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81.
82.
Modeling study is performed to reveal the special features of the entrainment of ambient air into subsonic laminar and turbulent
argon plasma jets. Two different types of jet flows are considered, i.e., the argon plasma jet is impinging normally upon
a flat substrate located in atmospheric air surroundings or is freely issuing into the ambient air. It is found that the existence
of the substrate not only changes the plasma temperature, velocity and species concentration distributions in the near-substrate
region, but also significantly enhances the mass flow rate of the ambient air entrained into the jet due to the additional
contribution to the gas entrainment of the wall jet formed along the substrate surface. The fraction of the additional entrainment
of the wall jet in the total entrained-air flow rate is especially high for the laminar impinging plasma jet and for the case
with shorter substrate standoff distances. Similarly to the case of cold-gas free jets, the maximum mass flow-rate of ambient
gas entrained into the turbulent impinging or free plasma jet is approximately directly proportional to the mass flow rate
at the jet inlet. The maximum mass flow-rate of ambient gas entrained into the laminar impinging plasma jet slightly increases
with increasing jet-inlet velocity but decreases with increasing jet-inlet temperature. 相似文献
83.
84.
85.
A low-molecular-weight gel with dual pH and glucose sensitivity was designed as the gate controller for mesoporous silica nanoparticles (MSNs) to fabricate a smart drug delivery system. The smart gel caped MSNs could control the antidiabetic drug release via the detection of glucose and pH levels. 相似文献
86.
Modeling results are presented to compare the characteristics of laminar and turbulent argon thermal plasma jets issuing into ambient air. The combined-diffusion-coefficient method and the turbulence-enhanced combined-diffusion-coefficient method are employed to treat the diffusion of ambient air into the laminar and turbulent argon plasma jects, respectively. It is shown that since only the molecular diffusion mechanism is involved in the laminar plasma jet, the mass flow rate of ambient air entrained into the laminar plasma jet is comparatively small and less dependent on the jet inlet velocity. On the other hand, since turbulent transport mechanism is dominant in the turbulent plasma jet, the entrainment rate of ambient air into the turbulent plasma jet is about one order of magnitude larger and almost directly proportional to the jet inlet velocity. As a result, the characteristics of laminar plasma jets are quite different from those of turbulent plasma jets. The length of the high-temperature region of the laminar plasma jet is much longer and increases notably with increasing jet inlet velocity or inlet temperature, while the length of the high-temperature region of the turbulent plasma jet is short and less influenced by the jet inlet velocity or inlet temperature. The predicted results are reasonably consistent with available experimental observation by using a DC arc plasma torch at arc currents 80–250 A and argon flow rates (1.8–7.0)×10−4 kg/s. 相似文献
87.
88.
Andrew J. Guenthner Sureeporn Khombhongse Wenxia Liu Pratyush Dayal Darrell H. Reneker Thein Kyu 《Macromolecular theory and simulations》2006,15(1):87-93
Summary: To mimic the emergence of gradient morphology in polymer nanofibers, a new theoretical approach has been developed in the context of Cahn‐Hilliard time evolution equation, alternatively known as time‐dependent Ginzburg‐Landau equation (Model B) involving concentration order parameter. The effects of solvent evaporation on the morphology evolution of the nanofibers have been demonstrated. The numerical simulation showed that the formation of skin layers is governed by the competition between solvent evaporation rate and mutual diffusion rate. That is to say the skin layers are formed in the nanotube whenever the rate of evaporation exceeds a critical value; otherwise, a solid fiber is formed. In hollow nanofibers, the layer can grow to a substantial fraction of the fiber diameter, allowing it to remain intact, albeit often in a collapsed form.
89.
The present study uses 2D NMR to assign all resonance lines of pentagastrin completely. From 2D NOESY and coupling constants JHNα, interproton distance and torsion angle Φ restraints were obtained. Based on them, the model of conformation for pentagastrin was proposed by restrained molecular dynamics calculation. It is shown that the C-terminal part of pentagastrin forms a Δ turn with a weak H-bond between the CO of Met and the NH of Phe. A strong H-bond between indole NH of Trp and β-carboxyl group of Asp stablizes the folded form in DMSO, which may result in a significant increase in the population of a favorable conformation for interaction with receptor. 相似文献
90.
Two-dimensional(2D) 1H. nuclear magnetic resonance exchange spectroscopy, 1D saturation transfer have been utilized to study the binding of imidazole(lm), 1-Methylimidazole(Melm), 1-Ethylimidazole(Etlm) to the heme iron of metmyoglobin. Some heme peripheral proton resonance's of these complexes have been first time assigned. The rates and equilibrium constants for Im, Melrn, Etlm binding to metMb are calculated from the 2D peak amplitudes. Analysis of the heme methyl shifts indicates that the orientations of the binding Im, Melm, Etlm are very similar. The steric effects and hydrogen bonding between the distal histidine and bound ligand are important factors regulating affinity. 相似文献