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991.
A series of furoxan-based novel nitric oxide-donating ursolic acid(UA) derivatives(7a-f) were synthesized,and their cytotoxic activities against HepG2 cells in vitro were evaluated by MTT method.It was found that 7a-d and 7f showed more potent cytotoxic activities than control 5-fluorouracil and UA. 相似文献
992.
Facile synthesis of the two new natural heterocyclic compounds bretschneiderazines A(2) and B(3),isolated from an extract of the stems of Bretschneidera sinensis,is reported.We employed the cyclization reaction of benzamide by directed lithiation and sequential treatment with sulfur and phosgene as key steps.All new compounds have been fully characterized by means of IR,1H NMR,13C NMR,and HRMS. 相似文献
993.
A cobalt(11) complex containing mixed-ligands of 1,10-phenathroline(phen) and glycollic acid(GA).|Co(GA)2(phen)| was synthesized and its structure was characterized by X-ray diffraction.The interaction of the complex with DNA was investigated by electronic absorption spectra and electrochemical methods.Electronic absorption spectrum experiments showed that after interaction with DNA.the characteristic absorption peaks of |Co(GA)2(phen)| underwent hypochromic effect as well as redshift. Also,the binding strength of 3.8×104L/mol was estimated by titration method.Electrochemical assays revealed that the redox peak currents of the complex decreased obviously accompanied by a positive shift of the formal potential after association with DNA.All these results revealed that the synthesized cobalt complex bound with DNA via an intercalation mode. 相似文献
994.
Ray effects are an inherent problem of the discrete ordinates method. RAY3 D, a functional module of ARES, which is a discrete ordinates code system, employs a semi-analytic first collision source method to mitigate ray effects. This method decomposes the flux into uncollided and collided components, and then calculates them with an analytical method and discrete ordinates method respectively. In this article, RAY3 D is validated by the Kobayashi benchmarks and applied to the neutron beamline shielding problem of China Spallation Neutron Source(CSNS)target station. The numerical results of the Kobayashi benchmarks indicate that the solutions of DONTRAN3 D with RAY3 D agree well with the Monte Carlo solutions. The dose rate at the end of the neutron beamline is less than10.83 μSv/h in the CSNS target station neutron beamline shutter model. RAY3 D can effectively mitigate the ray effects and obtain relatively reasonable results. 相似文献
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Wen Piao Satoru Tsuda Dr. Yuji Tanaka Dr. Satoshi Maeda Dr. Fengyi Liu Shodai Takahashi Yu Kushida Dr. Toru Komatsu Dr. Tasuku Ueno Dr. Takuya Terai Prof. Toru Nakazawa Prof. Masanobu Uchiyama Prof. Keiji Morokuma Prof. Tetsuo Nagano Dr. Kenjiro Hanaoka 《Angewandte Chemie (International ed. in English)》2013,52(49):13028-13032
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By expanding the hard-aperture function into a finite sum of complex Gaussian functions, we derive approximate analytical formulae for Lorentz and Lorentz-Gauss beams propagating through an apertured fractional Fourier transform (FRT) optical system. As an application example, properties of a Lorentz-Gauss beam in the FRT plane after propagating through a squarely or annularly apertured FRT optical system are studied numerically. The results obtained using the approximate analytical formula are in good agreement with those obtained using numerical integral calculation. The FRT optical system provides a convenient way for laser beam shaping. 相似文献