全文获取类型
收费全文 | 16783篇 |
免费 | 443篇 |
国内免费 | 136篇 |
专业分类
化学 | 11646篇 |
晶体学 | 136篇 |
力学 | 513篇 |
数学 | 2548篇 |
物理学 | 2519篇 |
出版年
2022年 | 113篇 |
2021年 | 159篇 |
2020年 | 223篇 |
2019年 | 204篇 |
2018年 | 188篇 |
2017年 | 151篇 |
2016年 | 323篇 |
2015年 | 276篇 |
2014年 | 318篇 |
2013年 | 800篇 |
2012年 | 789篇 |
2011年 | 1074篇 |
2010年 | 499篇 |
2009年 | 457篇 |
2008年 | 882篇 |
2007年 | 920篇 |
2006年 | 962篇 |
2005年 | 889篇 |
2004年 | 811篇 |
2003年 | 730篇 |
2002年 | 694篇 |
2001年 | 235篇 |
2000年 | 202篇 |
1999年 | 165篇 |
1998年 | 190篇 |
1997年 | 201篇 |
1996年 | 241篇 |
1995年 | 187篇 |
1994年 | 186篇 |
1993年 | 150篇 |
1992年 | 152篇 |
1991年 | 159篇 |
1990年 | 132篇 |
1989年 | 115篇 |
1988年 | 151篇 |
1987年 | 142篇 |
1986年 | 107篇 |
1985年 | 213篇 |
1984年 | 235篇 |
1983年 | 170篇 |
1982年 | 241篇 |
1981年 | 220篇 |
1980年 | 225篇 |
1979年 | 207篇 |
1978年 | 199篇 |
1977年 | 182篇 |
1976年 | 183篇 |
1975年 | 152篇 |
1974年 | 162篇 |
1973年 | 155篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
James P. Ignizio 《The Journal of the Operational Research Society》1985,36(6):507-515
Goal programming, and in particular lexicographic goal programming (i.e. goal programming within a so-called ‘pre-emptive priority’ structure or having non-Archimedean weights), has become one of the most widely used of the approaches for multi-objective mathematical programming. While also applicable to non-linear or integer models, most of the literature has considered the lexicographic linear goal-programming model and its solution via primal simplex-based methods. However, in many cases, enhanced efficiency (and significant additional flexibility) may be gained via an investigation of the dual of this problem. In this paper we consider an algorithm for solving such a dual and also indicate how it may be implemented on conventional (i.e. single objective) simplex software. 相似文献
122.
Abstract— The concentration of Escherichia coli in the input and output of a tertiary wastewater system (4 lagoons) has been monitored over an 11 month period. The integrated flux of biologically active solar ultraviolet (UV) radiation was measured during this period. By also determining (1) the effective temperature in the system, (2) the growth rate of E. coli at the effective temperature, (3) the penetration of the solar UV into the lagoons, (4) the dose-response relation for killing of E. coli by UV and (5) the retention time of water in the system, it is possible to compare the 'die off' expected from solar UV exposure to the actual 'die off' observed for different batches of water.
The observed killing of E. coli was quite close to the values calculated, considering the numerous factors involved. Solar UV light would thus seem to be a very important factor in the natural purification of water. Because each successful species must possess characteristics (physiological or behavioral) which provide adequate resistance to solar UV, the ecological role of solar UV radiation has not been widely appreciated. 相似文献
The observed killing of E. coli was quite close to the values calculated, considering the numerous factors involved. Solar UV light would thus seem to be a very important factor in the natural purification of water. Because each successful species must possess characteristics (physiological or behavioral) which provide adequate resistance to solar UV, the ecological role of solar UV radiation has not been widely appreciated. 相似文献
123.
124.
Ricardo Fierro James C. W. Chien Marvin D. Rausch 《Journal of polymer science. Part A, Polymer chemistry》1994,32(15):2817-2824
Racemic isopropylidene (1-η5-cyclopentadienyl)(1-η5-indenyl) dichlorozirconium and the 3-methylindenyl derivative have been synthesized and characterized. These precursors activated with methylaluminoxane produce poly(propylene) with hemiisotactic microstructures. © 1994 John Wiley & Sons, Inc. 相似文献
125.
