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911.
IntroductionThealkalihalidediatomicmoleculesprovideatypicalcurvecrosingproblem[1].Theoutstandingnonadiabaticbehaviorofthechem... 相似文献
912.
In the system of SDS/n-C5H11OH/n-C7H16/H2O with the weight ratio of SDS/n-C5H11OH/H2O system at5.0/47.5/47.5, the upper phase of the system was W/O microemulsion, and the lower phase was the bicontinuous microemulsion. When the n-heptane content was less than 1%, with the increase of the n-heptane content, the capacitance (Co, Cod) in the upper phase (W/O) dropped, the capacitance (CB1, CBld) in the lower phase (BI) raised. At the same time, the W/O-BI inteffacial potential (ΔE), capacitance (Ci), and charge-transfer current (ict) decreased.After the n-heptane content reached 1%, with the increase of the n-heptane content, ΔE, Ci and ict demonstrated no significant change. 相似文献
913.
负载型纳米TiO2复合载体及其CoMo催化剂的酸性及孔特性的研究 总被引:3,自引:0,他引:3
总结了复载不同纳米尺度的复合载体及其CoMo催化剂的表面酸性及孔结构特性的表征结果。结果表明,负载型纳米TiO2与基载体γ-Al2O3存在着相互作用。当负载比较少量的纳米TiO2时,复合载体的总酸量随着TiO2含量的增加而增加,超过γ-Al2O3的酸量,但当 TiO2的含量比较高时复合载体的酸量又降低,纳米TiO2优先负载在γ-Al2O3的强酸中心位;负载了CoMo活性组分后酸量增加。不同粒径的纳米TiO2对复合载体和催化剂的酸分布没有明显影响,但对总酸量有影响。对不同尺度TiO2,随着TiO2负载量的增加以及负载金属活性组分的增加,表面积、孔容和最可几孔径均有不同程度的减少。 相似文献
914.
Wei SUN Dan Dan WANG Rui Fang GAO Jian SUN Kui JIAO 《中国化学快报》2006,17(12):1589-1591
In recent years the direct electron transfer of redox protein on electrode surface has attracted great attentions1. Different kind of modified electrode and various supporting films for immobilization of proteins had been proposed. But most of them are ba… 相似文献
915.
CdS nanoparticles have been prepared and modified with mercaptoacetic acid. The functionalized nanoparticles are water-soluble and biocompatible. They could be used as a fluorescence probe in the determination of bovine serum albumin (BSA), which was proved to be a simple, rapid and specific method. In comparison with single organic fluorophores, these nanoparticle probes are brighter, more stable against photobleaching, and do not suffer from blinking. Under the optimum conditions, the response is linearly proportional to the concentration of BSA between 0.1 and 3.2 μg ml−1, and the limit of detection is 0.08 μg ml−1. 相似文献
916.
Lu W Mi BX Chan MC Hui Z Zhu N Lee ST Che CM 《Chemical communications (Cambridge, England)》2002,(3):206-207
Tridentate cyclometalated platinum(II) complexes bearing sigma-alkynyl ligands exhibit tunable photoluminescence and enhanced stability during vacuum deposition; OLEDs based on these materials display orange to red electrophosphorescence with low turn-on voltages (approximately 4 V), maximum luminance approaching 10,000 cd m-2 and efficiency up to 4.2 cd A-1. 相似文献
917.
我们利用Born-Mayer-Huggins相互作用势函数对(KF)N(N=108,256,500和864)团簇进行了分子动力学(MD)模拟。为了避免周期性边界条件对相变、成核和重结晶的干扰作用,对体系采用了自由边界。基于MD模拟结果,对团簇的熔化温度、熔化焓、扩散系数、成核速率、固液界面自由能、临界核大小等进行了计算和讨论。在对(KF)864双晶团簇的热退火模拟中,观察到了固态的重结晶和晶粒的生长。经典的成核理论成功地解释了(KF)864双晶团簇的重结晶MD模拟结果。 相似文献
918.
Xiu-Kui Qu Lan-Ying Zhu Ling Li Xi-Lian Wei Feng Liu De-Zhi Sun 《Journal of solution chemistry》2007,36(5):643-650
As a continuation of our previous investigation, interactions between cyclodextrin (β-CD), γ-cyclodextrin (γ-CD) and alkyl trimethylammonium bromides in aqueous solutions have been studied with titration calorimetry and 1H NMR at 298.15 K. The results are discussed in terms of the amphiphilic interaction of CD with surfactants and the iceberg
structure formed by water molecules existing around the hydrophobic tail of surfactant molecules. The stoichiometry of the β-CD–surfactant system is 1:1 whereas that of the γ-CD–surfactant system is 1:2. The corresponding formation enthalpy (negative) of the complexes of the two systems decreases
with an increase in the number of carbon atoms (n) in hydrophobic chain of surfactant molecule, C
n
H2n+1, whereas the entropy increases with the enlargement of n. 相似文献
919.
Liang Wang Jun Yue Bai Peng Fei Huang Hong Jing Wang Xiao Wei Wu Yu Qing Zhao 《Mikrochimica acta》2007,158(1-2):73-78
The electrochemical behaviors of uric acid (UA) at the penicillamine (Pen) self-assembled monolayers modified gold electrode
(Pen/Au) have been studied. The Pen/Au electrode is demonstrated to promote the electrochemical response of UA by cyclic voltammetry
(CV). The diffusion coefficient D of UA is 6.97 × 10−6 cm2 s−1. In differential pulse voltammetric (DPV) measurements, the Pen/Au electrode can separate the UA and ascorbic acid (AA) oxidation
potentials by about 120 mV and can be used for the selective determination of UA in the presence of AA. The detection limit
was 1 × 10−6 mol L−1. The modified electrode shows excellent sensitivity, good selectivity and antifouling properties. 相似文献
920.
1 INTRODUCTION In recent years, chiral β-amino alcohols have attracted much attention due to their special bio- logical functions and catalytic activities. Chiral β- amino alcohol moieties are usually found not only in natural products (e.g., cinchona alkaloids, ephe- drine, toxal, etc.) with special biological activities[1, 2], but also critical structural segments of some syn- thesized biologically active compounds, such as adrenergic agonists or antagolist[3, 4] and inhibitors for HI… 相似文献