Untersuchungen an oxidischen Katalysatoren. XLII. Redoxverhalten des Nickels in NiNa?Y-Zeolithen 4. Einfluß der Zusammensetzung auf die Reduzierbarkeit von Nickel in NiNa?Y-Zeolithen

Studies on Oxide Catalysts. XLii. Redox Behaviour of Nickel in Zeolites NiNa? Y. 4. Influence of Composition on the Reducibility of Nickel in Zeolites NiNa? Y By chemical analysis (reaction with K₂Cr₂O₇) and ESCA investigations we determined the degree of reduction in reduced samples NiNa-Y as function of the mole ratio SiO₂/Al₂O₃ (module), of the Ni²⁺ degree of exchange and the kind of the second cations. (NH₄₊, Ca²+, Co²+, and Nd³+) in the temperature region of 620–770 K. The degree of nickel reduction increases with increasing module, decreasing degree of exchange and decreasing number of Brönsted acidic centres. This behaviour is caused by the influence of the interaction between cations Ni²⁺ and zeolite lattice on the reduction equilibrium.     

Eine Notiz zum A-Typ der Lanthanoidoxide: Über Pr2O3

The A-type of Lanthanoide Oxides: On Pr₂O₃ . “Reductive” thermal decomposition of K₂PrO₃ [Ni-cylinder, semi-open system, 1000°C, 14 d] leads for the first time to light green single crystals of Pr₂O₃. The structure determination [105 symmetry independent hkl, four circle diffractometer Philips PW 1100; MoKα; R = 6.30%, R_w = 5.01%; space group P3m1; Z = 1; a = 385.77(3), c = 601.20(6) pm] verifies the A-type according to the proposed structure by PAULING .     

Measurement of γp→K + Λ and γp→K + Σ 0 at photon energies up to 1.47 GeV

The reactions pK ⁺ and pK ^{+ 0} have been measured with the multiparticle detector system SAPHIR at ELSA in Bonn. Besides the differential cross sections the polarization and, for the first time, the ⁰ polarization have been determined in a photon induced reaction. All data are presented as functions of the photon energy (from threshold up to 1.47 GeV) and of the kaon production angle (0°–180°). The polarization of both and ⁰ is substantial at all energies and varies strongly with the production angle.This work is supported by the Bundesminister für Forschung und Technologie (BMFT), FK 06 BN 621 I     

A large-scale application of the partial coverage uncapacitated facility location problem

The traditional, uncapacitated facility location problem (UFLP) seeks to determine a set of warehouses to open such that all retail stores are serviced by a warehouse and the sum of the fixed costs of opening and operating the warehouses and the variable costs of supplying the retail stores from the opened warehouses is minimized. In this paper, we discuss the partial coverage uncapacitated facility location problem (PCUFLP) as a generalization of the uncapacitated facility location problem in which not all the retail stores must be satisfied by a warehouse. Erlenkotter's dual-ascent algorithm, DUALOC, will be used to solve optimally large (1600 stores and 13?000 candidate warehouses) real-world implemented PCUFLP applications in less than two minutes on a 500?MHz PC. Furthermore, a simple analysis of the problem input data will indicate why and when efficient solutions to large PCUFLPs can be expected.     

Direct soft photon production inK + p andπ + p interactions at 250 GeV/c

Inclusive production of direct soft photons is studied inK ⁺ p andK ⁺ π interactions at 250 GeV/c. Total cross sections, Feynman-x and transverse momentum distributions of direct γ's are presented. The measured cross sections are several times larger than expected from QED inner bremsstrahlung, indicating the presence of an anomalous soft photon source. The model of Lichard and Van Hove, based on the “cold quark-gluon plasma” picture, agrees with the data.