A liquid chromatography/mass spectrometry (LC/MS) method was developed to quantitate and confirm residues of leucomalachite green (LMG) in salmon tissue after their conversion to chromic malachite green (MG) in the extraction process. The method uses no-discharge atmospheric pressure chemical ionization (APCI) in conjunction with an ion-trap instrument to generate product-ion spectra. In the sample preparation procedure, salmon tissue is extracted with acetonitrile/buffer, the LMG residue is partitioned into methylene chloride, the LMG is converted to MG using an organic oxidizing agent, and the MG is isolated on alumina/propylsulfonic acid solid-phase extraction cartridges. The method was validated by fortifying salmon with different levels of LMG, and then detecting the residue as MG The LC/MS conditions, including a comparison of electrospray and no-discharge APCI, were evaluated and optimized. MG was not confirmed in any of the control tissue extracts, and all fortified samples analyzed during validation met the confirmation criteria as described. In addition to providing confirmatory data, this method can provide an alternative method for quantitation of MG in salmon. The recoveries of LMG measured as MG by this LC/MS method, at fortification levels of 1-10 ng/g were very high (86-109%), with low relative standard deviation(RSD) values (6.4-13%). The results agreed very closely with those obtained for the same extracts using an LCNIS procedure, indicating that matrix suppression was not an issue. The presence of LMG in salmon tissue samples fortified at 0.25 ng/g was confirmed by this method, with an average recovery of 70.1% and an RSD of 12.0%. Sample extracts from fish exposed to MG were also analyzed. 相似文献
126.
127.
High density (98% of theoretical) was achieved at 900°C for an all-alkoxide derived bulk celsian gel prior to crystallisation. TEM indicated that crystallisation was dominated by volume nucleation and growth of hexagonal disc shaped hexacelsian. Kinetic studies using SEM indicate a maximum nucleation rate at 980°C and an activation energy for crystal growth of 566 KJ/mol. The high rates of densification and of nucleation are attributed to the high OH content in the gel-derived glass. 相似文献
128.
The cucurbit[n]uril (CB[n]) family of macrocycles occupies a prominent role in molecular recognition and self-assembly studies despite the current inability to access specific cucurbit[n]uril homologues, derivatives, and analogues by straightforward tailor-made synthetic procedures. In this paper, we explore an approach that circumvents the challenges posed by the tailor-made synthesis of macrocyclic CB[n] by preparing 1, which functions as an acyclic CB[6] congener. The o-xylylene connections to the glycoluril rings preorganize 1 into the (a,a,a,a)-1 conformation required for binding and reduce its tendency to undergo self-association. We surveyed the binding properties of 1 toward 16 amines (K(a) 相似文献
129.
Vaze A Parizo M Rusling JF 《Langmuir : the ACS journal of surfaces and colloids》2004,20(25):10943-10948
Redox proteins attached to surfaces designed for biocatalysis hold promise for future clean synthetic routes. It is advantageous for these biocatalysts to operate in low-toxicity fluids with a high capacity to dissolve reactants. Here we report cross-linked films of myoglobin (Mb) and poly(L-lysine) (PLL) chemically attached to oxidized carbon cloth cathodes that in microemulsions feature the protein in a water-rich film environment with reactant in an oil-rich environment. These cross-linked Mb/PLL films were the most stable in microemuslions and had the largest turnover rates for epoxidation of styrene compared to lightly cross-linked or uncross-linked Mb/poly(styrene sulfonate) films. Up to 40-fold larger turnover rates were found in bicontinuous microemulsions compared to oil-in-water microemulsions and micelles. Enhanced turnover rates are correlated with up to 10-fold faster mass transport of solutes in the oil phases of the bicontinuous fluids. 相似文献
130.
Paul Schaffer James F. Britten Alan Davison Alun G. Jones John F. Valliant 《Journal of organometallic chemistry》2003,680(1-2):323-328
Two homoleptic Re(I) complexes of ortho and para-carborane isocyanide ligands were prepared as the first examples of a new class of metal-based BNCT and BNCS agents. The target compounds were prepared in low yield through the reaction of [Re2(O2CPh)4Cl2] and [Re2(OAc)4Cl2] with 3-isocyano-1,2-dicarba-closo-dodecaborane and a para-carborane azetidine derivative respectively. The desired product from the latter reaction was characterized crystallographically and is only the second reported molecular structure of a homoleptic Re(I) isonitrile complex. 相似文献