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Frank J. Dinan Willis T. Schwartz Roger A. Wolfe Daniel S. Hojnicki Terry St. Clair J. Richard Pratt 《Journal of polymer science. Part A, Polymer chemistry》1992,30(1):111-118
Solution and solid-state proton decoupled 13C-NMR spectra were determined on two diimides derived from 4, 4′-oxydiphthalic anhydride. Comparison of the individual diimide spectra to that of a mixture of the two diimides indicates that ordering of these materials occurs in the solid state via charge transfer complex formation. A similar study was conducted using two isomeric dianhydrides, 4, 4′-isophthaloyldiphthalic anhydride (IDPA) and 4, 4′-terephthaloyldiphthalic anhydride (TDPA). The solution spectra of these compounds are similar and are those which would be expected for these compounds. However, their solid state spectra differ from each other. The solid-state spectrum of TDPA resembles its solution spectrum, whereas, that of IDPA differs greatly from its solution spectrum and indicates charge transfer complex formation occurs with this molecule. This difference is explained in terms of the stereochemistry of the two isomeric dianhydrides. 相似文献
74.
Beker H. Bøggild H. Boissevain J. Cherney M. Dodd J. Esumi S. Fabjan C. W. Fields D. E. Franz A. Hansen K. H. Holzer B. Humanic T. Jacak B. Jayanti R. Kalechofsky H. Kobayashi T. Kvatadze R. Lee Y. Y. Leltchouk M. Lörstad B. Maeda N. Medvedev A. Miake Y. Miyabayashi A. Murray M. Nagamiya S. Nishimura S. Noteboom E. Pandey S. U. Piuz F. Polychronakos V. Potekhin M. Poulard G. Sakaguchi A. Sarabura M. Shigaki K. Simon-Gillo J. Sletten H. Sondheim W. Sugitate T. Sullivan J. P. Sumi Y. van Hecke H. Willis W. J. Wolf K. 《Zeitschrift fur Physik C Particles and Fields》1994,64(2):209-217
K+K+ and K–K– correlations from S+Pb collisions at 200 GeV/c per nucleon and K+K+ correlations from p+Pb collisions at 450 GeV/c per nucleon, are presented as measured by the focusing spectrometer of the NA44 experiment at CERN. Multidimensional fits are performed in order to characterize the kaon-emission volume, which is found to be smaller than the pion-emission volume. 相似文献
75.
The statistics of the relaminarization of localized turbulence in a pipe are examined by direct numerical simulation. As in recent experimental data [J. Peixinho and T. Mullin, Phys. Rev. Lett. 96, 094501 (2006)10.1103/PhysRevLett.96.094501], the half-life for the decaying turbulence is consistent with the scaling (Rec-Re) -1, indicating a boundary crisis of the localized turbulent state familiar in low-dimensional dynamical systems. The crisis Reynolds number is estimated as Rec=1870, a value within 7% of the experimental value 1750. We argue that the frequently asked question, of which initial disturbances at a given Re trigger sustained turbulence in a pipe, is really two separate questions: the "local phase space" question (local to the laminar state) of what threshold disturbance at a given Re is needed to initially trigger turbulence, followed by the "global phase space" question of whether Re exceeds Rec at which point the turbulent state becomes an attractor. 相似文献
76.
Frontispiece: Gd‐DTPA‐Dopamine‐Bisphytanyl Amphiphile: Synthesis,Characterisation and Relaxation Parameters of the Nanoassemblies and Their Potential as MRI Contrast Agents 下载免费PDF全文
77.
A method for inverting the transforms of the terms in generalized ray series representations for disturbances in layered media is presented. It differs from the Cagniard reduction in that the solution of algebraic equations depending upon position x and time t is not required. This step is, in effect, replaced by contour integration of relatively simple functions. The method is applicable to anisotropic layers but it simplifies when applied to isotropic layers, for which any term in the ray series is represented as a single contour integral, around a fixed contour, of the product of a function that embodies material properties and a simple explicit function of x and t. The ‘material function’ can be tabulated and used repeatedly when the integral is evaluated for a range of values of x and t, so that the procedure is computationally quite efficient. It is illustrated by a computation of Green's function for an isotropic half-space, either free or overlaid by a fluid. Wave-front singularities are obtained explicitly from the representation and are given in an appendix. 相似文献
78.
A five-step and protecting group free synthesis of (±)-columbianetin from cyclohexane-1,3-dione is reported. The former compound was converted into its p-hydroxycinnamate derivative, (±)-angelmarin, using Coster’s esterification procedure. Efforts to modify the synthesis so as to prepare angelmarin and columbianetin in an enantioselective manner are described. 相似文献
79.
The racemic form of the title alkaloid, 1, has been prepared in 13 steps from the ring-fused gem-dibromocyclopropane 7. Key transformations include the thermally induced electrocyclic ring-opening of compound 7, the Pd[0]-catalyzed intramolecular Alder-ene (IMAE) reaction of the derived sulfonamide (±)-12, and the conversion of the ensuing C-3a-arylhexahydroindole (±)-16 into (±)-hamayne via a Pictet-Spengler reaction. 相似文献
80.
Using density functional theory (DFT), we have systematically calculated the equilibrium geometries, electronic structure, and electron detachment energies of Al(BH(4))(n=1→4) and Al(BF(4))(n=1→4) at the B3LYP/6-311+G(2d,p) level of theory. The electron affinities of Al(BH(4))(n) not only exhibit odd-even alternation, just as seen in (BH(4))(n), but also, for n = 3 and 4, show a remarkable behavior: whereas the electron affinities of BH(3) and BH(4) are, respectively, 0.06 and 3.17 eV, those of Al(BH(4))(3) and Al(BH(4))(4) are 0.71 and 5.56 eV. Results where H is replaced by F are also very different. The electron affinities of BF(3) and BF(4) are, respectively, -0.44 and +6.86 eV, and those of Al(BF(4))(3) and Al(BF(4))(4) are 1.82 and 8.86 eV. The results demonstrate not only marked difference when H is replaced by F but also substantially enhanced electron affinities by almost 2 eV when BH(4) and BF(4) units are allowed decorate a metal atom, confirming the recently observed hyperhalogen behavior of superhalogen building blocks. 相似文献