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951.
Ding Wenwen He Yongjia Lu Linnu Rao Meijuan Wang Fazhou 《Journal of Thermal Analysis and Calorimetry》2019,135(4):2009-2018
Journal of Thermal Analysis and Calorimetry - The present task is to investigate the influence of iron on the mineral composition and microstructure of the phase Q (C20A13M3S3, in the text below... 相似文献
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Progress in surface modification of magnetic nanoparticles(MNPs)is summarized with regard to organic molecules,macromolecules and inorganic materials.Many researchers are now devoted to synthesizing new types of multi-functional MNPs,which show great application potential in both diagnosis and treatment of disease.By employing an ever-greater variety of surface modification techniques,MNPs can satisfy more and more of the demands of medical practice in areas like magnetic resonance imaging(MRI),fluorescent marking,cell targeting,and drug delivery. 相似文献
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Wenwen Wu Honglie Shen Jieyi Chen Huirong Shang Jinze Li Wangyang Yang Yufang Li 《Journal of Sol-Gel Science and Technology》2018,86(2):266-273
A novel approach based on sol–gel spin coating method to deposit Zn(O,S) thin film using thiourea(TU) as a sulfur source replacing CdS as buffer layer was developed and the influence of TU concentration on the properties of Zn(O,S) thin films and Cu(In,Ga)Se2(CIGS) solar cells were investigated in this paper. It was found by X-ray diffraction and X-ray photoelectron spectroscopy that sol–gel derived Zn(O,S) thin films were amorphous and composed of ZnS, ZnO as well as Zn(OH)2. The variation of the optical band gap as a function of the S/(S+O) ratio was determined by energy-dispersive spectroscopy and UV-VIS-NIR. The results indicated that the minimum value for band gap of approximate 3.72?eV was obtained when the S/(S+O)?=?0.44. Efficiency of up to 7.28% was achieved for a CIGS solar cell with Zn(O,S) buffer layer from 0.2M TU, which was attributed to the optimized conduction band offset (CBO) of +0.45?eV at the CIGS/Zn(O,S) interface. 相似文献
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A new nitrosation and oxidation process to synthesize gem-dinitro compounds was accomplished by using nitryl chloride as nitrosation reagent and ozone as oxidizing agent. The main features of the present protocol include the compatibility to substances with high steric hindrance, high yields and mild reaction conditions. A plausible mechanism involving the formation of an intermediate of gem-nitrosonitro compound by means of single electron transfer was also proposed. 相似文献
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A colorimetric probe N,N’-bis(2-methoxy-ethyl)-2,3,3-trimethyl-3H-squaraine (MOESQ) with H2O solubility was synthesized to detect Cu2+. MOESQ exhibits good selectivity, high sensitivity and fast UV-Vis response toward Cu2+ over other competing ions in CH3CN. The detection limit of MOESQ for Cu2+ in CH3CN can reach 1.88?×?10?7?molL?1. By adsorbing MOESQ on the chromatography paper, a colorimetric test paper for Cu2+ was prepared, which could detect Cu2+ with the color change from blue to faint yellow even in the limit of detection concentration of 10?6?molL?1. 相似文献
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Baichuan Han Jin Sun Kai Chen Zhiyong Chen Minhua Huang Zhenzhong Gao Xianfeng Hou 《Tetrahedron》2018,74(50):7193-7197
A novel fluorescent probe was developed for formaldehyde, which can be synthesized by one-step Buchwald–Hartwig reaction. When hydrazino-group of probe reacted with formaldehyde, hydrophobic reaction product aggregates into nanoparticles and results in the blue fluorescence due to the monomer-excimer effect. With enough sensitivity, high selectivity, good stability in physiological pH range and excellent biocompatibility, this probe can image formaldehyde in living cells. 相似文献