Growth of silicon nanowires on UV-structurable glass using self-organized nucleation centres

We report on the growth of silicon nanowires on photostructurable glass by low-pressure chemical vapour deposition. Thereby, no additional catalyst was needed to stimulate the growth process. Instead, a self-organized crystallization process leads to the formation of metallic clusters and seed crystals within the glass, which are supposed to initialize the nanowire growth. The nanowires were contacted by direct deposition of Pt using a focussed ion beam system and characterized electrically.     

Extension Theorems for Spaces Arising from Approximation by Translates of a Basic Function

We establish extension theorems for functions in spaces which arise naturally in studying interpolation by radial basic functions. These spaces are akin in some way to the non-integer-valued Sobolev spaces, although they are considerably more general. Such extensions allow us to establish local error estimates in a way which we make precise in the introductory section of our paper. There are many other applications of these fundamental results, including improved L_p error estimates for interpolation by shifts of a single basic function, but these applications have been left to a later paper.     

Shell effects in the evolution of the mass asymmetry in heavy-ion collisions leading to composite systems withZ=108

Fragment mass distributions are presented obtained in the heavy-ion reactions²²Ne+²⁴⁹Cf,³²S+²³⁸U,⁴⁰Ar+²³²Th and⁵⁶Fe+²⁰⁸Pb leading to composite systems with equal nuclear charge numberZ=108. The experiments were performed at the heavy-ion cyclotron U 300 of the Laboratory of Nuclear Reactions in Dubna. The spectrometer DEMAS was used to measure the time-of-flight values and the laboratory angles of the correlated fragments. The shape of the mass distributions strongly depends on the initial mass asymmetry. When decreasing the bombarding energy down to values near the Coulomb barrier, the mass distributions obtained in the reactions³²S+²³⁸U and⁴⁰Ar+²³²Th exhibit relative maxima ofM≈205 interpreted to be due to stabilizing effects of nuclear shells during the fragmentation process.     

Advanced solvent signal suppression for the acquisition of 1D and 2D NMR spectra of Scotch Whisky

A simple and robust solvent suppression technique that enables acquisition of high‐quality 1D ¹H nuclear magnetic resonance (NMR) spectra of alcoholic beverages on cryoprobe instruments was developed and applied to acquire NMR spectra of Scotch Whisky. The method uses 3 channels to suppress signals of water and ethanol, including those of ¹³C satellites of ethanol. It is executed in automation allowing high throughput investigations of alcoholic beverages. On the basis of the well‐established 1D nuclear Overhauser spectroscopy (NOESY) solvent suppression technique, this method suppresses the solvent at the beginning of the pulse sequence, producing pure phase signals minimally affected by the relaxation. The developed solvent suppression procedure was integrated into several homocorrelated and heterocorrelated 2D NMR experiments, including 2D correlation spectroscopy (COSY), 2D total correlation spectroscopy (TOCSY), 2D band‐selective TOCSY, 2D J‐resolved spectroscopy, 2D ¹H, ¹³C heteronuclear single‐quantum correlation spectroscopy (HSQC), 2D ¹H, ¹³C HSQC‐TOCSY, and 2D ¹H, ¹³C heteronuclear multiple‐bond correlation spectroscopy (HMBC). A 1D chemical‐shift‐selective TOCSY experiments was also modified. The wealth of information obtained by these experiments will assist in NMR structure elucidation of Scotch Whisky congeners and generally the composition of alcoholic beverages at the molecular level.     

C-H functionalization logic in total synthesis

In this critical review, the strategic and economic benefits of C-H functionalization logic will be analyzed through the critical lens of total synthesis. In order to illustrate the dramatically simplifying effects this type of logic can potentially have on synthetic planning, we take the reader through a series of case studies in which it has already been successfully applied. In the first section, a chronological look at key historical syntheses will be examined, leading into modern day examples. In the second section, our own experience with applying and executing synthesis with a C-H functionalization "mindset" will be discussed (114 references).     

Synthetic prodiginine obatoclax (GX15-070) and related analogues: anion binding, transmembrane transport, and cytotoxicity properties

Synthetic prodiginine obatoclax shows promise as a potential anticancer drug. This compound promotes apoptosis of cancer cells, although the mechanism of action is unclear. To date, only the inhibition of BCL-2 proteins has been proposed as a mechanism of action. To gain insight into other possible modes of action, we have studied the anion-binding properties of obatoclax and related analogues in solution, in the solid state, and by means of density functional theory calculations. These compounds are well suited to interact with anions such as chloride and bicarbonate. The anion-transport properties of the compounds synthesized were assayed in model phospholipid liposomes by using a chloride-selective-electrode technique and (13)C NMR spectroscopy. The results demonstrated that these compounds are efficient anion exchangers that promote chloride, bicarbonate, and nitrate transport through lipid bilayers at very low concentrations. In vitro studies on small-cell lung carcinoma cell line GLC4 showed that active ionophores are able to discharge pH gradients in living cells and the cytotoxicity of these compounds correlates well with ionophoric activity.