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921.
Young Jin Cho Seung Hwan Lee Jong Woo Bae Sung Hoon Kim Sam Rok Keum Cheol Min Yoon 《合成通讯》2013,43(12):2205-2211
The 7-acetoxyspiropyrans (4a and 4b) have been prepared by the reaction of Fischer's bases (3) with 2,4-diacetoxybenzaldehyde in refluxing ethanol in moderate yields. The acetyl group of 7-acetoxy-spiropyran 4a was easily removed to give a 7-hydroxyspiropyran 6 in high yield under the basic condition. 相似文献
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Abstract The graft copolymerizations of acrylonitrile (AN) and 1-vinyl-naphthalene (1-VN) onto ethylene-propylene-diene terpolymer (EPDM) were carried out with benzoyl peroxide (BPO) as an initiator in toluene. The effects of the mole ratio of 1-VN to AN, initiator concentration, reaction time, reaction temperature, and EPDM concentration on the graft copolymerizations were examined. The synthesized graft terpolymers, acrylonitrile-EPDM-1-vinylnaphthalene (AEV1), were identified by IR spectra. The thermal stability and tensile strength of AEV1 were greatly improved compared with those of ABS. The light resistance and weatherability of AEV1 were better than those of ABS when subjected to UV light for longer than 96 hours. 相似文献
923.
Computation of a moving interface by the level‐set (LS) method typically requires reinitialization of LS function. An inaccurate execution of reinitialization results in incorrect free surface capturing and thus errors such as mass gain/loss so that an accurate and robust reinitialization process in the LS method is essential for the simulation of free surface flows. In the present study, we pursue further development of the reinitialization process, which directly corrects the LS function after advection is carried out by using the normal vector to the interface instead of solving the reinitialization equation of hyperbolic type. The Taylor–Galerkin method is adopted to discretize the advection equation of the LS function and the P1P1 splitting finite element method is applied to solve the Navier–Stokes equation. The proposed algorithm is validated with the well‐known benchmark problems, i.e. stretching of a circular fluid element, time‐reversed single‐vortex, solitary wave propagation, broken dam flow and filling of a container. The simulation results of these flows are in good agreement with previously existing experimental and numerical results. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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When the Wolsong 1st CANDU reactor in Korea is reaching the end of its original lifespan, decommissioning has been one of the largest issues faced by the nuclear industry and the government for the estimation of expense. The radioactive sources in the construction stuffs and components of the reactor such as pressure tubes, steam generators must be evaluated for the estimation of the appropriate expense for the decommissioning. Unfortunately we do not have exact information about the initial composition of the pressure tubes. In this study the elemental contents of Nb and Zr in the activated zircaloy pressure tubes was investigated. Nb is one of the important elements that characterize the physical and mechanical properties of the pressure tube and a major source of high radioactivity. The prepared samples were strongly irradiated again in the vertical irradiation channel at the HANARO research reactor in the Korea Atomic Energy Research Institute (KAERI) and then measured by an HPGe detector. 相似文献
926.
Hye-Young Lee You-Jin Choi Eun-Jung Jung Hu-Quan Yin Jung-Taek Kwon Ji-Eun Kim Hwang-Tae Im Myung-Haing Cho Ju-Han Kim Hyun-Young Kim Byung-Hoon Lee 《Journal of nanoparticle research》2010,12(5):1567-1578
Silver nanoparticles (AgNP) are among the fastest growing product categories in the nanotechnology industry. Despite the importance of AgNP in consumer products and clinical applications, relatively little is known regarding AgNP toxicity and its associated risks. We investigated the effects of AgNP on gene expression in the mouse brain using Affymetrix Mouse Genome Arrays. C57BL/6 mice were exposed to AgNP (geometric mean diameter, 22.18 ± 1.72 nm; 1.91 × 107 particles/cm3) for 6 h/day, 5 days/week using the nose-only exposure system for 2 weeks. Total RNA isolated from the cerebrum and cerebellum was subjected to hybridization. From over 39,000 probe sets, 468 genes in the cerebrum and 952 genes in the cerebellum were identified as AgNP-responsive (one-way analysis of variance; p < 0.05). The largest groups of gene products affected by AgNP exposure included 73 genes in the cerebrum and 144 genes in the cerebellum. AgNP exposure modulated the expression of several genes associated with motor neuron disorders, neurodegenerative disease, and immune cell function, indicating potential neurotoxicity and immunotoxicity associated with AgNP exposure. Real-time PCR data for five genes analyzed from whole blood showed good correlation with the observed changes in the brain. Following rigorous validation and substantiation, these genes may assist in the development of surrogate markers for AgNP exposure and/or toxicity. 相似文献
927.
Synthesis of Silicate Zeolite Analogues Using Organic Sulfonium Compounds as Structure‐Directing Agents
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Dr. Changbum Jo Sungjune Lee Prof. Sung June Cho Prof. Ryong Ryoo 《Angewandte Chemie (International ed. in English)》2015,54(43):12805-12808
A microporous crystalline silica zeolite of the MEL structure type and three other zeolite analogues composed of germanosilicate frameworks were synthesized using tributylsulfonium, triphenylsulfonium, or tri(para‐tolyl)sulfonium as the structure‐directing agent. The germanosilicates thus obtained had ISV, ITT, or a new zeolite structure depending on the synthesis conditions. The structure of the new germanosilicate was solved using X‐ray powder diffraction data with the aid of a charge‐flipping method. The solution indicated a crystal structure belonging to the P63/mmc space group with cell parameters of a=16.2003 Å and c=21.8579 Å. After calcination, the new germanosilicate material exhibited two types of accessible micropores with diameters of 0.61 and 0.78 nm. 相似文献
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