, but it need not
satisfy an equation of motion. The same arguments also work for anti-commutation relations and for vector-valued fields. To
indicate the strengths and limitations of our assumption we also prove the analogues of a theorem by Borchers and Zimmermann
on the self-adjointness of field operators and of a weak form of the Jost-Schroer theorem. The original proofs of these results
make use of analytic continuation arguments. In our case no analyticity is assumed, but to some extent the scalar commutation
relations can take its place. 相似文献