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71.
Dietmar Krämer Erwin Rosenberg Achim Krug Robert Kellner Wolfgang Hutter Werner Hampel 《Mikrochimica acta》1994,116(4):183-189
Chloride is determined indirectly by Spectrophotometric flow injection analysis. Two systems are compared, both based on the principle of ion exchange of easily detectable anions versus chloride from suitable mercury salts. The first method is based on the exchange of chloride with chloranilate which is detected at 332 nm or at 306 nm in neutral or in acidic medium respectively. In the second case, chloride reacts with Hg(SCN)2. The liberated thiocyanate forms a strongly coloured complex with Fe(III) in acidic solution with an absorption maximum at 460 nm. Both methods have a detection limit of about 5 mol Cl–/l (175 ng/ml). In the case of the thiocyanate method, the relative standard deviation is about 2% (7 measurements) in the range of 5 to 150 mol/l and decreases significantly to a value of approximately 0.2% at higher concentrations; for the chloranilate method it is 10% for lower and about 1% for higher concentrations respectively. 相似文献
72.
Werner Hoffmann 《Annals of Global Analysis and Geometry》1994,12(1):19-63
Automorphic forms of arbitrary real weight can be considered as functions on the universal covering group of SL(2, ). In this situation, we prove an invariant form of the Selberg trace formula for Hecke operators. For this purpose, the Fourier transforms of weightet orbital integrals, obtained by J. Arthur, R. Herb and P. Sally, jr., are explicitly calculated. Our formula does not follow from Arthur's invariant trace formula, since the group has infinite centre, and vector-valued automorphic forms with respect to non-congruence lattices are considered. 相似文献
73.
74.
We consider, both for unpolarized and longitudinally polarized electron beams, the reaction $e^ + e^ - \to t\bar t$ with subsequent semileptonict and nonleptonic $\bar t$ decay and vice versa and investigate optimized angular correlations which are sensitive to CP non-conservation in the $t\bar t$ production vertex. We calculate these correlations for two-Higgs-doublet extensions and the minimal super-symmetric extension of the Standard Model (SM) with CP violation beyond the Kobayashi-Maskawa phase. While the sensitivity of the optimal correlation for tracing dispersive CP effects is enhanced with longitudinally polarized electron beams, we find that the sensitivity of the best correlation for probing absorptive CP effects is almost independent of the polarization degree. 相似文献
75.
P. Ackerbauer W. H. Breunlich M. Fuchs S. Fussy M. Jeitler P. Kammel B. Lauss J. Marton W. Prymas J. Werner J. Zmeskal K. Lou C. Petitjean P. Baumann H. Daniel F. J. Hartmann W. Schott T. von Egidy P. Wojciechowski D. Chatellard J. P. Egger E. Jeannet T. Case K. M. Crowe R. H. Sherman V. Markushin 《Hyperfine Interactions》1993,82(1-4):243-258
Complementary to the investigations of the most efficient dt cycle, also the other muon-induced fusion cycles in mixtures of hydrogen isotopes have been studied. The results of these dedicated experiments provide rich information about muon-induced few-body reactions and contribute significantly to a better overall understanding of CF. A summary of the recent progress will be presented. Special emphasis will be put on two characteristic examples, namely a new experimental approach to study the muonic cascade in H-D mixtures and the systematic study of hyperfine effects in muon-induced reactions. 相似文献
76.
P. Ackerbauer J. Werner W. H. Breunlich M. Cargnelli M. Jeitler P. Kammel J. Marton N. Nägele A. Scrinzi J. Zmeskal J. Bistirlich K. M. Crowe C. Petitjean R. H. Sherman P. Baumann H. Bossy H. Daniel F. J. Hartmann W. Schott T. von Egidy W. Neumann 《Hyperfine Interactions》1993,82(1-4):357-372
A main source of information about the muon-catalyzed fusion cycle in D-T mixtures are the cycling rates c, which are characteristic for the kinetic equilibrium of states attained rapidly in dense targets. The measurement, analysis and interpretation of these rates will be discussed, concentrating on the extensive set of rates observed at PSI over the last decade in gaseous, liquid and solid targets.Invited talk presented by Peter Kammel. 相似文献
77.
[reaction: see text] The properties of the self-assembling aziadamantane inclusion complex with two alpha-cyclodextrin molecules have been exploited to perform a chemospecific monofunctionalization of alpha-cyclodextrin. The insertion of the photochemically generated carbenes takes place chemospecifically into the cyclodextrin's C-3-OH and C-2-OH bonds in 39 and 18% yield, respectively. This model reaction surpasses conventional methods in terms of yield as well as selectivity. 相似文献
78.
Vaporization of Silver in a Stream of Oxygen Using a transport equipment the vaporization of silver at 611–721°C in a stream of oxygen has been measured. Experiments with detachable cuffs of silver or with wools of silver in a bulb made from quartzglass or silver lead to the same results. By variation of the O2-pressure and the activity of silver is observed that the vaporization happens as Ag2O,g, see “Inhaltsübersicht”. The solid was at first pure silver. During long lasting experiments, however, it is covered with a thin layer of oxygen or silver oxide, which lowers the concentration of Ag2O,g in the equilibrium gas to a smaller, yet constant value. The following measurements using N2 as carrier gas lead to the decomposition of this layer and ends with the very small vapor pressure of silver. The layer of oxygen or silver oxide on the metal could be shown after Davies [2] using mercury. 相似文献
79.
Preparation and Crystal Structure of LnAl3Br12 (Ln = La, Ce, Pr, Nd, Sm, Gd) and Thermal Decomposition to LnBr3 LnAl3Br12 (Ln = La, Ce, Pr, Nd, Sm, Gd) was prepared in crystalline form for the first time. The crystal structures of LaAl3Br12, PrAl3Br12, and NdAl3Br12 were determined on single crystals by X-ray methods. The isotypic compounds crystallize with trigonal symmetry, space group P 3112, Z = 3. A structural comparison to lanthanoide chloroaluminates of equal composition is given and thermal decomposition of LnAl3Br12 (Ln = Nd) to the corresponding lanthanoide tribromide is described. 相似文献
80.
A practicable and selective liquid chromatography-mass spectrometry assay for the determination of two cyclooxygenase-2 inhibitors, etoricoxib and valdecoxib, in human plasma is presented. The analytical technique is based on reversed-phase high-performance liquid chromatography (HPLC) coupled to atmospheric pressure chemical ionisation (APCI) mass spectrometry (Finnigan Mat LCQ ion trap). Mass analysis was performed in the positive ion mode. The ion trap was operated in the tandem MS mode (MS2) and the transitions of etoricoxib (m/z 359.2 --> 280.3) and valdecoxib (m/z 315.1 --> 235.1) were followed by selected reaction monitoring. Retention times of etoricoxib and valdecoxib were 1.05 and 1.08 min, respectively. The method was validated over a linear range 10-2500 and 5-1000 microg/L using the other substrate as internal standard. After validation, the method was used to study the pharmacokinetic pro fi le of etoricoxib or valdecoxib in a healthy volunteer after administration of a single oral dose (valdecoxib, 20 mg; etoricoxib, 90 mg). The presented method was suf fi cient to cover more than 90% of the area under the plasma concentration time curve. 相似文献