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121.
利用锁定放大器, 恒电势仪, 压控频率正弦波信号发生器等组装成电解池电阻和容抗的快速测定仪。可以快速地自动测是和绘出阻抗谱图和电阻/容抗~时间图。采用微小恒定振幅正弛交流电流(<10 μA)作为微扰, 数据可能较为可靠。给出了线路及所需滤波器元件的数据, 说明仪器各部份之间的干扰可以减少。测定了滴汞电极在1 mol L~(-1)Na_2SO_4溶液中及1 mol L~(-1)Na_2SO_4被正庚醇饱和的溶液中的微分电容~电势数值。证明仪器工作良好。另外, 从实验数据和理论分析, 均表明D.C.Grahame的被广泛引用的有关经典数据有误。本文做了修正。还测定了半导体氧化铁电极在光照下黑暗中的阻抗谱图和氧化银电极充电和停止充电后开路下的电阻~时间图, 显示了仪器在电化学研究中利用的可能性。 相似文献
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Results of voltammetric, potentiometric, chronoamperometric, ion transport, and extraction studies on neutral carrier based, plasticized poly(vinyl chloride) membranes are summarized. They unambiguously confirm that such bulk membranes dispose of immobile anionic sites. These fixed sites lead to a Donnan exclusion of other anions from the membrane and thus to a permselectivity for cations. The results are in perfect agreement with the predictions of earlier membrane models. A rigorous Poisson-Boltzmann analysis of macroscopic liquid membranes clearly indicates that space-charge at the membrane/solution interfaces does not influence the electrochemical properties and the ion-selectivity behavior at steady state. 相似文献
126.
Erich Metzger Roland Aeschimann Martin Egli Gaby Suter Ren Dohner Daniel Ammann Max Dobler Wilhelm Simon 《Helvetica chimica acta》1986,69(8):1821-1828
Lipophilic neutral carriers were synthesized which show Li+/Na+ selectivities of up to ca. 80 in highly lipophilic liquid membranes. The sensor membranes exhibit improved response times and increased lifetimes as compared to systems described earlier. They allow reliable measurements of Li+ in blood serum within the clinical concentration range. A 1:1 Li+/ionophore complex of one representative (N,N,N′,N′-tetracyclohexyl-5,5-dimethyl-3,7-dioxaazelaamide) has been prepared, and its structure was elucidated by X-ray analysis. 相似文献
127.
Hubertus Appler Lutz W. Gross Bernd Mayer Wilhelm P. Neumann 《Journal of organometallic chemistry》1985,291(1):9-23
Factors governing the ease and mechanism of 7-silabicyclo[2.2.1]heptadienes thermolysis in order to generate free silylenes and the corresponding benzene derivatives are investigated. For this purpose, 29 new compounds of the types VII–X have been prepared. No indications for a polar mechanism or an intermediate biradical could be found. The degradation is exactly of first order in all cases investigated sofar, and is enhanced by phenyl groups at the bridgehead C atoms, if a conformation coplanar with the basic ring is allowed by the neighbouring substituents, but is not enhanced by phenyl groups at the Si. The X-ray structure of two typical derivatives is discussed with this respect. A special mechanism is operating in the easy thermolysis of carbomethoxy-substituted compounds leading to cyclic sila enolether intermediates. 相似文献
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Kuppuswamy Nagarajan Sharada J. Shenoy Hans Fritz Othmar Hosang Wilhelm J. Richter 《Helvetica chimica acta》1985,68(4):900-902
The reaction of anthranilamide with phosphorus pentasulfide in boiling pyridine leads to the benzodiazaphosphorine-pyridine salt 2 . The structure is established by elemental analysis, 1H- 13C- 15N- 31P-NMR, and mass spectral data. 相似文献
129.
Dirk Pohle Sabine Ponader Thomas Rechtenwald Michael Schmidt Karl Andreas Schlegel Helmut Münstedt Friedrich Wilhelm Neukam Emeka Nkenke Cornelius von Wilmowsky 《Macromolecular Symposia》2007,253(1):65-70
Summary: The following investigation focuses on polyetheretherketone (PEEK) for bone substitutes intended for maxillofacial surgery. Different three-dimensional discs with a diameter of 12 mm and a height of 3 mm were laser sintered. As filler materials nano-sized carbon black and β-tricalciumphosphate powder with an average grain size of 35 µm were used. Human osteoblasts were cultivated on the discs and examined with scanning electron microscopy. Cell vitality and cell growth was investigated. The data shows that PEEK surfaces does not suppress osteoblast proliferation. 相似文献
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